Fibers and Polymers
- Monthly
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- 1229-9197(pISSN)
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- 1875-0052(eISSN)
Aim & Scope
Fibers and Polymers, the journal of the Korean Fiber Society, provides you with state-of-the-art research in fiber and polymer science and technology related to developments in the textile industry. Bridging the gap between fiber science and polymer science, the journal's topics include fiber structure and property, dyeing and finishing, textile processing, and apparel science. Ranks 8 out of 23 in the ISI category Materials Science, Textiles with an Impact Factor of 1.022. Aims: The international bimonthly journal Fibers and Polymers publishes original research results in the fields of fiber and polymer science & engineering. Founded in the beginning of a new millennium, Fibers and Polymers starts with international readership and authorship, combining into one journal such closely related themes as fiber and polymer technologies. Fibers and Polymers is unique because it covers interdisciplinary areas related to fibers, polymers, textiles, apparels, colorants, fiber composites, and polymer processing. Scope: - Chemistry of Fiber Materials, Polymer Reactions and Synthesis - Physical Properties of Fibers, Polymer Blends and Composites - Fiber Spinning and Textile Processing, Polymer Physics, Morphology - Colorants and Dyeing, Polymer Analysis and Characterization - Chemical Aftertreatment of Textiles, Polymer Processing and Rheology - Textile and Apparel Science, Functional Polymers
https://www.editorialmanager.com/fipo KSCI KCI SCOPUS SCI SCIEVolume 7 Issue 4
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Poly(vinyl alcohol) (PVA)/multi-walled carbon nanotube (MWNT) composite films were prepared by casting a DMSO solution of PVA and MWNTs, whereby the MWNTs were dispersed by sonication. A significant improvement in the mechanical properties of the PVA drawn films was achieved by the addition of a small amount of MWNTs. The initial modulus and the tensile strength of the PVA drawn film increased by 30 % and 45 %, respectively, with the addition of 1 wt% MWNTs, which are close to those calculated from the rule of mixtures, and were strongly dependent upon the orientation of the PVA matrix. The mechanical properties, however, were not improved with a further increase in the MWNT content. The orientation of MWNTs in the composite was not well developed compared to that of the PVA matrix. This result suggests that the improvement of the molecular orientation of the PVA matrix plays a major role in the increase of the mechanical propeties of the drawn PVA/MWNT composite films.
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Poly(ethylene terephthalate) (PET) and poly(ethylene glycol) (PEG) copolymers cross-linked with pentaerythritol, a four-way cross-linker, are prepared to compare their mechanical and shape memory properties with the one cross-linked by glycerol. Composition of PEG and pentaerythritol is varied to search for the one with the best mechanical and shape memory properties. The highest shape recovery rate is observed for the copolymer composed of 30 mol% PEG-200 and 2.5 mol% pentaerythritol. Four-way cross-linking by pentaerythritol significantly improves shape recovery rate and retention of high shape recovery rate after repeated use compared to the one cross-linked by glycerol, a three-way cross-linker, and difference and advantage of additional cross-linking point are discussed.
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Silk fibroin (SF) fiber from the Antheraea pernyi silkworm was treated with a 1.23 N iodine-potassium iodide (
$I_2-KI$ ) aqueous solution, and the structure and physical properties were investigated to clarify the effects of the iodine treatment. The noticeably high weight gain value of SF fiber, about 25 wt% was attributed to the absorption of polyiodide ions in the form of$I_3{^-}\;and\;I_5{^-}$ . Fourier transform infrared spectroscopy and X-ray diffraction measurements suggested that polyiodide ions mainly entered the amorphous region. In addition, a new sharp reflection on the meridional direction, corresponding to a period of$7.0{\AA}$ , was observed and indicated the possibility of the formation of mesophase structure of${\beta}$ -conformation chains. Dynamic viscoelastic measurements showed that the damping tan${\delta}$ peak at$270^{\circ}C$ gradually shifted to lower temperature in the iodinated SF fibers, suggesting an enhancement of the molecular motion of the fibroin chains induced by the presence of polyiodide ions. With heating above$254^{\circ}C$ , the iodine component introduced intermolecular cross-linking of SF, and the melt flow of the sample was inhibited. The thermal decomposition stability of fibroin molecules was greatly enhanced by iodine treatment. -
The aim of this paper is to improve moisture regain of PET fabrics using a lipase treatment. Effects of nine lipase sources, lipase activator and nonionic surfactant on moisture regain of PET fabrics are examined. Moisture regains of lipase-treated samples improve by two times in average compared with untreated and buffer-treated samples. Alkaline treatment creates larger pitting by more aggressive attack into fiber which is proved by SEM and water contact angle measurement. Moisture regain by alkaline treatment (
$0.568%{\pm}0.08$ ) does not improve. However, lipase-treatment (L2 treatment) improves moisture regain up to 2.4 times ($1.272%{\pm}0.05$ ). Although lipase treatment is more moderate than alkaline treatment, lipase hydrolysis on PET fabrics improves moisture regain, efficiently. K/S values improved confirm that carboxyl and hydroxyl groups are produced on the surface of PET fabrics by lipase hydrolysis. Moisture regain and dyeability improve by lipase hydrolysis on PET fabrics. -
This paper is intended to determine the optimal processing parameters applied to the dyeing procedure so that the desired color strength of a raw fabric can be achieved. Moreover, the processing parameters are also used for constructing a system to predict the fabric quality. The fabric selected is the nylon and Lycra blend. The dyestuff used for dyeing is acid dyestuff and the dyeing method is one-bath-two-section. The Taguchi quality method is applied for parameter design. The analysis of variance (ANOVA) is applied to arrange the optimal condition, significant factors and the percentage contributions. In the experiment, according to the target value, a confirmation experiment is conducted to evaluate the reliability. Furthermore, the genetic algorithm (GA) is combined with the back propagation neural network (BPNN) in order to establish the forecasting system for searching the best connecting weights of BPNN. It can be shown that this combination not only enhances the efficiency of the learning algorithm, but also decreases the dependency of the initial condition during the network training. Most of all, the robustness of the learning algorithm will be increased and the quality characteristic of fabric will be precisely predicted.
