Toxicological Research

Korean Society of Toxicology & Korea Environmental Mutagen Society (한국독성학회)
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Analysis of Lead Ions in a Waste Solution Using Infrared Photo-Diode Electrode

  • Ly, Suw-Young (Biosensor Research Institute in Seoul National University of Technology) ;
  • Lee, Hyun-Kuy (Biosensor Research Institute in Seoul National University of Technology) ;
  • Kwak, Kyu-Ju (Department of Chemistry, Yonsei University) ;
  • Ko, Jun-Seok (Advanced Scientific Experiment Group in DaeJin High School) ;
  • Lee, Jeong-Jae (Advanced Scientific Experiment Group in DaeJin High School) ;
  • Cho, Jin-Hee (Advanced Scientific Experiment Group in DaeJin High School) ;
  • Kim, Ki-Hong (Advanced Scientific Experiment Group in DaeJin High School) ;
  • Kim, Min-Seok (Advanced Scientific Experiment Group in DaeJin High School) ;
  • Lee, So-Jung (The Science Group in CheongWon Women's High School)
  • Published : 2008.09.01
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Abstract

To detect lead ions using electrochemical voltammetric analysis, Infrared Photo-Diode Electrode(IPDE) was applied via cyclic and square wave stripping voltammetry. Lead ions were deposited at 0.5 V(versus Ag/AgCl) accumulation potential. Instrumental measurements systems were made based on a simple and compact detection system. The stripping voltammetric and cyclic voltammetric optimal parameters were searched. The results yielded a cyclic range of $40{\sim}240mgl^{-1}$ Pb(II) and a square wave stripping working range of $0.5{\sim}5.00mgl^{-1}$ Pb(II). The relative standard deviation at 2 and 4 $mgl^{-1}$ Pb(II) was 0.04% and 0.02%(n=15), respectively, using the stripping voltammetric conditions. The detection limit was found to be 0.05 $mgl^{-1}$ with a 40 sec preconcentration time. Analytical interference ions were also evaluated. The proposed method was applied to determine lead ions in various samples.

Keywords

References

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