Applied Chemistry for Engineering (공업화학)

The Korean Society of Industrial and Engineering Chemistry (한국공업화학회)
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The Preparation and Properties of Petroleum Sulfonate Dispersant

열분해 잔유를 원료로 한 분산제의 제조 및 특성

  • Choi, Sang-Won (Department of Chemical System Engineering, Chonnam National University) ;
  • Kim, Eun-Young (Department of Chemical System Engineering, Chonnam National University) ;
  • Chang, Woo-Seok (Department of Chemical System Engineering, Chonnam National University) ;
  • Kim, Viktor (Department of Chemical System Engineering, Chonnam National University) ;
  • Moon, Jang-Soo (KIEST)
  • 최상원 (전남대학교 공학대학 화학시스템 공학 전공) ;
  • 김은영 (전남대학교 공학대학 화학시스템 공학 전공) ;
  • 장우석 (전남대학교 공학대학 화학시스템 공학 전공) ;
  • 김빅토르 (전남대학교 공학대학 화학시스템 공학 전공) ;
  • 문장수 (한국환경기술진흥원)
  • Received : 2007.07.12
  • Accepted : 2007.08.04
  • Published : 2007.10.10
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Abstract

Dispersants were prepared from petroleum pyrolysis residual oil (PPRO) through sulfonation. Without employing a conventional polynaphthalene sulfonate formaldehyde condensate (PNS) process, the dispersants (NPS) were synthesized by a simpler process only in 2 h. The chemical structure of new dispersant, which has various naphthalene derivative groups, was similar to PNS conformed by UV-visible spectroscopy curves. The new dispersants demonstrated high dispersing ability in inorganic suspension ; cement, $Fe_2O_3$, and $CaCO_3$.

올레핀 제조를 위한 열분해공정에서의 잔유(PPRO)를 원료로 황산화 반응을 통하여, polynaphthalene sulfonate formaldehyde condensate (PNS) 반응 공정에 비하여 좀더 단순한 공정으로 2 h 이내의 반응시간에도 우수한 성능의 무기물 분산용 분산제(NPS)를 제조 하였다. 합성한 분산제의 자외선 흡수 곡선은 PNS와 비슷하여 다양한 나프탈렌 유도체의 구조임을 알 수 있었다. NPS는 시멘트, 산화철 및 탄산칼슘 등 무기입자들의 분산계에 이용할 수 있는 우수한 성능을 나타내었다.

Keywords

Acknowledgement

Supported by : 환경진흥원

References

  1. Gang-Soon Lee, New Surfactant, Se Hwa, 435 (1994)
  2. A. Eckard, I. Riff, and J. Weaver, Formulation of soluble oils with synthetic and petroleum sulfonation, J. Soc. Trbol. & Lub. Eng., 17-22 (1997)
  3. V. P. Lesnyak, L. V. Gaponik, V. P. Mardykin, and F. N. Kaputskii, Gel filteration chromatography of pertoleum sulfonates, Russ. J. App. Chem., 76, 1870 (2003) https://doi.org/10.1023/B:RJAC.0000018705.50124.62
  4. E. Ogata, N. Yanase, and T. Kitahara, Sulfonating agent and sulfonation process, US PAT 5,596,128 (1997)
  5. Green shield & Herbert peterge, Dispersant and it used dispersion, KR PAT 2000-7000768 (2003)
  6. W. L. Ng, G. H. Neale, and V. Hornof, Physicochemical behavior of mixed surfactant systems : petroleum sulfonate and lignosulfonates, J. App. Polm. Sci., 88, 860 (2003) https://doi.org/10.1002/app.11662
  7. H. Y. Wang, M. Y. Li, Z. L. Wu, and M. Q. Lin, Effect of petrileum sulphonate on interfacial property and stability of crude oil emulsion, Chin. J. Chem. Eng., 13, 691-695 (2005)
  8. S. Suzyki, A. Yamauchi, S. Kiyama, and K. Yamaki, Method for preparing dispersing agent, US PAT 3,970,690 (1976)
  9. S. W. Choi, N. H. Oh, O. Y. Kwon, H. J. Seo, and Y. B. Kwon, The preparation of and application of dispersants from waste phenolic liquid and pyrolysis residue oil, J. Korea Solid Waste Eng. Soc., 14, 1666 (1997)
  10. R. Brudckmann, W. Bury, J. P. Dix, M. Herrmann, W. Dlugosch, E. Kromm, H. Letter, N. Zimmermann, W. Kermer, and K. Taeger, Dye dispersants: aryl sulphonic acid-formaldehyde condensate or ligninsulfonate, US PAT 5,186,846 (1993)
  11. J. S. Rho, H. Y. Cho, and S. S. Hong, Research trend and subject of cement concrete surfactants, Chem. Ind. & Tec., 12, 397 (1994)
  12. J. M. Lee, J. C. Ko, B. S. Kim, and M. W. Han, Continuous manufacturing method that new manufacture system with aromatic sulfuric acid, KR PAT 1993-0014239 (1993)
  13. Sami Matar, Kerosens Chemistry Curriculum, Intervision 41 (2000)
  14. Y. Stephen and L. L. Bush, Process for graftig lignin with vinylic monomers using separate streams of initiator and monomer, US PAT 4,891,415 (1990)
  15. Z. Rui and P. Sonmasundaran, Advances in adsorption of surfactants and their mixtures at solide/solution interfaces, Adv. in Colloidal Interface Sci., 303, 213 (2006)
  16. Z. Adamczyk, M. Zembala, and A. Michna, Polyelectrolyte adsorption layers studided by streamig potential and particle deposition, J. Colloid & Interface Sci., 303, 353 (2006) https://doi.org/10.1016/j.jcis.2006.07.083
  17. L. Zhang, P. Sonmasundaran, and C. Maltesh, Adsorption of n-Dodecyl-$\beta$-D-maltoside on solides, J. Colloid & Interface Sci., 191, 202 (1997)
  18. M. Matsui, Effect of the salt in adsorption behavior of high reducing agent, Cement & Concrete, 43, 90 (1989)
  19. R. M. Silverstein, G. C. Bassler, and T. C. Morrill, Spectromertic indetification of organic compounds, 4th ed., John willey & Sons, INC, 289 (1991)