A Study on the Zeta Potential Measurement and the Stability Analysis of Nano Fluids using a Particle Image Processing System

입자 영상 처리 시스템을 이용한 콜로이드 입자의 제타포텐셜 측정 및 나노유체 분산 특성 연구

  • 이재근 (부산대학교 기계공학과) ;
  • 김성찬 (부산대학교 기계공학과) ;
  • 김희중 (세방전지㈜ 중앙전지기술연구소) ;
  • 이창건 (부산대학교 기계공학과) ;
  • 주찬홍 (세방전지㈜ 중앙전지기술연구소) ;
  • 이래철 (세방전지㈜ 중앙전지기술연구소)
  • Published : 2003.03.31

Abstract

Zeta potential measurements of colloid particles suspended in a liquid are performed by a Zeta Meter developed. There are many applications of colloid stability in spray technology, paints, wastewater treatment, and pharmaceuticalse. Zeta potentials of charged particles are obtained by measuring the electrophoretic velocities of the particles using video enhanced microscopy and image analysis program. The values of zeta potential of polystyrene latex(PSL), $silica(SiO_2)$M, polyvinylidence difluoride(PVDF), silicon nitride, and alumina particles in deionized (DI) water were measured to be -40.5, -31.9, -25.2, -15.1 and -10.1mV, respectively. The particles having high zeta potential less than -20 mV are stable in DI water, because the double layers of them have strong repulsive forces mutually, and the particles having low zeta potential over -20mV are unstable due to Van Der Waals forces. Silica(>20nm), PSL, aluminum and PVDF particles were found to be stable that would remain separate and well disperse, while silicon nitride and alumina particles were found to be unstable that would gradually agglomerate in DI water.

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