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The cotton fabrics were pretreated by sodium 2-(2,3-dibromopropionylamino)-5-(4,6-dichloro-1,3,5-triazinylamino) benzenesulfonate (DBDCBS) at alkaline condition ofroom temperature and then dyed with four disperse dyes having amino groups (C.I. Disperse Yellow 9, C.I. Disperse Red 11, C.I. Disperse Blue 56 and C.I. Disperse Violet 1) at acidic condition of high temperature. A novel hetero-bifunctional bridge compound, DBDCBS, has two reactive groups such as dichloro-striazinyl group and
${\alpha},\;{\beta}$ -dibromopropionylamido group. The first has reactivity towards hydroxy group of cellulosic fiber and the second shows reactivity towards amino groups of disperse dye containing amino groups. The results indicate that it is possible to dye polyester/cotton blend at one-bath dyeing using one kind of disperse dye containing amino groups. Therefore, two kinds of dyeing methods such as two-bath process one-bath dyeing and one-bath process one-bath dyeing were investigated and their dyeabilities were compared. The differences between these two methods were negligibly small so that perfect one-bath one-step dyeing of polyester/cotton blend by one kind of disperse dye was achieved. -
Thermotropic liquid crystal polymer (TLCP)-reinforced poly(butylene terephthalate) (PBT) composites were prepared by melt processing. The improvement in the mechanical properties and the processability of the PBT/TLCP composites was attributed to the reinforcing effect by TLCP phase and its well distribution in the PBT matrix. X-ray diffraction results demonstrated that a slow cooling process leads to the thicker lamellar structures and the formation of more regular crystallites in the composites. The incorporation of TLCP improves not only the tensile strength and flexural modulus but also the heat distortion temperature (HDT) of the PBT/TLCP composites. The HDT values of the composites were dependent on TLCP content. The improvement in the HDT values of the PBT/TLCP composites may be explained in terms with the increased flexural modulus, the development of more regular crystalline structures, and the enhancement of the ability of the composites to sustain the storage modulus by TLCP phase. In addition, the simple additivity rule makes it possible to predict the HDT values of the PBT/TLCP composites.
