Current Photovoltaic Research

  • 제12권4호
  • /
  • Pages.111-116
  • /
  • 2024
  • /
  • 2288-3274(pISSN)
  • /
  • 2508-125X(eISSN)
한국태양광발전학회 (Korea Photovoltaic Society)
권호 표지
DOI QR코드

DOI QR Code

최적화된 Anti-solvent 첨가물 방법을 이용한 페로브스카이트 박막 패시베이션

Optimization Strategy for Passivation of Perovskite thin Films via Anti-solvent Additive Method

  • 이원종 (에너지과학기술대학원, 충남대학교) ;
  • ;
  • ;
  • 김선규 (에너지과학기술대학원, 충남대학교) ;
  • 윤시원 (에너지과학기술대학원, 충남대학교) ;
  • 한혜지 (에너지과학기술대학원, 충남대학교) ;
  • 임종철 (에너지과학기술대학원, 충남대학교)
  • Wonjong Lee (Graduate School of Energy Science and Technology, Chungnam National University) ;
  • Muhammad Adnan (Graduate School of Energy Science and Technology, Chungnam National University) ;
  • Zobia Irshad (Graduate School of Energy Science and Technology, Chungnam National University) ;
  • Sunkyu Kim (Graduate School of Energy Science and Technology, Chungnam National University) ;
  • Siwon Yun (Graduate School of Energy Science and Technology, Chungnam National University) ;
  • Hyeji Han (Graduate School of Energy Science and Technology, Chungnam National University) ;
  • Jongchul Lim (Graduate School of Energy Science and Technology, Chungnam National University)
  • 투고 : 2024.10.30
  • 심사 : 2024.11.14
  • 발행 : 2024.12.31
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

An anti-solvent additive method is one of process for passivating defect to improve the crystal quality, stability, and suppressing charge losses. The functional groups of additives can interact with perovskite ions and it can prevent ion vacancies and defects. However, due to different polarity between additives and anti-solvent, the additives have less solubility in the anti-solvent. Herein, we propose a method to optimize the dissolution of additives in anti-solvents, and observe the characteristics of perovskite films produced by the anti-solvent additive method through spectroscopy analysis. We obtained the solubility of additives through absorbance and predicted the unsaturation concentration. In addition, the passivated perovskite films by optimized concentration showed different passivation effects according to additives.

키워드

과제정보

This research was supported by Nano·Material Technology Development Program through the National Research Foundation of Korea (NRF) funded by Ministry of Science and ICT (grant number-2021M3H4A1A02057007). This work was supported by the Korea Institute of Energy Technology Evaluation and Planning (KETEP) and the Ministry of Trade, Industry & Energy (MOTIE) of the Republic of Korea (No. RS-2023-00236664).

참고문헌

  1. H. Min, D. Y. Lee, J. Kim, G. Kim, K. S. Lee, J. Kim, M. J. Paik, Y. K. Kim, K. S. Kim, M. G. Kim, T. J. Shin, S. Il Seok, Perovskite solar cells with atomically coherent interlayers on SnO2 electrodes. Nature. 598, 444-450 (2021). https://doi.org/10.1038/s41586-021-03964-8
  2. W. S. Yang, B. W. Park, E. H. Jung, N. J. Jeon, Y. C. Kim, D.U. Lee, S. S. Shin, J. Seo, E. K. Kim, J. H. Noh, S. Il Seok, Iodide management in formamidinium-lead-halide-based perovskite layers for efficient solar cells, Science. 356, 1376-1379 (2017). https://doi.org/10.1126/science.aan2301
  3. S. K. K. Aung, A. Vijayan, G. Boschloo, T. Seetawan, Enhanced Thermal Stability of Low-Temperature Processed Carbon-Based Perovskite Solar Cells by a Combined Antisolvent/Polymer Deposition Method. Energy Technol. 10, 2200177 (2022).
  4. E. J. Juarez-Perez, L. K. Ono, M. Maeda, Y. Jiang, Z. Hawash, Y. Qi, J, Photodecomposition and thermal decomposition in methylammonium halide lead perovskites and inferred design principles to increase photovoltaic device stability. J. Mater. Chem. A. 6, 9604 (2018).
  5. A. E. Shalan, E. Akman, F. Sadegh, S. Akin, Efficient and stable perovskite solar cells enabled by dicarboxylic acid-supported perovskite crystallization. J. Phys. Chem. Lett. 12, 997 (2021).
  6. Y. Zhou, F. Wang, Y. Cao, J. P. Wang, H. H. Fang, M. A. Loi, N. Zhao, C. P. Wong, Benzylamine-treated wide-bandgap perovskite with high thermal-photostability and photovoltaic performance. Adv. Energy Mater. 7, 1701048 (2017).
  7. E. Yenel, İ. Deveci, Uridine as additive in antisolvent for improving performance and reproducibility of perovskite solar cells. J. Mater. Sci. Mater. Electron. 33, 11896 (2022).
  8. T. W. Chen, S. N. Afraj, S. H. Hong, L. H. Chou, A. Velusamy, C. Y. Chen, Y. Ezhumalai, S. H. Yang, I. Osaka, X. F. Wang, M. C. Chen, C. L. Liu, Synergetic effect on enhanced photovoltaic performance of spray-coated perovskite solar cells enabled by additive doping and antisolvent additive spraying treatment. ACS Appl. Energy Mater. 5, 4149 (2022).
  9. H. Zhang, Y. Wu, C. Shen, E. Li, C. Yan, W. Zhang, H. Tian, L. Han, W. H. Zhu, Efficient and stable chemical passivation on perovskite surface via bidentate anchoring. Adv. Energy Mater. 9, 1 (2019).
  10. X. Zhao, J. Zhou, S. Wang, L. Tan, M. Li, H. Li, C. Yi, Effects of N-Positions on pyridine carboxylic acid-modified inverted perovskite solar cells. ACS Appl. Energy Mater. 4, 6903 (2021).
  11. Z. Yang, Q. Fan, T. Shen, J. Jin, W. Deng, J. Xin, X. Huang, X. Wang, J. Li, Amine-passivated ZnO electron transport layer for thermal stability-enhanced perovskite solar cells. Sol. Energy. 204, 223 (2020).
  12. Z. Xu, R. A. Kerner, J. J. Berry, B. P. Rand, Iodine electrochemistry dictates voltage-induced halide segregation thresholds in mixed-halide perovskite devices. Adv. Funct. Mater. 32, 2203432 (2022).
  13. X. Du, J. Zhang, H. Su, X. Guo, Y. Hu, D. Liu, N. Yuan, J. Ding, L. Gao, S. Liu, Synergistic crystallization and passivation by a single molecular additive for high-performance perovskite solar cells. Adv. Mater. 34, 1 (2022).
  14. L. Xie, J. Chen, P. Vashishtha, X. Zhao, G. S. Shin, S. G. Mhaisalkar, N. G. Park, Importance of functional groups in cross-linking methoxysilane additives for high-efficiency and stable perovskite solar cells. ACS Energy Lett. 4, 2192 (2019).
  15. J. Liang, C. Chen, X. Hu, Z. Chen, X. Zheng, J. Li, H. Wang, F. Ye, M. Xiao, Z. Lu, Y. Xu, S. Zhang, R. Yu, C. Tao, G. Fang, Suppressing the phase segregation with potassium for highly efficient and photostable inverted wide-band gap halide perovskite solar cells. 12, 48458-48466 (2020).