DOI QR코드

DOI QR Code

A review of Graphene Oxide (GO) performance on cementitious application

  • Khairul Nazhan Khairul Izwan (Department of Structure and Materials, School of Civil Engineering, College of Engineering, Universiti Teknologi MARA) ;
  • Nazirah Mohd Apandi (Department of Structure and Materials, School of Civil Engineering, College of Engineering, Universiti Teknologi MARA) ;
  • Warid Wazien Ahmad Zailani (Department of Structure and Materials, School of Civil Engineering, College of Engineering, Universiti Teknologi MARA) ;
  • Alia Sofea Shamsol (Department of Structure and Materials, School of Civil Engineering, College of Engineering, Universiti Teknologi MARA) ;
  • Wei-Kit Chee (Petronas Research Sdn Bhd, Petronas Research and Scientific, Bangi Government and Private Training Centre Area)
  • Received : 2024.08.22
  • Accepted : 2025.03.07
  • Published : 2025.04.25

Abstract

Conventional cementitious materials, while widely used in construction, suffer from inherent drawbacks, particularly low tensile strength, which predisposes them to crack. Fortunately, recent advancements in nanotechnology offer promising avenues for enhancing the properties of these materials. Within the realm of cementitious composites, graphene oxide (GO) has emerged as a nanomaterial of considerable interest due to its ability to significantly improve the strength of mortar and cement paste even at low inclusion levels. These remarkable characteristic positions GO as a potentially superior nano-filler for use in cement composites, paving the way for the development of more efficient, robust, and durable construction materials. This review delves into the existing body of research on GO-reinforced cement composites, specifically focusing on their mechanical performance, microstructural characteristics, workability, and durability. By critically analyzing these aspects, the review aims to identify key strengths and limitations associated with GO incorporation. Furthermore, the review highlights areas for further research that could facilitate the optimization and effective application of GO as a nano-reinforcing agent in cement composites. In conclusion, the review acknowledges the challenges associated with GO implementation while simultaneously emphasizing the exciting potential it holds for the future of construction materials.

Keywords

References

  1. Aisheh, Y.I.A. (2023), "Palm oil fuel ash as a sustainable supplementary cementitious material for concrete: A state-of-the-art review", Case Stud. Constr. Mater., 18. https://doi.org/10.1016/j.cscm.2022.e01770
  2. Alian, A.R., Dewapriya, M.A.N. and Meguid, S.A. (2017), "Molecular dynamics study of the reinforcement effect of graphene in multilayered polymer nanocomposites", Mater. Des., 124, 47-57. https://doi.org/10.1016/j.matdes.2017.03.052
  3. Alla, S. and Asadi, S.S. (2023), "Investigation on fluidity, microstructure, mechanical and durability properties of snail shell based graphene oxide cement composite material", Constr. Build. Mater., 362. https://doi.org/10.1016/j.conbuildmat.2022.129767
  4. Alqarni, A.S. (2022), "A comprehensive review on properties of sustainable concrete using volcanic pumice powder ash as a supplementary cementitious material", Constr. Build. Mater., 323, p. 126533. https://doi.org/10.1016/j.conbuildmat.2022.126533
