Corrosion Science and Technology

The Corrosion Science Society of Korea (한국부식방식학회)
권호 표지
DOI QR코드

DOI QR Code

Evaluation of Iron Nickel Oxide Nanopowder as Corrosion Inhibitor: Effect of Metallic Cations on Carbon Steel in Aqueous NaCl

  • Chaudhry, A.U. (Department of Metallurgical & Materials Engineering, Colorado School of Mines) ;
  • Mittal, Vikas (Department of Chemical Engineering, The Petroleum Institute) ;
  • Mishra, Brajendra (Department of Metallurgical & Materials Engineering, Colorado School of Mines)
  • Received : 2015.12.11
  • Accepted : 2016.02.22
  • Published : 2016.02.28
Download PDF
⟨ Previous Next ⟩

Abstract

The aim of this study was to evaluate the use of iron-nickel oxide ($Fe_2O_3$.NiO) nanopowder (FeNi) as an anti-corrosion pigment for a different application. The corrosion protection ability and the mechanism involved was determined using aqueous solution of FeNi prepared in a corrosive solution containing 3.5 wt.% NaCl. Anti-corrosion abilities of aqueous solution were determined using electrochemical impedance spectroscopy (EIS) on line pipe steel (API 5L X-80). The protection mechanism involved the adsorption of metallic cations on the steel surface forming a protective film. Analysis of EIS spectra revealed that corrosion inhibition occurred at low concentration, whereas higher concentration of aqueous solution produced induction behavior.

Keywords

References

  1. M. R. Bagherzadeh and F. Mahdavi, Prog. Org. Coat., 60, 117 (2007). https://doi.org/10.1016/j.porgcoat.2007.07.011
  2. P. P. Mahulikar, R. S. Jadhav, and D. G. Hundiwale, Iran. Polym. J., 20, 367 (2011).
  3. K.-C. Chang, W.-F. Ji, M.-C. Lai, Y.-R. Hsiao, C.-H. Hsu, T.-L. Chuang, Y. Wei, J.-M. Yeh, and W.-R. Liu, Polym. Chem., 5, 1049 (2014). https://doi.org/10.1039/C3PY01178J
  4. C. M. Santos, K. Milagros Cui, F. Ahmed, M. C. R. Tria, R. A. M. V. Vergara, A. C. de Leon, R. C. Advincula, and D. F. Rodrigues, Macromol. Mater. Eng., 297, 807 (2012). https://doi.org/10.1002/mame.201100334
  5. A. Kalendova, Prog. Org. Coat., 38, 199 (2000). https://doi.org/10.1016/S0300-9440(00)00103-X
  6. A. Amirudin, C. Barreau, R. Hellouin, and D. Thierry, Prog. Org. Coat., 25, 339 (1995). https://doi.org/10.1016/0300-9440(94)00546-D
  7. M. J. Pryor, J. Electrochem. Soc., 101, 141 (1954). https://doi.org/10.1149/1.2781219
  8. S. Sathiyanarayanan, C. Jeyaprabha, S. Muralidharan, and G. Venkatachari, Appl. Surf. Sci., 252, 8107 (2006). https://doi.org/10.1016/j.apsusc.2005.10.028
  9. D. M. Drazic and L. Ž. Vorkapic, Corros. Sci., 18, 907 (1978). https://doi.org/10.1016/0010-938X(78)90011-2
  10. R. A. Covert and H. H. Uhlig, J. Electrochem. Soc., 104, 537 (1957). https://doi.org/10.1149/1.2428648
  11. A. D. McQuillan and M. K. McQuillan, Titanium, Butterworths Scientific Publications, London (1956).
  12. D. Schlain and J. S. Smatko, J. Electrochem. Soc., 99, 417 (1952). https://doi.org/10.1149/1.2779612
  13. M. Rey, P. Coheur, and H. Herbiet, Trans. Electrochem. Soc., 73, 315 (1938). https://doi.org/10.1149/1.3493972
  14. H. Leidheiser, Corrosion, 36, 339 (1980). https://doi.org/10.5006/0010-9312-36.7.339
  15. I. M. Zin, J. Mater. Sci., 36, 450 (2000). https://doi.org/10.1007/BF02769610
  16. J. L. Mora-Mendoza and S. Turgoose, Corros. Sci., 44, 1223 (2002). https://doi.org/10.1016/S0010-938X(01)00141-X
  17. A. U. Chaudhry, V. Mittal, and B. Mishra, Mater. Chem. Phys., 163, 130 (2015). https://doi.org/10.1016/j.matchemphys.2015.07.023
  18. A. Bonnel, F. Dabosi, C. Deslouis, M. Duprat, M. Keddam, and B. Tribollet, J. Electrochem. Soc., 130, 753 (1983). https://doi.org/10.1149/1.2119798
  19. S. L. d. Assis, S. Wolynec, and I. Costa, Electrochim. Acta, 51, 1815 (2006). https://doi.org/10.1016/j.electacta.2005.02.121
  20. C. Chen and F. Mansfeld, Corros. Sci., 39, 409 (1997). https://doi.org/10.1016/S0010-938X(97)83355-0
  21. A. Miszczyk and K. Darowicki, Anti-Corros. Method. M., 58, 13 (2011). https://doi.org/10.1108/00035591111097657
  22. U. R. Evans, The corrosion and oxidation of metals: scientific principles and practical application, Edward Arnold, London (1960).
  23. M. Pourbaix, Atlas of electrochemical equilibria in aqueous solutions, 2nd English ed., Natl. Assoc. of Corrosion Engineers, Houston, TX (1974).
  24. G. N. Mu, T. P. Zhao, M. Liu, and T. Gu, Corrosion, 52, 853(1996). https://doi.org/10.5006/1.3292077