Applied Chemistry for Engineering (공업화학)

The Korean Society of Industrial and Engineering Chemistry (한국공업화학회)
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New Yellow Quinoline Derivatives Including Dione Moiety for Image Sensor Color Filters

이미지 센서 컬러 필터용 다이온 성분을 포함하는 신규 황색 퀴놀린 유도체

  • Sunwoo, Park (Integrated Engineering, Department of Chemical Engineering, Kyung Hee University) ;
  • Seyoung, Oh (Integrated Engineering, Department of Chemical Engineering, Kyung Hee University) ;
  • Yuna, Kang (Integrated Engineering, Department of Chemical Engineering, Kyung Hee University) ;
  • Hyukmin, Kwon (Integrated Engineering, Department of Chemical Engineering, Kyung Hee University) ;
  • Sunwoo, Dae (Integrated Engineering, Department of Chemical Engineering, Kyung Hee University) ;
  • Changyu, Lee (Integrated Engineering, Department of Chemical Engineering, Kyung Hee University) ;
  • Dae Won, Kim (R&D Center of SKC hi-tech&marketing) ;
  • Min-Sik, Jang (R&D Center of SKC hi-tech&marketing) ;
  • Jongwook, Park (Integrated Engineering, Department of Chemical Engineering, Kyung Hee University)
  • 박선우 (경희대학교 화학공학과 융합공학) ;
  • 오세영 (경희대학교 화학공학과 융합공학) ;
  • 강유나 (경희대학교 화학공학과 융합공학) ;
  • 권혁민 (경희대학교 화학공학과 융합공학) ;
  • 대선우 (경희대학교 화학공학과 융합공학) ;
  • 이찬규 (경희대학교 화학공학과 융합공학) ;
  • 김대원 (SKC 하이테크앤 마케팅 R&D 센터) ;
  • 장민식 (SKC 하이테크앤 마케팅 R&D 센터) ;
  • 박종욱 (경희대학교 화학공학과 융합공학)
  • Received : 2022.12.01
  • Accepted : 2022.12.19
  • Published : 2023.02.10
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Abstract

New yellow quinoline-dione dye derivatives were designed and synthesized for use in image sensor color filters. The synthesized compounds have a basic chemical structure composed of quinoline and dione groups. New materials were evaluated on the basis of their optical and thermal properties under conditions mimicking those of a commercial device fabrication process. A comparison of their related performances revealed that, between the two prepared compounds, 2-(3-hydroxyquinolin-2(1H)-ylidene)-1H-indene-1,3(2H)-dione (HQIDO) exhibited the superior performance as an image sensor color filter material, including a solubility greater than 0.5 wt% in propylene glycol monomethyl ether acetate solvent and a high decomposition temperature of 298 ℃, respectively. The results suggest that HQIDO can be used as a yellow dye additive in an image sensor colorant.

이미지 센서 컬러 필터에 사용하기 위해 새로운 노란색 퀴놀린-다이온 염료 파생물을 설계하고 합성했습니다. 합성된 화합물은 퀴놀린과 디온 그룹으로 구성된 기본 화학 구조를 가지고 있습니다. 새로운 재료는 상업적 장치 제조 공정을 모방한 조건에서 광학적, 열적 특성을 기반으로 평가되었습니다. 이들의 관련 성능을 비교한 결과, 제조된 두 화합물 사이에서 2-(3-hydroxyquinolin-2(1H)-ylidene)-1H-indene-1,3(2H)-dione (HQIDO)이 다음과 같은 우수한 성능을 나타냈습니다. 프로필렌 글리콜 모노메틸 에테르 아세테이트 용매에서 0.5 wt%보다 큰 용해도, 각각 298 ℃의 높은 분해온도를 포함하는 이미지 센서 컬러 필터 재료. 결과는 HQIDO가 이미지 센서 착색제에서 노란색 염료 첨가제로 사용될 수 있음을 시사합니다.

Keywords

Acknowledgement

This research is (partially) funded by the BK21 FOUR program of National Research Foundation of Korea. This work was supported by the ITECH R&D program of MOTIE/KEIT [project No. 20009872, Development of high throughput colorimetric chemical materials]. This research was supported by the Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education (2020R1A6A1A03048004). This work was supported by the Korea Institute for Advancement of Technology (KIAT) and the Ministry of Trade, Industry & Energy (MOTIE) of the Republic of Korea (No. P0017363). This research was supported by Basic Science Research Capacity Enhancement Project through Korea Basic Science Institute (National research Facilities and Equipment Center) grant funded by the Ministry of Education (No. 2019R1A6C1010052).

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