  5. Amran, M., Al-Fakih, A., Chu, S.H., Fediuk, R., Haruna, S., Azevedo, A. and Vatin, N. (2021), "Long-term durability properties of geopolymer concrete: An in-depth review", Case Stud Constr. Mater., 15. https://doi.org/10.1016/j.cscm.2021.e00661
  6. Anwar, A., Mohammed, B.S., Wahab, M.A. and Liew, M.S. (2020), "Enhanced properties of cementitious composite tailored with graphene oxide nanomaterial - A review", Develop. Built Environ., 1, p. 100002. https://doi.org/10.1016/j.dibe.2019.100002
  7. Anwar, A., Liu, X. and Zhang, L. (2023), "Nano-cementitious composites modified with Graphene Oxide – a review", Thin-Wall. Struct., 183, p. 110326. https://doi.org/10.1016/j.tws.2022.110326
  8. Apandi, N., Ma, C.K., Awang, A.Z. and Omar, W. (2021), "Structural behaviour of pre-damaged RC columns immediate repaired employing pre-tensioned steel straps", Structures, 34, 964-978. https://doi.org/10.1016/j.istruc.2021.08.039
  9. Babak, F., Abolfazl, H., Alimorad, R. and Parviz, G. (2014), "Preparation and mechanical properties of graphene oxide: Cement nanocomposites", Scientif. World J., 2014, p. 276323. https://doi.org/10.1155/2014/276323
  10. Bheel, N., Ali, M.O.A., Kırgız, M.S., Shafiq, N. and Gobinath, R. (2023), "Effect of graphene oxide particle as nanomaterial in the production of engineered cementitious composites including superplasticizer, fly ash, and polyvinyl alcohol fiber", Materials Today: Proceedings. https://doi.org/10.1016/j.matpr.2023.03.010
  11. Burgos, D.M., Guzmán, Á., Torres, N. and Delvasto, S. (2017), "Chloride ion resistance of self-compacting concretes incorporating volcanic materials", Constr. Build. Mater., 156, 565-573. https://doi.org/10.1016/j.conbuildmat.2017.09.017
  12. Chetty, K., Watson, M., Raine, T., McGurgan, T., Ladislaus, P., Chen, J., Zhang, S., Lin, L. and Jiang, G. (2022), "EnEnhancing concrete and mortar properties and durability using pristine graphene particles", Coatings, 12(11), 1703. https://doi.org/10.3390/coatings12111703
  13. Chintalapudi, K. and Pannem, R.M.R. (2020a), "An intense review on the performance of graphene oxide and reduced graphene oxide in an admixed cement system", Constr. Build. Mater., 259, p. 120598. https://doi.org/10.1016/j.conbuildmat.2020.120598
  14. Chintalapudi, K. and Pannem, R.M.R. (2020b), "The effects of Graphene Oxide addition on hydration process, crystal shapes, and microstructural transformation of Ordinary Portland Cement", J. Build. Eng., 32, p. 101551. https://doi.org/10.1016/j.jobe.2020.101551
  15. Chu, H., Zhang, Y., Wang, F., Feng, T., Wang, L. and Wang, D. (2020), "Effect of graphene oxide on mechanical properties and durability of ultra-high-performance concrete prepared from recycled sand", Nanomaterials, 10(9), 1-17. https://doi.org/10.3390/nano10091718
  16. Chuah, S., Pan, Z., Sanjayan, J.G., Wang, C.M. and Duan, W.H. (2014), "Nano reinforced cement and concrete composites and new perspective from graphene oxide", Constr. Build. Mater, 73, 113-124. https://doi.org/10.1016/j.conbuildmat.2014.09.040
  17. Chuah, S., Li, W., Chen, S.J., Sanjayan, J.G. and Duan, W.H. (2018), "Investigation on dispersion of graphene oxide in cement composite using different surfactant treatments", Constr. Build. Mater., 161, 519-527. https://doi.org/10.1016/j.conbuildmat.2017.11.154
  18. Du, H. and Pang, S.D. (2015), "Enhancement of barrier properties of cement mortar with graphene nanoplatelet", Cement Concrete Res., 76, 10-19. https://doi.org/10.1016/j.cemconres.2015.05.007
