• 제목/요약/키워드: Polyimide

검색결과 1,077건 처리시간 0.257초

XPS를 이용한 Cu/Polyimide의 계면에 관한 연구: 고온에서 증착한 Cu의 초기성장과 정(II) (Study on the Cu/Polyimide interface using XPS: Initial growth of Cu sputter-deposited on the polyimide at high temperature (II))

  • 이연승;황정남
    • 한국진공학회지
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    • v.7 no.2
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    • pp.135-140
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    • 1998
  • 고온($350^{\circ}C$)에서 polyimide위에 증착한 Cu의 초기성장 과정과 Cu/polyimide계면에서 의 반응물 형성에 관하여 XPS를 이용하여 관찰하였다. Polyimide 위에 고온 중에서의 Cu 증착시, 상온에서와는 달리 초기에는 Cu-C-N complex가 먼저 형성되고, 다음에 Cu-N-O complex가 주가 되어 Cu/Polyimide 계면을 형성하고, Cu의 증착두께가 증가함에 따라 Cu 산화물에서 서서히 metallic Cu로 성장하는 것을 볼 수 있었다. 그리고 반응물 형성 관점에 서, Cu 고온 증착시에 형성된 Cu/polyimide의 계면이 상온에서 이루어진 계면보다 상당히 예리함을 볼 수 있었다.

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XPS를 이용한 Cu/Polyimide 계면에 관한 연구 : 상온에서 증착한 Cu의 초기성장과정(I) (Study on the Cu/polyimide interface using XPS: Initial growth of Cu sputter-deposited on the polyimide at room temperature (I))

  • 이연승;황정남
    • 한국진공학회지
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    • v.6 no.3
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    • pp.187-193
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    • 1997
  • 상온에서 polyimide 위에 증착한 Cu의 초기성장 과정과 Cu/polyimide의 계면의 형 태에 관하여 XPS를 이용하여 관찰하였다. Polyimide 위에 Cu가 증착됨에 따라, 초기단계에 는 강한 결합의 Cu-N-O complex가 주가 되어 Cu/polyimide 계명을 형성하고, Cu의 증착 두께가 증가함에 따라, 약한 결합의 Cu산화물에서 서서히 metallic Cu로서 성장하는 것을 볼 수 있었다. 이상이 결과들을 통해, Cu/polyimide의 계면은 Cu-N-O complex와 Cu산화물 이 혼합되어 있는 형태이며 polyimide 표면에 가까울수록 Cu-N-O complex가 주가 되고, Cu쪽에 가까울수록 Cu산화물이 주가 되는 형태를 이루고 있다는 것을 알 수 있었다.

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폴리이미드 표면개질과 에폭시접착제 개질을 통한 폴리이미드/에폭시의 접착력 향상 (Improvement of Polyimide/Epoxy Adhesion Strength from the Modification of Polyimide Surface and Epoxy Adhesive)

  • 김성훈;이동우;정경호
    • 한국재료학회지
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    • v.9 no.1
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    • pp.65-72
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    • 1999
  • In order to minimize flexible printed circuit(FPC), which is used in computer, communication, medical facility, aviation space industry, it is required to improve the interfacial adhesion of polymide/epoxy or polyimide/polyimide consists of FPC. In this study, it was considered to improve the adhesion strength of polyimide/epoxy joint by introducing functional group on polyimide film and improving mechanical property of epoxy. Functional group on polyimide film was introduced by changing polyimide film surface to polyamic acid in KOH aqueous solution. The optimum conditions for surface modification were the concentration of 1M KOH and treatment time of 5min. Also, the optimum adhesion strength of polyimide/epoxy joint was obtained using rubber modified epoxy and polyamic acid as a base resin and curing agent of epoxy adhesive, respectively. The degree of surface modification of polyimide film examined with contact angle measurement of FTIR, thus modification of polyimide to polyamic acid was identified. Fracture surface of plymide/epoxy joint was analyzed by scanning electron microscopy, and modified polyamic acid reimidezed to polymide as increasing curing temperature.

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Cu/Ni/Polyimide 시스템의 접착력 및 계면화학반응 (The Adhesion Strength and Interface Chemical Reaction of Cu/Ni/Polyimide System)

  • 최철민;채홍철;김명한
    • 한국재료학회지
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    • v.17 no.12
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    • pp.664-668
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    • 2007
  • The magnetron sputtering was used to deposit Ni buffer layers on the polyimide surfaces to increase the adhesion strength between Cu thin films and polyimide as well as to prevent Cu diffusion into the polyimide. The Ni layer thickness was varied from 100 to $400{\AA}$. The adhesion strength increased rather significantly up to $200{\AA}$ of Ni thickness, however, there was no significant increase in strength over $200{\AA}$. The XPS analysis revealed that Ni thin films could increase the adhesion strength by reacting with the polar C=O bonds on the polyimide surface and also it could prevent Cu diffusion into the polyimide. The Cu/Ni/ polyimide multilayer thin films showed a high stability even at the high heating temperature of $200^{\circ}C$, however, at the temperature of $300^{\circ}C$, Cu diffused through the Ni buffer layer into polyimide, resulting in the drastic decrease in adhesion strength.

