Applied Chemistry for Engineering (공업화학)

The Korean Society of Industrial and Engineering Chemistry (한국공업화학회)
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Preparation of Polystyrene-Polyetherimide Core-Shell Particles by Dispersion Polymerization

분산중합에 의한 폴리스티렌-폴리에테르이미드 코어-셀 입자의 합성

  • Ahn, Byung Hyun (Department of Material Engineering, Pukyong National University)
  • 안병현 (부경대학교 재료공학과)
  • Received : 2014.07.22
  • Accepted : 2014.08.28
  • Published : 2014.10.10
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Abstract

Polystyrene-poly(etheramic acid) core-shell particles were prepared by dispersion polymerization of styrene using poly(etheramic acid) obtained by the reaction of 2,2'-bis[4-(3,4-dicarboxyphenoxy) phenyl]propane dianhydride and 3,5-diamniobenzoic acid as a stabilizer. 4-Vinylbenzyltrimethylammonium chloride was used as a comonomer to increase the binding efficiency of poly(etheramic acid). When the ethanol-water mixture (7 : 3) was used as a reaction medium, particles were stabilized well and the size distribution of particles was fairly narrow. The particle size increased with the amount of styrene. The particles polymerized in the dimethylformamide-water mixture had a broad size range. Polystyrene-poly(etheramic acid) core-shell particles were transformed to polystyrene-polyetherimide core-shell particles by the chemical imidization of shells.

2,2'-Bis[4-(3,4-dicarboxyphenoxy) phenyl]propane dianhydride와 3,5-diamniobenzoic acid의 반응에 의해 얻어진 폴리에테르아미드산을 안정제로 사용하여 스티렌을 분산중합하여 폴리스티렌-폴리에테르아미드산 코어-셀 입자를 얻었다. 폴리에테르아미드산의 결합 효율을 증가시키기 위하여 4-vinylbenzyltrimethylammonium chloride를 공단량체로 사용하였다. 에탄올-물(7 : 3) 혼합용액을 반응매질로 사용했을 때 입자의 안정성 가장 높았고 입자의 크기도 비교적 균일하였다. 폴리스티렌-폴리에테르아미드산 코어-셀 입자의 크기는 스티렌의 양에 비례하여 증가하였다. Dimethylformamide-물 혼합용액에서 중합한 경우에는 입자의 크기 분포가 넓어졌다. 폴리스티렌-폴리에테르아미드산 코어-셀 입자의 셀을 화학적으로 이미드화 하여 폴리스티렌-폴리에테르이미드 코어-셀 입자로 변환시켰다.

