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Incorporation of Montmorillonite/Silica Composite for the Corrosion Protection of an Epoxy Coating on a 2024 Aluminum Alloy Substrate

  • Thai Thu Thuy (Institute for Tropical Technology, Vietnam Academy of Science and Technology) ;
  • Trinh Anh Truc (Institute for Tropical Technology, Vietnam Academy of Science and Technology) ;
  • Pham Gia Vu (Institute for Tropical Technology, Vietnam Academy of Science and Technology)
  • Received : 2022.09.06
  • Accepted : 2022.11.16
  • Published : 2023.04.30

Abstract

Layered silicate clay montmorillonite (MMT) has been used in nanocomposite coating to improve corrosion protection by reinforcing the barrier property. The better dispersion of MMT in the coating produces a higher barrier effect. Pretreatment with MMT could favor the delamination of clay platelets, facilitating MMT dispersion in the coating. In the present work, a montmorillonite/silica (MMT/Si) composite was prepared by the in situ sol-gel method. x-ray diffraction measurements and field-emission scanning electron microscopy observations showed silica crystal formation and increased basal spacing between the MMT platelets. Composite MMT/Si particles were introduced in an epoxy resin to reinforce the corrosion protection of the coating applied on the AA2024 surface. Electrochemical impedance spectroscopy (EIS) was performed to characterize the protective property of the coating. The results demonstrated the high barrier effect of the coating containing 5 wt% of MMT/Si. Adhesion evaluation after a salt spray test exhibited a high adherence to the epoxy coating containing MMT/Si.

