Journal of Photoscience

Korean Society of Photoscience (한국광과학회)
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Photochemical Reactions of Some Carbonyl Compounds with N, Nv-Dimethylaniline: Formation of $\beta- and \gamma-Hydroxynmines$

  • Kim, Sung-Sik (Department of Chemistry, Chonbuk National University) ;
  • Change, Ji-Ae (Department of Chemistry, Chonbuk National University) ;
  • Mah, Yoon-Jung (Department of Chemistry, Chonbuk National University)
  • Published : 2002.03.01
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Abstract

Direct irradiation of carbonyl compounds such as some aldehydes, ketones and anthraquinone in N,N-dimethylamiline(DMA), without using other solvents, gave $\beta$-hydroxyamines as the major products. Irradiation of anthrone and DMA in methanol afforded ${\gamma}$-hydroxyamine. The structure of the photoproduct was confirmed by treatment with an acid to give a bicyclic compound.

Keywords

References

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