Acknowledgement
Supported by : Basic Science Research
Analytical Science and Technology (분석과학)
- Volume 10 Issue 1
- /
- Pages.9-17
- /
- 1997
- /
- 1225-0163(pISSN)
- /
- 2288-8985(eISSN)
Analysis of Nitrophenols Using Liquid Chromatography/Atmospheric Pressure Chemical Ionization Mass Spectrometry
액체 크로카토그래피-대기압화학이온화법 질량분석기를 이용한 nitrophenol류의 분석
- Hong, Jongki (Korea Basic Science Institute) ;
-
Yoo, Jong Shin
(Korea Basic Science Institute)
;
- Kim, Kang-Jin (Department of Chemistry, Korea University)
- Received : 1996.08.31
- Published : 1997.02.25
Abstract
Nitrophenols are a group of important priority pollutants classified by the US Environmental Protection Agency. Reverse-phase liquid chromatographic method combined with mass spectromethy employing atmospheric pressure chemical ionization(APCI) interface is utilized to determine a mixture of nitrophenols in water matrix without any pretreatment. The sensitivity and selectivity for the identification of different kind of nitrophenols is enhanced by the use of selected ion monitoring and cone voltage fragmentation. The fragmentation patterns of nitrophenols are compared with those obtained from the collision induced dissociation(CID) MS/MS technique.
nitrophenol류는 미국 환경청에서 주요 priority 오염물질로 규정하고 있다. 물 중에 존재하는 nitrophenol류의 혼합물을 분석하기 위해 역상 액체크로마토그래피법에 대기압 화학이온화법을 연결한 질량분석기를 이용하였다. 추가적으로, 선택이온 검색법과 cone 전압차분해법(cone voltage fragmentation)을 이용하여 nitrophenol류의 확인에 있어서 감도와 선택성을 높였다. nitrophenol의 분해 형태는 충돌유발분해법인 MS/MS 기법으로 얻어진 분해 형태와 비교하였다.