Analytical Science and Technology (분석과학)

The Korean Society of Analytical Sciences (한국분석과학회)
권호 표지

Inclusion Selectivity of the Cyanocadmate Host Complex with Piperazine Ligand for Aromatic Guest Molecules; Benzene, Toluene, Ethylbenzene and Xylene Isomers

Piperazine 리간드를 가진 시아노카드뮴 호스트 착물의 방향족 게스트 분자에 대한 포접선택성

  • Kim, Chong-Hyeak (Chemical Analysis Laboratory, Korea Research Institute of Chemical Technology) ;
  • Lee, Sueg-Geun (Chemical Analysis Laboratory, Korea Research Institute of Chemical Technology)
  • Received : 2003.07.02
  • Accepted : 2003.08.05
  • Published : 2003.08.25
Download PDF
⟨ Previous Next ⟩

Abstract

Inclusion selectivity of a three-dimensional piperazine-ligated cyanocadmate host complex, $[Cd_x(CN)_{2x}\{HN(CH_2CH_2)_2NH\}_y]{\cdot}zG$, has been investigated for benzene (B), toluene (T), ethylbenzene (E), o- (O), m- (M), and p-xylene (P) isomers as the aromatic guest molecules. From the binary, ternary and quarternary guest mixtures of E and xylene isomer (X), the order of inclusion selectivity in the host complex is O>E>P>M. From the binary to quinary BTX mixtures, the order of preference in the complex is seen to be B>T>O${\gg}$P>M.

Keywords

References

  1. J. M. Lehn, 'Perspectives in Coordination Chemistry', pp. 447-462, A. F. Williams, C. Floriani, A. E. Merbach, Eds., VCM, New York, 1992.
  2. J. L. Atwood, J. E. D. Davies and D. D. MacNicol, 'Inclusion Compounds', Vol. 1-3, Academic Press, London, 1984.
  3. J. L. Atwood, J. E. D. Davies and D. D. MacNicol, 'Inclusion Compounds', Vol. 4-5, Oxford University Press, Oxford, 1991.
  4. T. Kitazawa, S. Nishikiori, R. Kuroda and T. Iwamoto, J. Chem. Soc., Dalton Trans., 1029 (1994).
  5. T. Kitazawa, S. Nishikiori and T. Iwamoto, Materials Science Forum, 91-93, 257 (1992).
  6. T. Kitazawa, S. Nishikiori and T. Iwamoto, J. Chem. Soc., Dalton Trans., 3695 (1994).
  7. A. Clearfield, Chem. Rev., 88, 125 (1988).
  8. S. L. Suib, Chem. Rev., 93, 803 (1993).
  9. C. H. Kim, S. Nishikiori and T. Iwamoto, Chem. Lett., 409 (1995).
  10. C. H. Kim, S. Nishikiori and T. Iwamoto, Mol. Cryst. Liq. Cryst., 276, 13 (1996). https://doi.org/10.1080/10587259608039354
  11. G. Boxhoorn, J. Moolhuysen, J. G. F. Coolegem and R. A. van Santen, J. Chem. Soc., Chem. Commun., 1305 (1985).
  12. P. Cartraud, A. Cointot and A. Renaud, J. Chem. Soc., Faraday Trans., 77, 1561 (1981).
  13. M. J. Minton and N. O. Smith, J. Phys. Chem., 71, 3618 (1967).
  14. H. L. Wiener, L. Ilardi, P. Liberati, L. Dengler, S. A. Jeffas, S. Saba, and N. O. Smith, J. Incl. Phenom., 4, 415 (1986).
  15. C. H. Kim, Ph.D. Thesis, The University of Tokyo, Japan, 1996.