크롬/폴리이미드의 접착력에 미치는 폴리이미드 표면의 플라즈마 처리의 효과 (The effects of plasma treatment of polyimide surface on the adhesion of chromium/polyimide)

  • 정태경;김영호;유진
    • 한국표면공학회지
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    • v.26 no.2
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    • pp.71-81
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    • 1993
  • Thed effects of Ar or Oxygen RF plasma treatment on the adhesion behavior of Cr films to polyimide sub-strates have been investigated by using SEM, XRD, AES, and $90^{\circ}$peel test. By applying RF plasma treatment of the polyimide surface prior to metal deposition, the peel adhesion strength of Cu/Cr films sputtered onto the fully cured BPDA-PDA polyimide was highly increased from about 3g/mm to 90 ~ 100g/mm. Improved peel adhesion strength of Cr/polyimide interfaces due to RF plasma treatment was attributed to the contributions from surface cleaning, Cr-polyimide bonding at the interface, and force required for plastic deformation of the film. While the surface topology change of the polyimide caused by RF plasma treatment makes a little contri-bution to the improved adhesion.

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Polyimide 터널 장벽을 이용한 Au/polyimide/유기 단분자막/Pb 구조에서 비탄성 전자 터널링에 관한 연구 (Inelastic Electron Tunneling in Au/polyimide/monolayer Organic Film/Pb Structures using a Polyimide Barrier)

  • 이호식;이원재;장경욱;최명규;이성일;김태완;;이준웅
    • 한국전기전자재료학회논문지
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    • v.17 no.2
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    • pp.196-200
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    • 2004
  • Using polyimide Langmuir-Blodgett(LB) films as a tunneling harrier, we fabricated Au/Polyimide/1-layer arachidic acid/Pb structure in order to investigate electron transport properties through a junction. It was found that 9-layer polyimide LB films function as a good tunneling harrier in a study of current-voltage(I-V) chararteristics. And several peaks originating in the vibrational modes of the constituent molecules of 1-layer arachidic acid LB films were clearly observed in d$^2$V/dI$^2$- V corves.

수직 복합 폴리이미드층에서의 액정 배향 특성 (Liquid Crystal Aligning Capabilities on Homeotropic Blending Polyimide Layer)

  • 황정연;서대식;김재형
    • 한국전기전자재료학회:학술대회논문집
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    • pp.337-340
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    • 2001
  • The control of high pretilt angle for nematic liquid crystal (NLC) with negative dielectric anisotropy on the rubbed blending polyimide (homeotropic and homogeneous alignment) surface were studied. High NLC pretilt angle generated on the blending polyimide (homeotropic polyimide and SE-7492 surface was measured and the NLC pretilt angle increases with blending ratio and rubbing strength. However, the NLC pretilt angle generated on the blending polyimide (homeotropic polyimide and SE-150 surface was not varied. The high pretilt angle the NLC using blending polyimide surface can be achieved.

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Laser ablation을 이용한 폴리이미드 필름 전극제조 및 전기화학적 글루코오즈 바이오센서 응용 (Fabrication of Polyimide Film Electrode by Laser Ablation and Application for Electrochemical Glucose Biosensor)

  • 박덕수
    • 센서학회지
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    • v.22 no.5
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    • pp.357-363
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    • 2013
  • An ultraviolet pulsed laser ablation of polyimide film coated with platinum has been used to enhance the sensitivity for the application as an electrochemical biosensor. Densely packed cones are formed on polyimide surface after UV irradiation which results in increase of surface area. In order to apply the sensitivity improvement of laser ablated polyimide film electrodes, the glucose oxidase modified biosensor was fabricated by using an encapsulation in the gel matrix through sol-gel transition of tetraethoxysliane on the surface of laser ablated polyimide film. The optimum conditions for glucose determination have been characterized with respect to the applied potential and pH. The linear range and detection limit of glucose detection were from 2.0 mM to 18.0 mM and 0.18 mM, respectively. The sensitivity of glucose biosensors fabricated with laser ablated polyimide film is about three times higher than that of plain polyimide film due to increase in surface area by laser ablation.

습식 표면개질 처리된 폴리이미드 필름 표면의 특성에 관한 연구 (A Study on Characteristics of Surface Modified Polyimide Film by Wet Process)

  • 구석본;이홍기
    • 한국표면공학회지
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    • v.39 no.4
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    • pp.166-172
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    • 2006
  • Metallized Polyimide films are extensively used as base materials in microelectronics, optical and automotive applications. However it is difficult to deposit metals on those because of their structural stabilities. In this work, polyimide films are modified by a wet process with alkalinemetalhydroxide and additives to introduce functional groups. The surface molecular structures of polyimide are investigated using X-ray photoelectron spectroscopy(XPS), fourier transform infrared reflection spectroscopy(FTIR-ATR), atomic force micro-scopic(AFM). XPS spectra and FTIR spectra show that the surface structure of polyimide is converted into potassium polyamate. AFM image and AFM cross-sectional analyses reveal the increased roughness on the modified surface of polyimide films. As a result, it is shown that the adhesion strength between polyimide surface and electroless nickel layer is increased by the nano-anchoring effect.

A Study on Electrical and Thermal Properties of Polyimide/MWNT Nanocomposites

  • Park, Soo-Jin;Chae, Sung-Won;Rhee, John-Moon;Kang, Shin-Jae
    • Bulletin of the Korean Chemical Society
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    • v.31 no.8
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    • pp.2279-2282
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    • 2010
  • In this work, the electrical and thermal properties of polyimide/multi-walled carbon nanotube (MWNT) nanocomposites were investigated. The polyimide/MWNT nanocomposites contained from 0 to 2.0 wt % of MWNT. The electrical properties of the polyimide films were characterized by a specific resistance measurement. The thermal properties were evaluated using thermogravimetric analysis (TGA) and a differential scanning calorimeter (DSC). It was found that the thermal properties of the polyimide nanocomposites increased with increasing MWNT content and specific resistance as well. This result indicated that the crosslinking of polyimide/MWNT nanocomposites was enhanced by good distribution of the MWNT in the polyimide resins, resulting in the increase of the electrical and thermal properties of the nanocomposites.