DOI QR코드

DOI QR Code

Decay Resistance of the Acetylated Tropical Hardwood Species

  • 투고 : 2019.10.04
  • 심사 : 2020.06.29
  • 발행 : 2020.09.30

초록

Chemical modification of wood is an effective method to enhance the biological durability of wood with no toxic effect on the environment. In this study, wood of Triplochiton scleroxylon was modified using acetylation techniques. A total of one hundred wood blocks, (each 20×20×60 mm) obtained from a 22-year old T. scleroxylon tree were conditioned and acetylated at 120℃ in a bioreactor containing acetic anhydride for 60, 120, 180, 240 and 300 minutes. The percentage weight gain of acetylated wood was determined. The untreated (control) and treated blocks were exposed to Pleurotus ostreatus (white rot fungus) and Fibroporia vaillanti (brown rot fungus) after which moisture content (MC) and weight loss (WL) was monitored for 16 weeks. Data were analysed using descriptive and inferential statistics at p<0.05 level of significance. The percentage weight gain of acetylated wood samples increased with time from 10.4% (60 minutes) to 22.7% (300 minutes). MC of untreated blocks inoculated with Pleurotus ostreatus was significantly higher than those of Fibroporia vaillantii after 16 weeks exposure. There was no significant difference in the MC of the of the acetylated samples for the two fungi after 300 minutes reaction time. The WL of untreated blocks inoculated with Fibroporia vaillantii was higher than those of Pleurotus ostreatus, however, the two fungi showed no significant difference in the WL for the acetylated samples after 16 weeks exposure. Acetylation prevents moisture absorption and inhibition of fungi growth in acetylated wood compared to untreated wood, thereby enhancing the durability of Triplochiton scleroxylon.

