Analytical Science and Technology (분석과학)

The Korean Society of Analytical Sciences (한국분석과학회)
권호 표지
DOI QR코드

DOI QR Code

A Study on the Acid Digestion Bomb Pretreatment Method of Fire Retardant Chemicals (DBDPE-$Sb_2O_3$) for the Determination of Antimony

DBDPE-$Sb_2O_3$ 중 Sb를 분석하기 위한 가압 산분해 전처리 연구

  • Choi, Jong-Keum (Advanced Analysis Center, Korea Institute of Science and Technology) ;
  • Park, Je-An (Advanced Analysis Center, Korea Institute of Science and Technology) ;
  • Park, Kyung-Su (Advanced Analysis Center, Korea Institute of Science and Technology) ;
  • Kim, Sun-Tae (Advanced Analysis Center, Korea Institute of Science and Technology) ;
  • Kim, Young-Sang (Department of Chemistry, Korea University)
  • 최종금 (한국과학기술연구원 특성분석센터) ;
  • 박제안 (한국과학기술연구원 특성분석센터) ;
  • 박경수 (한국과학기술연구원 특성분석센터) ;
  • 김선태 (한국과학기술연구원 특성분석센터) ;
  • 김영상 (고려대학교 화학과)
  • Received : 2000.09.25
  • Published : 2000.12.25
Download PDF
⟨ Previous Next ⟩

Abstract

The acid digestion bomb pretreatment method for the determination of antimony in a commercial fire retardant material sample (DBDPE-$Sb_2O_3$) was studied. DBDPE-$Sb_2O_3$ sample was digested with $H_2SO_4:HCl$(1:2) mixture in digestion bomb at $220^{\circ}C$ for 2 hrs. and antimony was determined by atomic absorption spectrophotometry. Recovery of 99.6-99.8% and C.V. of 0.94-1.07% for Sb was obtained for spiked real samples. In the present method, the analytical results obtained for antimony were 40.3 and 36.3% (w/w), respectively.

상용되는 난연제인 DBDPE-$Sb_2O_3$ 중 안티몬을 신속 정확하게 분석하기 위하여 가압 산 분해법을 이용하여 전처리하였다. DBDPE-$Sb_2O_3$ 시료를 가압 산 분해장치 내에서 $H_2SO_4:HCl$(1:2) 혼합산을 가하여 $220^{\circ}C$에서 2시간 동안 분해시킨 후 AAS를 이용하여 Sb를 정량하였다. 그 결과 99.6-99.8%의 회수율과 0.94-1.07%의 변동계수값을 얻었다. 이 전처리 방법을 실제시료에 적용하여 40.3과 36.3%의 Sb 함량을 구할 수 있었다.

Keywords

References

  1. Plastics Compounding v.71 M. R. Christy
  2. 한국소방학회지 v.9 손연수;김진규
  3. J. Anal. Chem. v.358 A. Golloch;D. Siegmund, Fresenius'