Journal of Photoscience

Korean Society of Photoscience (한국광과학회)
권호 표지

Formation and Properties of Enyne Radical Cation

  • Kim, Bang-Duk (Department of Chemistry, School of Molecular Science-BK21, Korea Advanced Institute of Science and Technology) ;
  • Shim, Sang-Chul (Department of Chemistry, School of Molecular Science-BK21, Korea Advanced Institute of Science and Technology) ;
  • Noboyuki Ichinose (The Institute of Scientific and Industrial Research, Osaka University) ;
  • Sachiko Tojo (The Institute of Scientific and Industrial Research, Osaka University) ;
  • Tetsuro Majima (The Institute of Scientific and Industrial Research, Osaka University)
  • Published : 2001.06.01
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Abstract

Radical cations of DPBEY and PPCB were generated by ${\gamma}$-radiolysis and pulse radiolysis in halogenated solvents. The radical cation PPCB+ shows 505 (shoulder) and 520 nm absorption peaks with 700 ns lifetime in agreement with the laser flash photolysis work and strongly support the exciplex mechanism proposed for the photoreaction of PPCB and dimethylfumarate.

Keywords

References

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