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Baik, Doo-Hyun;Kim, Hae-Young;Kwon, Sun-Jin;Kwon, Myung-Hyun;Lee, Han-Sup;Youk, Ji-Ho;Seo, Seung-Won 367
Thermal properties of copolyetherester/silica nanocomposites were examined by using DSC and TGA. The segmented block copolyetheresters with various hard segment structures and hard segment contents (HSC) were synthesized and their silica nanocomposite films were prepared by solution casting method. The nano-sized fumed silica particles were found to act as a nucleating agent of the copolyetheresters. The nanocomposites always showed reduced degree of supercooling or faster crystallization than the corresponding copolyetheresters. The nanocomposites also showed increased hard segment crystallinity except HSC 35 sample which had short hard segment length. In case of 2GT [poly(ethylene terephthalate)] copolyetheresters, which were not developed commercially because of their low crystallization rate, the hard segment crystallinity increased considerably. The copolyetherester/silica nanocomposites showed better thermal stability than copolyetheresters. -
The surface topography, tensile properties, and thermal properties of ramie fibers were investigated as reinforcement for fully biodegradable and environmental-friendly 'green' composites. SEM micrographs of a longitudinal and cross sectional view of a single ramie fiber showed a fibrillar structure and rough surface with irregular cross-section, which is considered to provide good interfacial adhesion with polymer resin in composites. An average tensile strength, Young's modulus, and fracture strain of ramie fibers were measured to be 627 MPa, 31.8 GPa, and 2.7 %, respectively. The specific tensile properties of the ramie fiber calculated per unit density were found to be comparable to those of E-glass fibers. Ramie fibers exhibited good thermal stability after aging up to
$160^{\circ}C$ with no decrease in tensile strength or Young's modulus. However, at temperatures higher than$160^{\circ}C$ the tensile strength decreased significantly and its fracture behavior was also affected. The moisture content of the ramie fiber was 9.9 %. These properties make ramie fibers suitable as reinforcement for 'green' composites. Also, the green composites can be fabricated at temperatures up to$160^{\circ}C$ without reducing the fiber properties. -
Fully biodegradable and environment-friendly green composite specimens were made using ramie fibers and soy protein concentrate (SPC) resin. SPC was used as continuous phase resin in green composites. The SPC resin was plasticized with glycerin. Precuring and curing processes for the resin were optimized to obtain required mechanical properties. Unidirectional green composites were prepared by combining 65% (on weight basis) ramie fibers and SPC resin. The tensile strength and Young's modulus of these composites were significantly higher compared to those of pure SPC resin. Tensile and flexural properties of the composite in the longitudinal direction were moderate and found to be significantly higher than those of three common wood varieties. In the transverse direction, however, their properties were comparable with those of wood specimens. Scanning electron microscope (SEM) micrographs of the tensile fracture surfaces of the green composite indicated good interfacial bonding between ramie fibers and SPC resin. Theoretical values for tensile strength and Young's modulus, calculated using simple rule of mixture were higher than the experimentally obtained values. The main reasons for this discrepancy are loss of fiber alignment, voids and fiber compression due to resin shrinking during curing.
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The beneficial effects of graduated compression stockings (GCS) in prophylaxis and treatment of venous disorders of human lower extremity have been recognized. However, their pressure functional performances are variable and unstable in practical applications, and the exact mechanisms of action remain controversial. Direct surface pressure measurements and indirect material properties testing are not enough for fully understanding the interaction between stocking and leg. A three dimensional (3D) biomechanical mathematical model for numerically simulating the interaction between leg and GCS in dynamic wear was developed based on the actual geometry of the female leg obtained from 3D reconstruction of MR images and the real size and mechanical properties of the compression stocking prototype. The biomechanical solid leg model consists of bones and soft tissues, and an orthotropic shell model is built for the stocking hose. The dynamic putting-on process is simulated by defining the contact of finite relative sliding between the two objects. The surface pressure magnitude and distribution along the different height levels of the leg and stress profiles of stockings were simulated. As well, their dynamic alterations with time processing were quantitatively analyzed. Through validation, the simulated results showed a reasonable agreement with the experimental measurements, and the simulated pressure gradient distribution from the ankle to the thigh (100:67:30) accorded with the advised criterion by the European committee for standardization. The developed model can be used to predict and visualize the dynamic pressure and stress performances exerted by compression stocking in wear, and to optimize the material mechanical properties in stocking design, thus, helping us understand mechanisms of compression action and improving medical functions of GCS.
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Dimensional constants (k values) of single jersey fabrics made from
$LincLITE^{(R)}$ and conventional yams are calculated under dry, steam, full relaxation treatments. Fabrics were made under different tightness factors such as high, medium and low with different twist factors, twist directions and feeder blending.$LincLITE^{(R)}$ yarns made to get soft and bulkier effects with yam count of 39 tex and conventional yams made into 39 tex and 48 tex yam counts. Various effects on K values are analysed using correlation coefficients. K-values are increased with relaxation progression and have shown some differences between in$LincLITE^{(R)}$ and conventional fabrics, and feeder blended fabrics. Loop shape factor is highly affected by tightness factor, relaxation and feeder blending in$LincLITE^{(R)}$ fabrics, whereas twist factor not significantly effects on loop shape factor in conventional fabrics. Stitch density significantly increases with relaxation in conventional fabrics and no significant effect shows with$LincLITE^{(R)}$ fabrics. -
This study examines multiple quality optimization of the injection molding for Polyether Ether Ketone (PEEK). It also looks into the dimensional deviation and strength of screws that are reduced and improved for the molding quality, respectively. This study applies the Taguchi method to cut down on the number of experiments and combines grey relational analysis to determine the optimal processing parameters for multiple quality characteristics. The quality characteristics of this experiment are the screws' outer diameter, tensile strength and twisting strength. First, one should determine the processing parameters that may affect the injection molding with the
$L_{18}(2^1{\times}3^7)$ orthogonal, including mold temperature, pre-plasticity amount, injection pressure, injection speed, screw speed, packing pressure, packing time and cooling time. Then, the grey relational analysis, whose response table and response graph indicate the optimum processing parameters for multiple quality characteristics, is applied to resolve this drawback. The Taguchi method only takes a single quality characteristic into consideration. Finally, a processing parameter prediction system is established by using the back-propagation neural network. The percentage errors all fall within 2%, between the predicted values and the target values. This reveals that the prediction system established in this study produces excellent results. -
The paper presents information concerning metrological and technical characteristics of KTU-Griff-Tester device, the optimization of its parameters and the cases of its application. It was defined that the behaviour of textile material during its extraction through a rounded hole depends upon its structure. Variations of geometrical shape of woven and knitted specimens can be described by mathematical expressions of shortened epicycloids and Cassini ovals. It is shown that waving process of disc shaped specimen can be predicted on the basis of the law of sine curve. The examples of textiles treatment with different types of commercial softeners are presented, herewith showing the suitability (sensitiveness) of the new device to detect the changes of textile hand. Meantime it is shown that the level of materials anisotropy can be decided on the basis of transformations of specimen's geometrical shape.
