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Solvothermal synthesis and characterization of silver nanoparticles

  • Guptha, K. Venkateswara (Department of Chemistry, School of Science and Humanities, Karunya University (Karunya Institute of Technology and Sciences)) ;
  • Nesaraj, A. Samson (Department of Chemistry, School of Science and Humanities, Karunya University (Karunya Institute of Technology and Sciences))
  • Received : 2012.09.12
  • Accepted : 2014.09.23
  • Published : 2014.09.25

Abstract

Among the various nanoparticles reported for commercial applications, considerable interest has been generated by the use of silver nanoparticles. Owning to extremely small size, silver nanoparticles exhibit enhanced properties when compared with the bulk material. In this research work, silver nanoparticles were prepared by the reduction of silver salt with a reducing agent by a solvothermal method using different solvent mediums such as ethanol, hexane, toluene and acetone with water. The prepared silver nanoparticles were characterized systematically by X-ray diffraction (XRD), particle size analysis and scanning electron microscope (SEM). The results revealed the formation of pure silver phase and nano-sized particles. Among the different solvent mediums used, the silver nanoparticles prepared by hexane and water as solvent mixture resulted in very low particle size.

Keywords

References

  1. An, J., Zhang, M., Wang, S. and Tang, J. (2008), "Physical, chemical and microbiological changes in stored green asparagus spears as affected by coating of silver nanoparticles-PVP", LWT-Food Sci. Tech., 41, 1100-1107. https://doi.org/10.1016/j.lwt.2007.06.019
  2. Berger, T.J., Spadaro, J.A., Chapin, S.E. and Becker, R.O. (1976), "Electrically generated silver ions: quantitative effects on bacterial and mammalian cells", Antimicrob. Agents. Chemother., 9, 357-358. https://doi.org/10.1128/AAC.9.2.357
  3. Christian, K., Radian, P., Erich, M., Dagmar, G. and Claus, F. (2010), "Microemulsion-based synthesis of nanoscaled silver hollow spheres and direct comparison with massive particles of similar size", Nanoscale, 2, 2223-2229. https://doi.org/10.1039/c0nr00291g
  4. Dhermendra, K.T. and Behari, J. (2009), "Biocidal nature of combined treatment of Ag-nanoparticle and ultrasonic irradiation in Escherichia coli dh5", Adv. Biolog. Res., 3-4, 89-95.
  5. Ganesh Babu, M. and Gunasekaran, P. (2009), "Production and structural characterization of crystalline silver nanoparticles from Bacillus cereus isolate", Coll. Surf. B: Biointerf., 74, 191-195. https://doi.org/10.1016/j.colsurfb.2009.07.016
  6. Heng, M., Wand, Z.S. and Zhu, Y.W. (2006), "Preparation of silver nanoparticle via active template under ultrasonic", Tran. Non Ferr. Met. Soc. China, 16, 1348-1352. https://doi.org/10.1016/S1003-6326(07)60018-1
  7. Jiang, G.H., Wang, L., Chen, T., Yu, H.J. and Wang, J.J. (2005), "Preparation and characterization of dendritic silver nanoparticles", J. Mater. Sci., 40, 1681-1683. https://doi.org/10.1007/s10853-005-0669-9
  8. Garcia-Barrasa, J., Lopez-de-Luzuriaga, J.M. and Monge, M. (2010), "Silver nanoparticles: synthesis through chemical methods in solution and biomedical applications", Centr. Euro. J. Chem., 9, 7-19.
  9. Guzman, M.G., Dille, J. and Godet, S. (2009), "Synthesis of silver nanoparticles by chemical reduction method and their antibacterial activity", Int. J. Chem. Biomol. Eng., 2, 104-111.
  10. Guardia, P., Prez, N., Labarta, A. and Batlle, X. (2010), "Controlled synthesis of iron oxide nanoparticles over a wide size range", Langmuir, 26, 5843-5847. https://doi.org/10.1021/la903767e
  11. Kim, T.H., Kim, K., Park, G.H., Choi, J.H., Lee, S., Kang, H.J., Lee, J.Y. and Kim, J. (2009), "Preparation and characterization of water-dispersible silver nanoparticles stabilized by PEO-conjugated pro-drugs", Macromol. Res., 17, 770-775. https://doi.org/10.1007/BF03218613
  12. Mazur, M. (2004), "Electrochemically prepared silver nanoflakes and nanowires", Electrochem. Commun., 6, 400-403. https://doi.org/10.1016/j.elecom.2004.02.011
  13. Nadia, G.K., Howida, T.Z., Mansoura, I.M. and Hemat, M.M. (2010), "Silver nanoparticles effect on antimicrobial and antifungal activity of new heterocycles", Bull. Korean Chem. Soc., 31, 3530-3538. https://doi.org/10.5012/bkcs.2010.31.12.3530
  14. Raffi, M., Hussain, F., Bhatti, T.M., Akhter, J.I., Hameed, A. and Hasan, M.M. (2008), "Antibacterial Characterization of Silver Nanoparticles against E: Coli ATCC-15224", J. Mater. Sci. Technol., 24, 192-196.
  15. Song, K.C., Lee, S.M., Park, T.S. and Lee, B.S. (2009), "Preparation of colloidal silver nanoparticles by chemical reduction method", Korean J. Chem. Eng., 26, 153-155. https://doi.org/10.1007/s11814-009-0024-y
  16. Varshney, R., Mishra, A.N., Bhadauria, S. and Gaur. M.S. (2009), "A novel microbial route to synthesize silver nanoparticles using fungus Hormoconis resinae", Digest J. Nanomater. Biostruct., 4, 349-355.
  17. Wasif, A.I. and Laga, S.K. (2009), "Use of nano silver as an antimicrobial agent for cotton", Autex Res. J., 9(1), 1348-1352.
  18. Yadav, V.B. and Yadav, A.V. (2009), "Polymeric recrystallized agglomerates of Cefuroxime Axetil prepared by emulsion solvent diffusion technique", Trop. J. Pharmaceut. Res., 8(4), 361-369.
  19. Zhou, M., Wei, Z., Qiao, H., Zhu, L., Yang, H. and Xia, T. (2009), "Particle size and pore structure characterization of silver nanoparticles prepared by confined arc plasma", J. Nanomater., 1-5.