Corrosion Behavior of Nickel-Plated Alloy 600 in High Temperature Water

  • Kim, Ji Hyun (HH Uhlig Corrosion Lab, Massachusetts Institute of Technology) ;
  • Hwang, Il Soon (Department of Nuclear Engineering, Seoul National University)
  • Published : 2008.02.01

Abstract

In this paper, electrochemical and microstructural characteristics of nickel-plated Alloy 600 were investigated in order to identify the performance of electroless Ni-plating on Alloy 600 in high-temperature aqueous condition with the comparison of electrolytic nickel-plating. For high temperature corrosion test of nickel-plated Alloy 600, specimens were exposed for 770 hours to typical PWR primary water condition. During the test, open circuit potentials (OCP's) of all specimens were measured using a reference electrode. Also, resistance to flow accelerated corrosion (FAC) test was examined in order to check the durability of plated layers in high-velocity flow environment at high temperature. After exposures to high flow rate aqueous condition, the integrity of surfaces was confirmed by using both scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS). For the field application, a remote process for electroless nickel-plating was demonstrated using a plate specimen with narrow gap on a laboratory scale. Finally, a practical seal design was suggested for more convenient application.

Keywords

References

  1. J.M Gras, Parkins Symposium on Fundamentals Aspects of Stress Corrosion Cracking, p. 411, TMS, Metals Park, OH (1992)
  2. S. Fyfitch, Proceedings of Conference on Vessel Head Penetration Inspection, Cracking and Repairs, p. 493, US NRC, Gaithersburg, MD (2003)
  3. D.B. Darling and J.A. Richards, Nuclear Plant Journal, 12, 34 (1994)
  4. J.K. Dennis, T.E. Such, Nickel and chromium plating, third ed., ASM International, OH (1993)
  5. S.H. Oh, M.S. Thesis, Seoul National University, 2002
  6. G. Lu, G. Zangari, Electrochimica Acta, 47, 2969 (2002) https://doi.org/10.1016/S0013-4686(02)00198-6
  7. S.H. Park and D.N. Lee, J. Mater. Sci., 23, 1643 (1988) https://doi.org/10.1007/BF01115703
  8. N.R. Sorensen and R.B. Diegle, Metals Handbook, 9th Ed., Corrosion, vol. 13, p. 864, ASM, Metals Park, OH (1987)
  9. Z. Yu and R.M. Latanision, Corros. Sci., 34, 1697 (1993) https://doi.org/10.1016/0010-938X(93)90041-E