Abstract
In an effort to obtain high efficiency in gas fired absorption chillers, a new working fluid has been developed with thc addition of the component of $LiNO_3$, LiCl and LiI to the conventional solution of $LiBr-H_2O$. The solubility and vapor pressure of the 4 component working fluid developed in this work were measured and compared to the results of $LiBr-H_2O$ solution. It was observed that there exists an optimal mole ratio of the inorganic salts in terms of solubility. The mole ratio of LiBr, $LiNO_3$ and LiCl was found to be around 5:1:1~2 in the $LiBr-LiNO_3-LiCl-H_2O$ mixture, and in the case of $LiBr-LiO_3-Lil-H_2O$ and $LiBr-Lil-LiCl-H_2O$ mixtures, the mole ratio of LiBr, $LiNO_3$ and Lil/ LiBr, LiI and LiCl were found to be around 5:1:1 and 5:1:0.5~1 respectively. The vapor pressure of the 4 component working fluid of the optimal mole ratio was increascd with adding the component of $LiNO_3$, LiCl and LiI except for $LiBr-LiNO_3-LiCl-H_2O$ mixture. The absorption capacity of $LiBr-LiNO_3-LiCl-H_2O$ mixture was obtained higher than that of $LiBr-H_2O$ mixture.
고효율 가스흡수식 냉방기를 위한 신 작동매체로 기존의 $LiBr-H_2O$ 용액에 $LiNO_3$, LiCl, LiI 성분을 첨가하여 4성분 용액을 제조하였다. 본 연구를 통하여 제조된 4성분계의 작동매체에 대한 용해도와 증기압을 측정하여 기존의 $LiBr-H_2O$계와 비교 분석하였으며, 이들에 대한 최적혼합 몰비를 각각 구하였다. 용해도 측면에서 $LiBr-LiNO_3-LiCl$계는 5:1:1~2, $LiBr-LiNO_3-LiCl$계는 5:1:1, LiBr-LiI-LiCl계의 경우 5:1:0.5~1로 나타났다. 한편 $LiBr-LiNO_3-LiCl-H_2O$계를 제외하고 모두 증기압이 $LiBr-H_2O$계에 비해 높게 나타났다. $LiBr-LiNO_3-LiCl-H_2O$계를 이용한 흡수성능 실험시 $LiBr-H_2O$계 보다 우수한 특성을 지녔다.