  19. Du, H., Gao, H.J. and Pang, S.D. (2016), "Improvement in concrete resistance against water and chloride ingress by adding graphene nanoplatelet", Cement Concrete Res., 83, 114-123. https://doi.org/10.1016/j.cemconres.2016.02.005
  20. Ebrahimi, K., Daiezadeh, M.J., Zakertabrizi, M., Zahmatkesh, F. an Habibnejad Korayem, A. (2018), "A review of the impact of micro- and nanoparticles on freeze-thaw durability of hardened concrete: Mechanism perspective", Constr. Build. Mater., 186, 1105-1113. https://doi.org/10.1016/j.conbuildmat.2018.08.029
  21. Ganesh, S., Thambiliyagodage, C., Perera, S.J. and Rajapakse, R.K.N.D. (2023), "Influence of laboratory synthesized graphene oxide on the morphology and properties of cement mortar", Nanomaterials, 13(1). https://doi.org/10.3390/nano13010018
  22. Garcés, P., Andión, L.G., Zornoza, E., Bonilla, M. and Payá, J. (2010), "The effect of processed fly ashes on the durability and the corrosion of steel rebars embedded in cement-modified fly ash mortars", Cement Concrete Compos., 32(3), 204-210. https://doi.org/10.1016/j.cemconcomp.2009.11.006
  23. Glasser, F.P., Marchand, J. and Samson, E. (2008), "Durability of concrete - Degradation phenomena involving detrimental chemical reactions", Cement Concrete Res., 38(2), 226-246. https://doi.org/10.1016/j.cemconres.2007.09.015
  24. Goyal, R., Verma, V.K. and Singh, N.B. (2023), "Nanomaterials based self-healing concrete", Mater. Today: Proceedings. https://doi.org/10.1016/j.matpr.2023.03.553
  25. Han, Y., Shao, S., Fang, B., Shi, T., Zhang, B., Wang, X. and Zhao, X. (2023), "Chloride ion penetration resistance of matrix and interfacial transition zone of multi-walled carbon nanotube-reinforced concrete", J. Build. Eng., 72, p. 106587. https://doi.org/10.1016/j.jobe.2023.106587
  26. Hong, X., Lee, J.C., Ng, J.L., Md Yusof, Z., He, Q. and Li, Q. (2023), "Effect of graphene oxide on the mechanical properties and durability of high-strength lightweight concrete containing shale ceramsite", Materials, 16(7), p. 2756. https://doi.org/10.3390/ma16072756
  27. Hosseini, P., Hosseinpourpia, R., Pajum, A., Khodavirdi, M.M., Izadi, H. and Vaezi, A. (2014), "Effect of nano-particles and aminosilane interaction on the performances of cement-based composites: An experimental study", Constr. Build. Mater., 66, 113-124. https://doi.org/10.1016/j.conbuildmat.2014.05.047
  28. Huang, H., Teng, L., Gao, X., Khayat, K.H., Wang, F. and Liu, Z. (2022), "Effect of carbon nanotube and graphite nanoplatelet on composition, structure, and nano-mechanical properties of CSH in UHPC", Cement Concrete Res., 154, p. 106713. https://doi.org/10.1016/j.cemconres.2022.106713
  29. Hyvert, N., Sellier, A., Duprat, F., Rougeau, P. and Francisco, P. (2010), "Dependency of C-S-H carbonation rate on CO2 pressure to explain transition from accelerated tests to natural carbonation", Cement Concrete Res., 40(11), 1582-1589. https://doi.org/10.1016/j.cemconres.2010.06.010
  30. Jing, G., Ye, Z., Lu, X. and Hou, P. (2017), "Effect of graphene nanoplatelets on hydration behaviour of Portland cement by thermal analysis", Adv. Cement Res., 29(2), 63-70. https://doi.org/10.1680/jadcr.16.00087
  31. Lee, J.C., Shafigh, P. and Bahri, S. (2019), "Comparative study of mechanical properties for substitution of normal weight coarse aggregate with oil-palm-boiler clinker and lightweight expanded clay aggregate concretes", J. Des. Built Environ., 19(3), 62-77. https://doi.org/10.22452/jdbe.vol19no3.7
