DOI QR코드

DOI QR Code

Interaction of industrial effluents and bentonite: a comparative study of their physico-chemical and geotechnical characteristics

  • Murugaiyan, V. (Department of Civil Engineering, Pondicherry Engineering College) ;
  • Saravanane, R. (Department of Civil Engineering, Pondicherry Engineering College) ;
  • Sundararajan, T. (Department of Civil Engineering, Pondicherry Engineering College)
  • Received : 2009.04.16
  • Accepted : 2009.10.06
  • Published : 2009.12.25

Abstract

One-dimensional soil-column studies were carried out to understand the interaction of three industrial effluents namely amino acid ('highly acidic'), surfactant ('highly organic') and pharmaceutical ('organic and toxic') on the physicochemical behavior, index properties and shear strength of bentonite due to artificial contamination extending to nearly 300 days. Changes in inorganic and organic pollutants present in the effluents due to the interaction of the above effluents and soil were assessed to understand the physico-chemical behaviour. Batch and continuous modes of operation, 8 hrs and 16 hrs Hydraulic Retention Time [HRT] and 25%, 50% concentrations of effluents, were the parameters considered. Amino acid, surfactant and pharmaceutical effluents have shown a high variation in pH (7 to 8) after artificial contamination on bentonite that is their original characteristics of the above effluents have been completely reversed. Further, it is found that the shear strength of bentonite has reduced by about 20%, and with respect to liquid limit and plastic limit shows an increasing trend with time within the period of contamination.

Keywords

References

  1. APHA (2005), Standard Methods for the Examination of Water and Waste Water, 21st Edition, American Public Health Association, Washington, DC.
  2. Badv, K. and Kerry Rowe, R. (1996), "Contaminant transport though a soil liner underlain by an unsaturated stone collection layer", Can. J. Geotech. Eng., 33, 416-430 . https://doi.org/10.1139/t96-063
  3. Chu, W. (2003), "Remediation of Contaminated Soils by Surfactant-Aided Soil-Washing", Pract. Periodical Haz. Toxic Radioactive Waste Mgmt., 7(1), 19-24. https://doi.org/10.1061/(ASCE)1090-025X(2003)7:1(19)
  4. Deane, G., Chroneer, Z. and Lick, W. (1999), "Diffusion and sorption of hexachlorobenzene in sediments and saturated soils", J. Environ. Eng., 125, 689-696. https://doi.org/10.1061/(ASCE)0733-9372(1999)125:8(689)
  5. Fang, H. Y. (1986), "Introductory Remarks on Environmental Geotechnology", Proceedings of the 1st International Symposium on Environmental Geotechnology, Bethlehem.
  6. Gallipol, D. Wheeler, S.J. and Karstunen, M. (2003), "Modelling the variation of degree of saturation in a deformable unsaturated soil", Geotechnique, 53(1), 105-112. https://doi.org/10.1680/geot.2003.53.1.105
  7. IS: 2720 Part 4 (1985), "Methods of Test for Soils Part-4 Grain Size Analysis", BIS, New Delhi, India.
  8. Kamon, M., Inazumi, S., Rajasekaran, G. and Kastsumi, J. (2002), "Evaluation of waste sludge compatibility for landfill cover application", J. Japanese Geotech. Soc-soils Found., 42(4), 13-27. https://doi.org/10.3208/sandf.42.4_13
  9. Khan, S.U., Shafiullah, and Khan, J.A. (1999), "Mobility of amino acids through soils amended with some pesticides", Indian J. Environ. Health, 41(2), 83-89.
  10. Murugaiyan, V., Saravanane, R., Sundarajan, T. and Stalin, V.K. (2005a), "Effect of Industrial Effluent on Physico-Chemical and Index properties of Fine grained Soil", Proceedings of All India Seminar on Advances in Geotechnical Engineering (AGTE-2005), National Institute of Technology, Rourkela, January.
  11. Murugaiyan, V., Saravanane, R., Sundarajan, T. and Stalin, V.K. (2005b), "Characterisation and effect of Industrial Effluent on Clayey Soil", Proceedings of All India Seminar on Advances in Geotechnical Engineering (AGTE-2005), National Institute of Technology, Rourkela, January.
  12. Murugaiyan, V., Saravanane, R. and Sundararajan, T. (2008), "Effect of Acid Effluent on the Characterization and Physio-Chemical Behaviour of Clayey and Sandy Soil", Proceedings of GeoCongress 2008: Geotechnics of Waste Management and Remediation, New Orleans, March.
  13. Murugaiyan, V., Saravanane, R. and Sundararajan, T. (2004), "Effect of industrial effluent on Characterization and Remediations of Clayey-silty soil site by Physio-chemical and Strength behaviour Assessment", Proceedings of 7th International Symposium on Environmental Geotechnology and Global Sustainable Developemnt, Helsinki and Espoo, June.
  14. Miura, N., Ghai, J., Hino, T. and Shimoyama, S. (1998), "Depositional Environment and Geotechnical Properties of Soft Deposit in Saga Plain", Indian Geotech. J., 28(2), 121-145.
  15. Peirce, J.J., Sallfors, G., Peel, T.A. and Witter, K.A. (1987), "Effects of selected inorganic leachates on clay permeability", J. Geotech. Eng., 113(8), 915-922. https://doi.org/10.1061/(ASCE)0733-9410(1987)113:8(915)
  16. Fox, P. and Drewes, J.E. (1999), "Behavior and Characterization of residual organic compounds in wastewater used for indirect potable reuse", Water Sci. Technol., 40(4-5), 391-398. https://doi.org/10.1016/S0273-1223(99)00522-3
  17. Ruhl, J.L. and Daniel, D.E. (1997), "Geosynthetic clay liners permeated with chemical solutions and leachates", J. Geotech. Geoenviron. Eng., 123(5), 438-445. https://doi.org/10.1061/(ASCE)1090-0241(1997)123:5(438)
  18. Sharma, R.S. and Mohamed, M.H.A. (2003), "Patterns and mechanism of light non-aqueous phase liquid in an unsaturated sand" Geotechnique, 133(3), 225-239.
  19. Sivapullaiah, P.V., Sridharan, A. and Ramesh, H.N. (1995), "Mechanism controlling the index properties of lime treated black cotton soil in the presence of sulphate", Indian Geotech. J., 25(3), 379-394.
  20. Soule, N.M. and Burns, S.E. (2001), "Effects of organic cation structure on behaviour of organobentonites", J. Geotech. Geoenviron. Eng., 127(4), 363-370. https://doi.org/10.1061/(ASCE)1090-0241(2001)127:4(363)
  21. Sridharan, A. and Venkatappa Rao, G. (1979), "Shear strength behaviour of saturated clays and the role of effective stress concept", Geotechnique, 29(2), 177-193. https://doi.org/10.1680/geot.1979.29.2.177
  22. Sridharan, A. (1990), "Engineering behaviour of soils-A fundamental approach", Indian Geotechnical Society's 13th Annual Lecture, Bombay.
  23. Stren, R.T. and Shackelford, C.D. (1998), "Permeation of sand-processed clay mixtures with calcium chloride solutions", J. Geotech. Geoenviron. Eng., 124(3), 231-241. https://doi.org/10.1061/(ASCE)1090-0241(1998)124:3(231)
  24. Wosten, J.H.M. and van Genuchten, M.T. (1988), "Using texture and other soil properties to predict the unsaturated soil hydraulic functions", Soil Sci. Soc. Am. J., 52(1).