키워드

참고문헌

  1. Adegeye AO, Ogunsanwo OY, Olajuyigbe SO. 2009. Antifungal Activities of Heart Wood Extract (HWE) of Teak Tectona grandis Against Two White Rots in Woods of Gmelina arborea and Triplochiton scleroxylon. Acad J Plant Sci 2: 279-285.
  2. Adetogun AC. 1998. The potentials of cashew nut shell liquid as a fungicide against wood decay. PhD thesis. University of Ibadan, Ibadan, Nigeria.
  3. Anagnost SE, Smith WB. 1997. Hygroscopicity of decayed wood: implications for weight loss determination. Wood Fiber Sci 29: 299-305.
  4. Anne-Marie T, Rune S, Rowell RM. 1987. Dimensional stability and resistance to biological degradation of wood products by a simplified acetylation procedure. In: Proceedings, 4th International symposium of Wood and Pulping Chemistry; Paris, France; April 27-30, 1987. pp 125-129.
  5. Beckers EPJ, Militz H, Stevens M. 1994. Resistance of acetylated wood to basidiomycetes, softrot and blue stain. No. IRG/WP94-40021. pp 11.
  6. Blanco E, Alfaro J. 2014. Chemical Modification of Calophyllum brasiliense Cambess. and Enterolobium cyclocarpum (Jacq.) Griseb. Wood. Colomb For 17: 125-132. https://doi.org/10.14483/udistrital.jour.colomb.for.2014.1.a08
  7. Calonego FW, Severo ET, Furtado EL. 2010. Decay resistance of thermally-modified Eucalyptus grandis wood at 140 degrees C, 160 degrees C, 180 degrees C, 200 degrees C and 220 degrees C. Bioresour Technol 101: 9391-9394. https://doi.org/10.1016/j.biortech.2010.06.119
  8. Chauhan SS, Nagaveni HC. 2009. Moisture adsorption behaviour of decayed rubber wood. J Institute Wood Sci 19: 1-6. https://doi.org/10.1179/002032009X12536100261953
  9. Cowling EB. 1961. Comparative Biochemistry of the Decay of Sweetgum Sapwood by White-Rot and Brown-Rot Fungi. No. Technical Bulletin 1258.
  10. Curling SF, Clausen CA, Winandy JE. 2001. The effect of hemicellulose degradation on the mechanical properties of wood during brown rot decay. No. IRG/WP 01-20219.
  11. Curling S, Winandy JE, Clausen CA. 2000. An experimental method to simulate incipient decay of wood by basidiomycete fungi. No. IRG/WP00-20200.
  12. Eaton RA, Hale MDC. 1993. Wood: Decay, Pests, and Protection. Chapman & Hall, London, 546 pp.
  13. Fojutowski A, Noskowiak A, Kropacz A. 2013. The effect of acetylation of alder, beech, birch and poplar wood on decay caused by Coniophora puteana fungus. For Wood Technol 82: 273-277.
  14. Girotra K. 2009. Process for Wood Acetylation and Product Thereof. WO2009095687.
  15. Hill CAS. 2006. Wood Modification: Chemical, Thermal and Other Processes. John Wiley & Sons, Chichester, 239 pp.
  16. Hill CAS, Forster SC, Farahani MRM, Hale MDC, Ormondroyd GA, Williams GR. 2005. An investigation of cell wall micropore blocking as a possible mechanism for the decay resistance of anhydride modified wood. Int Biodeterior Biodegrad 55: 69-76. https://doi.org/10.1016/j.ibiod.2004.07.003
  17. Lahiry AK. 2006. Manual for inspection of waterborne preservative treated timber products. No. IRG/WP06-20322.
  18. Lomeli-Ramirez MG, Ochoa-Ruiz HG, Fuentes-Talavera FJ, Garcia-Enriquez S, Cerpa-Gallegos MA, Silva-Guzman JA. 2009. Evaluation of accelerated decay of wood plastic composites by Xylophagus fungi. Int Biodeterior Biodegrad 63: 1030-1035. https://doi.org/10.1016/j.ibiod.2009.08.002
  19. Militz H, Beckers EPJ, Homan WJ. 1997. Modification of solid wood: research and practical potential. No. IRG/WP97-40098.
  20. Mohebby B. 2003. Biological attack of acetylated wood. PhD thesis. Georg-August-Universitat Gottingen, Gottingen, Germany.
  21. Mohebby B. 2008. Application of ATR Infrared Spectroscopy in Wood Acetylation. J Agric Sci Technol 10: 253-259.
  22. Neogi AN, Peterson GD, Shaw J. 2007. Methods Foresterifying Hydroxyl Groups in Wood. No. US7300705B2.
  23. Norimoto M. 2001. Chemical modification of wood. In: Wood and cellulosic chemistry (Hon DNS, Shiraishi N, eds). 2nd ed. Marcel Dekker, New York, pp 573-598.
  24. Ogunsanwo OY, Adedeji GA. 2010. Effect of Bark Extract of Erythrophleum suaveolens (Guillemin & Perrottet) Brenan on Fungal Activities in Wood of Triplochiton scleroxylon K. Schum. J Environ Ext 9: 56-62.
  25. Ogunsanwo OY, Onilude MA. 2000. Specific gravity and shrinkage variation in plantation grown obeche (Triplochiton scleroxylon K. Schum). J Trop For Res 16: 39-45.
  26. Papadopoulos AN. 2010. Chemical modification of solid wood and wood raw material for composites production with linear chain carboxylic acid anhydrides: a brief review. BioRes 5: 499-506.
  27. Papadopoulos AN, Hill CAS. 2002. The biological effectiveness of wood modified with linear chain carboxylic acid anhydrides against Coniophora puteana. Holz als Roh- und Werkstoff 60: 329-332. https://doi.org/10.1007/s00107-002-0327-8
  28. Pardo Sequeira T. 2013. Evaluacion del efecto de la concentracion de anhidrido acetico, temperatura y tiempo en la reaccion de acetilacion para la modificacion quimica de Tectona grandis y Gmelina arborea. Master's thesis. University of Costa Rica, San Jose, Costa Rica. (in Espanol)
  29. Peterson MD, Thomas RJ. 1978. Protection of Wood from Decay Fungi by Acetylation- An Ultrastructural and Chemical Study. Wood Fiber 10: 149-163.
  30. Rahman MR. 2018. Wood Polymer Nanocomposites: Chemical Modifications, Properties and Sustainable Applications. Springer, Cham, 314 pp.
  31. Rowell R. 2012. Chemical Modification of Wood to Produce Stable and Durable Composites. Cellul Chem Technol 46: 443-448.
  32. Sandberg D, Kutnar A, Mantanis G. 2017. Wood modification technologies- a review. IForest 10: 895-908. https://doi.org/10.3832/ifor2380-010
  33. Sarker PK, Rahman MA, Bulbul MR, Das T, Ilias GNM. 2006. Standard Test Methods for Wood Preservatives by Laboratory Agar-Block Test. In: The International Research Group on Wood Protection; Tromso, Norway; June 18-22, 2006.
  34. Suttie ED, Hill CA, Jones D, Orsler RJ. 1998. Chemically modified solid wood. I. Resistance to fungal attack. Mater Org 32: 159-182.
  35. Thomasson G, Capizzi J, Dost F, Morrell J, Miller D. 1989. Wood preservation and wood product treatment: A Training Manual of the University of Oregon. Corvallis, Oregon USA. Extension and Station Communications.
  36. Van Acker J, Hill C. 2003. Proceedings of the First European Conference on Wood Modification: ECWM 2003. Ghent University, Ghent, 414 pp.