  32. Li, Z., Wang, H., He, S., Lu, Y. and Wang, M. (2006), "Investigations on the preparation and mechanical properties of the nano-alumina reinforced cement composite", Mater. Lett., 60(3), 356-359. https://doi.org/10.1016/j.matlet.2005.08.061
  33. Li, X., Liu, Y.M., Li, W.G., Li, C.Y., Sanjayan, J.G., Duan, W.H. and Li, Z. (2017), "Effects of graphene oxide agglomerates on workability, hydration, microstructure and compressive strength of cement paste", Constr. Build. Mater., 145, 402-410. https://doi.org/10.1016/j.conbuildmat.2017.04.058
  34. Liu, Q., Xu, Q., Yu, Q., Gao, R. and Tong, T. (2016), "Experimental investigation on mechanical and piezoresistive properties of cementitious materials containing graphene and graphene oxide nanoplatelets", Constr. Build. Mater., 127, 565-576. https://doi.org/10.1016/j.conbuildmat.2016.10.024
  35. Liu, J., Qiu, Q., Chen, X., Xing, F., Han, N., He, Y. and Ma, Y. (2017), "Understanding the interacted mechanism between carbonation and chloride aerosol attack in ordinary Portland cement concrete", Cement Concrete Res., 95, 217-225. https://doi.org/10.1016/j.cemconres.2017.02.032
  36. Long, W.J., Gu, Y.C., Xing, F. and Khayat, K.H. (2018), "Microstructure development and mechanism of hardened cement paste incorporating graphene oxide during carbonation", Cement Concrete Compos., 94, 72-84. https://doi.org/10.1016/j.cemconcomp.2018.08.016
  37. Lv, S.H., Deng, L.J., Yang, W.Q., Zhou, Q.F. and Cui, Y.Y. (2016), "Fabrication of polycarboxylate/graphene oxide nanosheet composites by copolymerization for reinforcing and toughening cement composites", Cement Concrete Compos., 66, 1-9. https://doi.org/10.1016/j.cemconcomp.2015.11.007
  38. Ma, C.K., Yung, S.C.S., Apandi, N., Awang, A.Z. and Omar, W. (2017), "Innovative concrete repairing technique using post tensioning steel straps", In: MATEC Web of Conferences, Vol. 103, p. 02011.
  39. Maglad, A.M., Zaid, O., Arbili, M.M., Ascensão, G., Șerbănoiu, A.A., Grădinaru, C.M., García, R.M., Qaidi, S.M., Althoey, F. and de Prado-Gil, J. (2022), "A study on the properties of geopolymer concrete modified with nano graphene oxide", Buildings, 12(8), p. 1066. https://doi.org/10.3390/buildings12081066
  40. Manikanta, D. and Ravella, D.P. (2020), "Mechanical and durability characteristics of high performance self-compacting concrete containing flyash, silica fume and graphene oxide", Materials Today: Proceedings, 43, 2361-2367. https://doi.org/10.1016/j.matpr.2021.01.684
  41. Marques, P.F., Chastre, C. and Nunes, Â. (2013), "Carbonation service life modelling of RC structures for concrete with Portland and blended cements", Cement Concrete Compos., 37(1), 171-184. https://doi.org/10.1016/j.cemconcomp.2012.10.007
  42. Mirjavadi, S.S., Forsat, M., Yahya, Y.Z., Barati, M.R., Jayasimha, A.N. and Khan, I. (2020), "Analysis of post-buckling of higher-order graphene oxide reinforced concrete plates with geometrical imperfection", Adv. Concrete Constr., Int. J., 9(4), 397-406. https://doi.org/10.12989/acc.2020.9.4.397
  43. Mo, L., Zhang, F., Deng, M., Jin, F., Al-Tabbaa, A. and Wang, A. (2017), "Accelerated carbonation and performance of concrete made with steel slag as binding materials and aggregates", Cement Concrete Compos., 83, 138-145. https://doi.org/10.1016/j.cemconcomp.2017.07.018
  44. Mohammed, A., Sanjayan, J.G., Duan, W.H. and Nazari, A. (2015), "Incorporating graphene oxide in cement composites: A study of transport properties", Constr. Build. Mater., 84, 341-347. https://doi.org/10.1016/j.conbuildmat.2015.01.083