Keywords

References

  1. L. Lunelli, L. Pasquardini, C. Pederzolli, L. Vanzetti, and M. Anderle, Covalently anchored lipid structures on amine-enriched polystyrene, Langmuir, 21, 8338-8343 (2005). https://doi.org/10.1021/la050650m
  2. M. H. Kim, S. H. Im, and O. O. Park, Rapid fabrication of twoand three-dimensional colloidal crystal films via confined convective assembly, Adv. Funct. Mater., 15, 1329-1335 (2005). https://doi.org/10.1002/adfm.200400602
  3. X. Xu and S. A. Asher, Synthesis and utilization of monodisperse hollow polymeric particles in photonic crystals, J. Am. Chem. Soc., 126, 7940-7945 (2004). https://doi.org/10.1021/ja049453k
  4. D. V. Orlin and M. L. Abramham, Colloidal crystals as templates for porous materials, Curr. Opin. Colloid Interface Sci., 5, 56-63 (2000). https://doi.org/10.1016/S1359-0294(00)00039-X
  5. M. S. Kim, S. K. Kim, J. Y. Lee, S. H. Cho, K. H. Lee, J. Kim, and S. S. Lee, Synthesis of polystyrene nanoparticles with monodisperse size distribution and positive surface charge using metal stearates, Macromol. Res., 16, 178-181 (2008). https://doi.org/10.1007/BF03218848
  6. K. Narayanan, N. Jayachandran, and P. R. Chatterji, Preparation of linear and crosslinked polymer microspheres by dispersion polymerization, J. Macromol. Sci., Polym. Rev., C41, 79-94 (2001).
  7. A. J. Paine, W. Luymes, and J. McNulty, Dispersion polymerization of styrene in polar solvents. 6. Influence of reaction parameters on particle size and molecular weight in poly(N-vinylpyrro1idone)-stabilized reactions, Macromolecules, 23, 3104-3109 (1990). https://doi.org/10.1021/ma00214a012
  8. I. Capek, M. Riza, and M. Akashi, Dispersion copolymerization of poly(oxyethylene) macromonomers and styrene, J. Polym. Sci., Part A: Polym. Chem., 35, 3131-3139 (1997). https://doi.org/10.1002/(SICI)1099-0518(19971115)35:15<3131::AID-POLA6>3.0.CO;2-Z
  9. C. M. Tseng, Y. Y. Lu, M. S. El-Aasser, and J. W. Vanderhoff, Uniform polymer particles by dispersion polymerization in alcohol, J. Polym. Sci., Part A: Polym. Chem., 24, 2995-3007 (1986). https://doi.org/10.1002/pola.1986.080241126
  10. H. Uyama and S. Kobayashi, Dispersion polymerization of styrene in aqueous alcohol solution: Effects of reaction parameters on the polymer particle formation, Polym. Int., 34, 339-344 (1994). https://doi.org/10.1002/pi.1994.210340315
  11. K. P. Lok and C. K. Ober, Particle size control in dispersion polymerization of polystyrene, Can. J. Chem., 63, 209-216 (1985). https://doi.org/10.1139/v85-033
  12. S. Watanabe, K. Ueno, K. Kudoh, M. Murata, and Y. Masuda, Preparation of core-shell polystyrene-polyimide particles by dispersion polymerization of styrene using poly(amic acid) as a stabilizer, Macromol. Rapid Commun., 21, 1323-1326 (2000). https://doi.org/10.1002/1521-3927(20001201)21:18<1323::AID-MARC1323>3.0.CO;2-X
  13. S. Watanabe, K. Ueno, K. Kudoh, M. Murata, and Y. Masuda, Preparation of polystyrene-polyimide Particles by dispersion polymerization of styrene using poly(amic acid) as a stabilizer, Polymer Journal, 38, 471-476 (2006). https://doi.org/10.1295/polymj.38.471
  14. S. Shen, E. D. Sudol, and M. S. El-Aasser, Dispersion polymerization of methyl methacrylate: Mechanism of particle formation, J. Polym. Sci., Part A: Polym. Chem., 32, 1087-1100 (1994). https://doi.org/10.1002/pola.1994.080320611
  15. S. Kobayashi, H. Uyama, S. W. Lee, and Y. Matsumoto, Preparation of micron-size monodisperse polymer particles by dispersion copolymerization of styrene with poly(2-oxazoline) macromonomer, J. Polym. Sci., Part A: Polym. Chem., 31, 3133-3139 (1993). https://doi.org/10.1002/pola.1993.080311229
  16. E. Bourgeat-Lami and A. Guyot, Preparation of monodisperse polystyrene particles using thiol-ended polyethylene oxide stabilizer in dispersion polymerization, Polym. Bull., 35, 691-696 (1995). https://doi.org/10.1007/BF00294951
  17. T. Itoh, S. Komada, E. Ihara, and K. Inoue, Dispersion polymerization of styrene using a polystyrene/poly(L-glutamic acid) block copolymer as a stabilizer, J. Colloid Interface Sci., 388, 112-117 (2012). https://doi.org/10.1016/j.jcis.2012.08.040
  18. L. Houillot, C. Bui, C. Farcet, C. Moire, J. Aaust, H. Pasch, M. Save, and B. Charleux, Dispersion polymerization of pethyl acrylate in nonpolar solvent stabilized by block copolymers formed in situ via the RAFT process, ACS Appl. Mater. Interfaces, 2, 434-442 (2010). https://doi.org/10.1021/am900695a
  19. K. Takahashi, S. Miyamori, H. Uyama, and S. Kobayashi, Preparation of monodisperse polymer particles from 4-vinylpyridine, Macromol. Rapid Commun., 18, 471-475 (1997). https://doi.org/10.1002/marc.1997.030180603
  20. D. Horak and P. Shapoval, Reactive poly(glycidyl methacrylate) microspheres prepared by dispersion polymerization, J. Polym. Sci., Part A: Polym. Chem., 38, 3855-3863 (1994).