Morphological study of $SF_6$ clathrate hydrate crystal

$SF_6$ 하이드레이트 결정 성장의 특성

  • 이윤석 (부산대학교 재료공학부) ;
  • 이현주 (부산대학교 재료공학부) ;
  • 이은경 (부산대학교 재료공학부) ;
  • 김수민 (부산대학교 재료공학부) ;
  • 이주동 (한국생산기술 연구원 동남권기술지원본부) ;
  • 김양도 (부산대학교 재료공학부)
  • Published : 2009.06.25


Global warming has been widely recognized as a serious problem threatening the future of human beings. It is caused by the buildup in the atmosphere of greenhouse gases, such as carbon dioxide, methane, hydrofluorocarbons (HFCs), and sulfur hexafluoride (SF6). Particularly, SF6 has extremely high global warming potential compare to those of other global warming gases. One option for mitigating this greenhouse gas is the development of an effective process for capturing and separating these gases from anthropogenic sources. In general, gas hydrates can be formed under high pressure and low temperature. However, SF6 gas is known to form hydrate under relatively milder conditions. Therefore, technological and economical effects could be expected for the separation of SF6 gas from waste gas mixtures. In this study, we carried out morphological study for the SF6 hydrate crystals to understand its formation and growth mechanisms. The observations were made in high-pressure optical cell charged with liquid water and SF6 gas at constant pressure and temperature. Initially SF6 hydrate formed at the surface between gas and liquid regions, and then subsequent dendrite crystals grew at the wall above the gas/water interface. The visual observations of crystal nucleation, migration, growth and interference were reported. The detailed growth characteristics of SF6 hydrate crystals were discussed in this study.