Corrosion Science and Technology

  • 제23권1호
  • /
  • Pages.54-63
  • /
  • 2024
  • /
  • 1598-6462(pISSN)
  • /
  • 2288-6524(eISSN)
한국부식방식학회 (The Corrosion Science Society of Korea)
권호 표지
DOI QR코드

DOI QR Code

Characterizations of Precipitated Zinc Powder Produced by Selective Leaching Method

  • Marwa F. Abd (Department of Production Engineering, and Metallurgy, University of Technology) ;
  • F. F. Sayyid (Department of Production Engineering, and Metallurgy, University of Technology) ;
  • Sami I. Jafar Al-rubaiey (Department of Production Engineering, and Metallurgy, University of Technology)
  • 투고 : 2022.05.04
  • 심사 : 2024.01.30
  • 발행 : 2024.02.29
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

This work investigated the influence of concentration and applied potential on the characteristics of zinc powder (purity, apparent density, morphology, particle size distribution, and particle zeta potential) produced by the electrochemical process from waste brass. High-purity zinc powder is obtained using selective leaching of industrial brass waste in acidic, neutral, and alkaline solutions. The free immersion method with and without voltage using linear polarization technique is used. In the electrochemical process, hydrochloric acid HCl in three different concentrations (0.1, 0.2, and 0.3) M is used. The time and the distance between the electrodes are set to be 30 min and 3 cm, respectively. It has been found that the percentage purity is 98%, 96%, and 94% for the acidic, neutral, and alkaline solutions, respectively. In addition, the morphology of zinc powder analyzed by SEM was dendritic and mossy. It has been recorded that the purity of zinc increases with the increase of the concentration and applied potential. The highest value of purity for zinc powder was %98.58 in 1000 mV and 0.3M concentration for graphite cathode.

키워드

참고문헌

  1. R. C. Newman, 2.05-Dealloying, Shreir's Corrosion, 2, 801 (2010). Doi: https://doi.org/10.1016/B978-044452787-5.00031-7 
  2. R. W. Revie, H. H. Uhlig, Corrosion and Corrosion Control: An Introduction to Corrosion Science and Engineering, 4th ed., pp.43 - 48, John Wiley & Sons, Inc., New York (2008). Doi: https://doi.org/10.1002/9780470277270 
  3. C. D. S. Tuck, C.A. Powell, J. Nuttall, Corrosion of Copper and Its Alloys, Reference Module in Materials Science and Materials Engineering, pp. 443 - 470, Elsevier Inc., Amsterdam (2016). Doi: https://doi.org/10.1016/B978-0-12-803581-8.01634-9 
  4. R. H. Abd alster, R. S.Yaseen and F. F. Sayyid, International Journal of Mechanical Engineering, Electrodeposition of Zinc from Galvanized Steel, Journal of University of Babylon for Engineering Sciences, 27, 394 (2019). Doi: https://doi.org/10.29196/jubes.v27i1.2189 
  5. M. F. Abd, S. I. Jaafar, F. F. Sayyid, The effect of Immersion Period on the Dezincification Behavior of α -Brass Alloy Waste, International Journal of Mechanical Engineering, 7, 543 (2022). https://kalaharijournals.com/resources/61-80/IJME_Vol7.1_74.pdf 
  6. T. S. Weisser, The De-alloying of Copper Alloys, Studies in Conservation, 20, 207 (1975). Doi: https://doi.org/10.1179/sic.1975.s1.035 
  7. G. D. Walker, An SEM and Micro analytical Study of Inservice Dezincification of Brass, Corrosion, 33, 262 (1977). Doi: https://doi.org/10.5006/0010-9312-33.7.262 
  8. J. Weissmuller, R. C. Newman, H. -J. Jin, A. M. Hodge and J. W. Kysar, Nanoporous Metals by Alloy Corrosion: Formation and Mechanical Properties, MRS Bulletin, 34, 577 (2009). Doi: https://doi.org/10.1557/mrs2009.157 
  9. J. Erlebacher, C. Newman, K. Sieradzki, Fundamental physics and chemistry of nanoporosity evolution during dealloying, In Nanoporous Gold FROMan Ancient Technology to a High-Tech Materia, pp. 11 - 29, RSC Nanoscience and Nanotechnology, Royal Society of Chemistry (2012). Doi: https://doi.org/10.1039/9781849735285-00011 
  10. K. Ismail, Evaluation of cysteine as environmentally friendly corrosion inhibitor for copper in neutral and acidic chloride solutions, Electrochimica Acta, 52, 7811 (2007). Doi: https://doi.org/10.1016/j.electacta.2007.02.053 
  11. S. Zaferani, M. Sharifi, D. Zaarei, and M. Shishesaz, Application of eco-friendly products as corrosion inhibitors for metals in acid pickling processes-A review, Journal of Environmental Chemical Engineering, 1 652 (2013). Doi https://doi.org/10.1016/j.jece.2013.09.019 
  12. E. S. M. Sherif, R. M. Erasmus, and J. D. Comins, Inhibition of copper corrosion in acidic chloride pickling solutions by 5-(3-aminophenyl)-tetrazole as a corrosion inhibitor, Corrosion Science, 50, 3439 (2008). Doi: https://doi.org/10.1016/j.corsci.2008.10.002 
  13. S. M. Milic and M. M. Antonijevic, Some aspects of copper corrosion in presence of benzotriazole and chloride ions, Corrosion Science, 51, 28 (2009). Doi: https://doi.org/10.1016/j.corsci.2008.10.007 
  14. G. Abd El-Hafez and W. Badawy, The use of cysteine, N-acetyl cysteine and methionine as environmentally friendly corrosion inhibitors for Cu-10Al-5Ni alloy in neutral chloride solutions, Electrochimica Acta, 108, 860 (2013). Doi https://doi.org/10.1016/j.electacta.2013.06.079 
  15. Yaofu Zhang and Marc Edwards, Effects of pH, chloride, bicarbonate, and phosphate on brass dezincification, Journal - American Water Works Association, 103, 90 (2011). Doi: https://doi.org/10.1002/j.1551-8833.2011.tb11438.x= 
  16. Oleg D. Neikov, N. A. Yefimov, Stanislav Naboychenko, Handbook of Non-Ferrous Metal Powders: Technologies and Applications, 2nd ed., pp. 3 - 62, Elsevier (2019). Doi: https://doi.org/10.1016/B978-0-08-100543-9.00001-4 
  17. Firas F. Sayyid, Ali M. Mustafa1, Mahdi M. Hanoon, Lina M. Shaker, and Ahmed A. Alamiery, Corrosion Protection Effectiveness and Adsorption Performance of Schiff Base-Quinazoline on Mild Steel in HCl Environment, Corrosion Science and Technology, 21, 77 (2022). Doi: https://doi.org/10.14773/cst.2022.21.2.77