Keywords

Acknowledgement

The authors thank VAST for the funding support under project NVCC13.06/21-21

References

  1. Richard A. Vaia, Gary Price, Patrick N. Ruth, Hieu T. Nguyen, Joseph Lichtenhan, Polymerr layered silicate nanocomposites as high performance ablative materials, Applied Clay Science, 15, 67 (1999). Doi: https://doi.org/10.1016/S0169-1317(99)00013-7
  2. Dongyan Wang, Charles A. Wilkie, In-situ reactive blending to prepare polystyrene-clay and polypropylene-clay nanocomposites, Polymer Degradation and Stability, 80, 171 (2003). Doi: https://doi.org/10.1016/S0141-3910(02)00399-3
  3. AijuanGua, Guozheng Liang, Thermal degradation behaviour and kinetic analysis of epoxy/montmorillonite nanocomposites, Polymer Degradation and Stability, 80, 383- (2003). Doi: https://doi.org/10.1016/S0141-3910(03)00026-0
  4. DavoodZaarei, Ali Asghar Sarabi, Farhad Sharif,Seid Mahmood Kassiriha, Structure, properties and corrosion resistivity of polymericnanocomposite coatings based on layered silicates, Journal of Coatings Technology and Research, 5, 241 (2008). Doi: https://doi.org/10.1007/s11998-007-9065-5
  5. Jui-Ming Yeh, Kung-Chin Chang, ReviewPolymer/layered silicate nanocomposite anticorrosive coatings, Journal of Industrial and Engineering Chemistry, 14, 275 (2008). Doi: https://doi.org/10.1016/j.jiec.2008.01.011
  6. Milos D. Tomic, BrankoDunjic, Jelena B. Bajat,Violeta Likic, Jelena Rogan, JasnaDjonlagic, Anticorrosive epoxy/clay nanocomposite coatings: rheologicaland protective properties, Journal Coatings Technology and Research, 13, 439 (2016). Doi: https://doi.org/10.1007/s11998-015-9762-4
  7. Jui-Ming Yeha, Hsiu-Yin Huanga, Chi-Lun Chena, WenFen Sua, Yuan-Hsiang Yu, Siloxane-modified epoxy resin-clay nanocomposite coatings with advanced anticorrosive properties prepared by a solution dispersion approach, Surface and Coatings Technology, 200, 2753 (2006). Doi: https://doi.org/10.1016/j.surfcoat.2004.11.008
  8. Rajkiran R. Tiwari, Kartic C. Khilar, Upendra Natarajan, Synthesis and characterization of novel organo-montmorillonites, Applied Clay Science, 38, 203 (2008). Doi: https://doi.org/10.1016/j.clay.2007.05.008
  9. LucileneBetega de Paiva, Ana Rita Morales, Francisco R. Valenzuela Diaz, Organoclays : Properties, preparation and applications, Applied Clay Science, 42, 8 (2008). Doi: https://doi.org/10.1016/j.clay.2008.02.006
  10. J. Y. Lee, H. K. Lee, Characterization of organobentonite used for polymer nanocomposites, Materials Chemistry and Physics, 85, 410 (2004). Doi: https://doi.org/10.1016/j.matchemphys.2004.01.032
  11. To Thi Xuan Hang, Trinh Anh Truc, Truong Hoai Nam, Vu Ke Oanh, Jean-Baptiste Jorcin, Nadine Pebere, Corrosion protection of carbon steel by an epoxy resin containing organically modified clay, Surface and Coatings Technology, 201, 7408 (2007). Doi: https://doi.org/10.1016/j.surfcoat.2007.02.009
  12. Trinh Anh Truc, To Thi Xuan Hang, Vu Ke Oanh, Eric Dantras, Colette Lacabanne, Djar Oquab, Nadine Pebere, Incorporation of an indole-3 butyric acid modified clay in epoxy resin for corrosion protection of carbon steel, Surface and Coatings Technology, 202, 4945 (2008). Doi: https://doi.org/10.1016/j.surfcoat.2008.04.092
  13. To Thi Xuan Hang, Trinh Anh Truc, Marie-Georges Olivier, Catherine Vandermiers, Nathalie Guerit, Nadine Pebere, Corrosion protection mechanisms of carbon steel by an epoxy resin containingindole-3 butyric acid modified clay, Progress in Organic Coatings, 69, 410 (2010). Doi: https://doi.org/10.1016/j.porgcoat.2010.08.004
  14. Trinh Anh Truc, Thai Thu Thuy, Vu Ke Oanh, To Thi Xuan Hang, Anh Son Nguyen, Nicolas Causse, Nadine Pebere, 8-hydroxyquinoline-modified clay incorporated in an epoxy coating for the corrosion protection of carbon steel, Surfaces and Interfaces, 14, 26 (2019). Doi: https://doi.org/10.1016/j.surfin.2018.10.007
  15. Massoud Malaki, Yasser Hashemzadeh, Mehdi Karevan, Effect of nano-silica on the mechanical properties of acrylic polyurethane coatings, Progress in Organic Coatings, 101, 477 (2016). Doi: https://doi.org/10.1016/j.porgcoat.2016.09.012
  16. MassoudMalakia, Yasser Hashemzadeh, Alireza Fadaei Tehrani, Abrasion resistance of acrylic polyurethane coatings reinforced by nano silica, Progress in Organic Coatings, 125, 507 (2018). Doi: https://doi.org/10.1016/j.porgcoat.2018.07.034
  17. Tiina Nypelo, Monika Osterberg, Xuejie Zu, Janne Laine, Preparation of ultrathin coating layers using surface modified silica nanoparticles, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 392, 313 (2011). Doi: https://doi.org/10.1016/j.colsurfa.2011.10.009
  18. DeryaIsin, Nilhan Kayaman-Apohan, Atilla Gungor, Preparation and characterization of UV-curable epoxy/silica nanocomposite coatings, Progress in Organic Coatings, 65, 477 (2009). Doi: https://doi.org/10.1016/j.porgcoat.2009.04.007
  19. M. Rostami, Z. Ranjbar, M. Mohseni, Investigating the interfacial interaction of different aminosilane treated nano silicas with a polyurethane coating, Applied Surface Science, 257, 899 (2010). Doi: https://doi.org/10.1016/j.apsusc.2010.07.087
  20. Peter C. LeBaron, Zhen Wang, Thomas J. Pinnavaia, Polymer-layered silicate nanocomposites: an overview, Applied Clay Science, 15, 11 (1999). Doi: https://doi.org/10.1016/S0169-1317(99)00017-4
  21. V. V. Arslanov, W. Funke, The effect of water on the adhesion of organic coatings on aluminum, Progress in Organic Coatings, 15, 355 (1988). Doi: https://doi.org/10.1016/0033-0655(88)85004-0