  45. Morandeau, A., Thiéry, M. and Dangla, P. (2014), "Investigation of the carbonation mechanism of CH and C-S-H in terms of kinetics, microstructure changes and moisture properties", Cement Concrete Res., 56, 153-170. https://doi.org/10.1016/j.cemconres.2013.11.015
  46. Najigivi, A., Khaloo, A., Iraji Zad, A. and Abdul Rashid, S. (2013), "Investigating the effects of using different types of SiO2 nanoparticles on the mechanical properties of binary blended concrete", Compos. Part B: Eng., 54(1), 52-58. https://doi.org/10.1016/j.compositesb.2013.04.035
  47. Oyebisi, S., Ede, A., Olutoge, F. and Ngene, B. (2020), "Assessment of activity indexes on the splitting tensile strengthening of geopolymer concrete incorporating supplementary cementitious materials", Mater. Today Commun., 24, p. 101356. https://doi.org/10.1016/j.mtcomm.2020.101356
  48. Pan, Z., He, L., Qiu, L., Korayem, A.H., Li, G., Zhu, J.W., Collins, F., Li, D., Duan, W.H. and Wang, M.C. (2015), "Mechanical properties and microstructure of a graphene oxide-cement composite", Cement Concrete Compos., 58, 140-147. https://doi.org/10.1016/j.cemconcomp.2015.02.001
  49. Ranjbar, N., Mehrali, M., Mehrali, M., Alengaram, U.J. and Jumaat, M.Z. (2015), "Graphene nanoplatelet-fly ash based geopolymer composites", Cement Concrete Res., 76, 222-231. https://doi.org/10.1016/j.cemconres.2015.06.003
  50. Sairam, V., Shanmugapriya, T., Jain, C., Agrahari, H.K. and Malpani, T. (2021), "Experimental study of graphene oxide on wollastonite induced cement mortar", Adv. Concrete Constr., Int. J., 12(6), 479-490. https://doi.org/10.12989/acc.2021.12.6.479
  51. Sajjad, U., Sheikh, M.N. and Hadi, M.N.S. (2022), "Incorporation of graphene in slag-fly ash-based alkali-activated concrete", Constr. Build. Mater., 322, p. 126417. https://doi.org/10.1016/j.conbuildmat.2022.126417
  52. Sanchez, F. and Sobolev, K. (2010), "Nanotechnology in concrete - A review. In Construction and Building Materials", 24(11), 2060-2071. https://doi.org/10.1016/j.conbuildmat.2010.03.014
  53. Seifan, M., Mendoza, S. and Berenjian, A. (2020), "Mechanical properties and durability performance of fly ash based mortar containing nano- and micro-silica additives", Constr. Build. Mater., 252, p. 119121. https://doi.org/10.1016/j.conbuildmat.2020.119121
  54. Tong, T., Fan, Z., Liu, Q., Wang, S., Tan, S. and Yu, Q. (2016), "Investigation of the effects of graphene and graphene oxide nanoplatelets on the micro- and macro-properties of cementitious materials", Constr. Build. Mater., 106, 102-114. https://doi.org/10.1016/j.conbuildmat.2015.12.092
  55. Tragazikis, I., Dassios, K.G., Dalla, P.T., Exarchos, D.A. and Matikas, T.E. (2019), "Acoustic emission investigation of the effect of graphene on the fracture behavior of cement mortars", Eng. Fract. Mech, 210, 444-451. https://doi.org/10.1016/j.engfracmech.2018.01.004
  56. Villain, G., Thiery, M. and Platret, G. (2007), "Measurement methods of carbonation profiles in concrete: Thermogravimetry, chemical analysis and gammadensimetry", Cement Concrete Res., 37(8), 1182-1192. https://doi.org/10.1016/j.cemconres.2007.04.015
  57. Wang, Q., Wang, J., Lu, C.X., Liu, B.W., Zhang, K. and Li, C.Z. (2015), "Influence of graphene oxide additions on the microstructure and mechanical strength of cement", New Carbon Mater., 30(4), 349-356. https://doi.org/10.1016/s1872-5805(15)60194-9
