Journal of Photoscience

Korean Society of Photoscience (한국광과학회)
권호 표지

Photochromism of A Styrene-Derived Polymer Having Pendant Phenoxyanthraquinones

  • Ju, Sang-Yong (Functional Polymer Laboratory, Korea Instituteof Science and Technology) ;
  • Ahn, Kwang-Duk (Functional Polymer Laboratory, Korea Instituteof Science and Technology) ;
  • Han, Dong-Keun (Functional Polymer Laboratory, Korea Instituteof Science and Technology) ;
  • Suh, Dong-Hack (Division of Chemical Engineering, Center for Ultra-microchemical Process Systems,Hanyang University) ;
  • Kim, Jong-Man (Division of Chemical Engineering, Center for Ultra-microchemical Process Systems,Hanyang University)
  • Published : 2000.12.01
Download PDF
⟨ Previous Next ⟩

Abstract

A Styrene-derived polymer having pendent phenoxyanthraquinones for photochromism was prepared by AIBN-initiated radical polymerization. Syntgesus of the monomers was straightforward and the polymer was obtained in 65% yield. Photoinduced rearrangement from the “trans” quinone forms to the “ana” quinone forms readily occurred both in solution and in film when the polymer was irradiated with UV light.

Keywords

References

  1. Macromolecules v.26 Synthesis of new photochromic polymers based on hyenoxy-naphthacenequinone Buchholtz;F.;A.Zelichenok;V.Krongauz
  2. J.Am.Chem.Soc. v.121 Photochemical imprint of molecular recognition sites in monolayers assembled on Au electrodes Lahav;M.;E.Katz;A.Doron;F.Patolsky;I.Willner
  3. Chem.Lett. Photochromic properties of thermally irreversible 6-aryloxy-5,12-naphthacenequinones Yokohama;Y.;S.Fukui;Y.Yokohama
  4. J.Photochem.Photobiol.A:Chem. v.70 Photochromism of quinoid compounds:properties of photo-induced anaquinones. Gritsan;N.P.;L.S.Klimemko
  5. Macromolecules Synthesis of norbornene-derived polymers having pendant phenoxyquinones for photochromism Kim;J.M.;H.Y.Shin;K.H.Park;T.H.Kim;S.Y.Ju;D.K.Han;K.D.Ahn
  6. Angew.Chem.Int.Ed. v.39 Photoacid-induced fluorescence quenching:a new strategy for fluorescent inaging in polymer films Kim;J.M.;T.E.Chang;J.H.Kang;K.H.Park;D.K.Han;K.D.Ahn
  7. Adv.Mater. v.11 Synthesis of and fluorescent inaging with a polymer having t-BOC-protected quinizarin moieties Kim;J.M.;T.E.Chang;J.H.Kang;D.K.Han;K.D.Ahn
  8. Chem.Mater. v.10 A novel precursor for color and fluorescence imaging Kim;J.M.;J.H.Kang;D.K.Han;C.W.Lee;K.D.Ahn
  9. Chem.Lett. Generation of patterned color images in polymer film with photogenerated base. Kim;J.M.;T.E.Chang;R.H.Park;D.J.kim;D.K.Han;K.D.Ahn
  10. Chem.Lett. Color and Fluorescence imaging with t-Boc-protected dihydroxynaphthacenedione Kim;J.M.;J.Y.Kim;T.H.Kim;D.K.Han;K.D.Ahn