  58. Wang, J., Tao, J., Li, L., Zhou, C. and Zeng, Q. (2020), "Thinner fillers, coarser pores? A comparative study of the pore structure alterations of cement composites by graphene oxides and graphene nanoplatelets", Compos. Part A: Appl. Sci. Manuf., 130, p. 105750. https://doi.org/10.1016/j.compositesa.2019.105750
  59. Wei, Z., Wang, Y., Qi, M., Bi, J., Yang, S. and Yuan, X. (2021), "The role of sucrose on enhancing properties of graphene oxide reinforced cement composites containing fly ash", Constr. Build. Mater., 293, p. 123507. https://doi.org/10.1016/j.conbuildmat.2021.123507
  60. Wu, Y.Y., Que, L., Cui, Z. and Lambert, P. (2019), "Physical properties of concrete containing graphene oxide nanosheets", Materials, 12(10), p. 1707. https://doi.org/10.3390/MA12101707
  61. Xie, Z., Zhou, H., Li, Q., He, C., Zhang, S. and Li, D. (2020), "Effects of colloidal nanosilica/polycarboxylate ether superplasticizer nanocomposite and graphene oxide on properties of fly ash blended cement", Constr. Build. Mater., 262. https://doi.org/10.1016/j.conbuildmat.2020.120767
  62. Yasmin, M. (2021), "Compressive strength prediction for concrete modified with nanomaterials", Case Stud. Constr. Mater., 15. https://doi.org/10.1016/j.cscm.2021.e00660
  63. Yoo, D.Y., Oh, T. and Banthia, N. (2022), "Nanomaterials in ultra-high-performance concrete (UHPC) – A review", Cement Concrete Compos., 134, p. 104730. https://doi.org/10.1016/j.cemconcomp.2022.104730
  64. Yu, L. and Wu, R. (2020), "Using graphene oxide to improve the properties of ultra-high-performance concrete with fine recycled aggregate", Constr. Build. Mater., 259, p. 102657. https://doi.org/10.1016/j.conbuildmat.2020.120657
  65. Yu, L., Bai, S. and Guan, X. (2023), "Effect of graphene oxide on microstructure and micromechanical property of ultra-high performance concrete", Cement Concrete Compos., 138, p. 104964. https://doi.org/10.1016/j.cemconcomp.2023.104964
  66. Yuan, X., Zhang, L., Chen, X. and Liu, F. (2022), "Study on the mechanical properties and frost resistance of multiple modified concrete", Mater. Res. Express, 9(4), p. 045013. https://doi.org/10.1088/2053-1591/ac3951
  67. Zaid, O., Ahmad, J., Siddique, M.S., Aslam, F., Alabduljabbar, H. and Khedher, K.M. (2021), "A step towards sustainable glass fiber reinforced concrete utilizing silica fume and waste coconut shell aggregate", Scientific Reports, 11(1), p. 12822. https://doi.org/10.1038/s41598-021-92228-6
  68. Zhang, S.P. and Zong, L. (2014), "Evaluation of relationship between water absorption and durability of concrete materials", Adv. Mater. Sci. Eng., 2014(1), p. 650373. https://doi.org/10.1155/2014/650373
  69. Zhang, Y., Cui, M., Chen, G. and Han, W. (2022), "Experimental study of the effects of graphene nanoplatelets on microstructure and compressive properties of concrete under chloride ion corrosion", Constr. Build. Mater., 360, p. 129564. https://doi.org/10.1016/j.conbuildmat.2022.129564
  70. Zhao, L., Hou, D., Wang, P., Guo, X., Zhang, Y., Liu, J. and Zhang, J. (2020), "Experimental and molecular dynamics studies on the durability of sustainable cement-based composites: Reinforced by graphene", Constr. Build. Mater., 257, p. 119566. https://doi.org/10.1016/j.conbuildmat.2020.119566
  71. Zhao, W., Chen, Y., Liu, Z., Wang, L. and Li, X. (2023), "Effects of surface-modified coal-bearing metakaolin and graphene oxide on the properties of cement mortar", Constr. Build. Mater., 372, p. 103796. https://doi.org/10.1016/j.conbuildmat.2023.130796