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Spandex has been successfully applied on modified worsted spinning system to produce spandex core spun yam. However it's difficult to produce wool/spandex core-spun yam on woolen spinning system with the same modified device because the drafting device of the two systems is quite different. A new method is introduced to apply spandex on woolen spinning system in this paper. Core-spun yam produced in this way has good appearance and quality by comparing with normal yam. A series of experiments were carried out to study the influence of spandex drafting ratio and yam twist factor on tensile' properties and elasticity of core-spun yams. The results indicate that core-spun yam with spandex drawing ratio of 2.5 and twist factor of 13.63 has highest value of tenacity and breaking elongation.
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Roll drafting, a mechanical operation attenuating fiber bundles to an appropriate thickness, is an important operation unit for manufacturing staple yams. It influences not only the linear density regularity of the slivers or staple yams that are produced, but also the quality of the textile product and the efficiency of the thereafter processes. In this research, the dynamic states of the fiber bundle in the roll drafting zone were analyzed by simulation, based on the mathematical model that describes the dynamic behavior of the flowing bundle. The state variables are the linear density and velocity of the fiber bundles and we simulated the dynamics states of the bundle flow, e.g., the profiles of the linear density and velocity in the draft zone for various values of the model parameters and boundary conditions, including the initial conditions to obtain their influence on the dynamic state. Results showed that the mean velocity profile of the fiber bundle was strongly influenced by draft ratio and process speed, while the input sliver linear density has hardly affected the process dynamics. Velocity variance of individual fibers that could be supposed to be a disturbing factor in drafting was also influenced by the process speed. But the major disturbance occurred due to the velocity slope discontinuity at the front roll, which was strongly influenced by the process speed. Thickness of input sliver didn't play any important role in the process dynamics.
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High Modulus and high tenacity polypropylene fibers have been prepared by drawing on a gradient heater. Results show that fiber properties are significantly affected by temperature profiles of final stage drawing on a gradient heater. The gradient drawn filaments showed superior mechanical properties when compared to filaments drawn over a constant temperature heater. Fibers with initial modulus of 16.4 GPa and tenacity of 670 MPa have been manufactured in the process. The nature of the gradient drawing had a significant effect on end properties. The superior mechanical properties are attributed to the high crystal perfection and crystallinity and low void fractions obtained at high draw ratios when drawn over a gradient heater.
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An integrated platform for garment drape simulation system has been developed. In this system, garment patterns from conventional two-dimensional CAD systems can be assembled into a three-dimensional garment on a parametrically resizable realistic human body model. A fast and robust particle-based physical calculation engine has been developed for garment shape generation. Then a series of geometric and graphical techniques were applied to create realistic impressions on simulated garments. This system can be used as the rapid prototyping tool for garments in the future quick-response system.
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The purpose of this study was to compare the subjective fabric hand evaluation and wear comfort of PET treated by Ultraviolet and to evaluate the subjective results from the investigation of microclimate temperature. The subjective hand evaluation was performed by 20 subjects (age: 20-25) with 5-point scale questionnaires to investigate the change of PET knit fabrics treated for different times, specifically, 0, 30 and 90 minutes. The questionnaires were composite with 8 questions; roughness, smoothness, wetness, stiffness, coolness, touch, preference, and comfort. In order to evaluate sensations of wear comfort, we made garments with UV treated fabric and five female students were tested. They walked at the speed of 6.7 km/ hr for 15 minutes in an environment, which was controlled at
$29^{\circ}C,\;75{\pm}5%$ RH. Before and after exercising, the microclimate under clothing and subjective wear comfort was measured. The results of subjective evaluation of fabric hand were that untreated and treated for 30 minutes PET were recognized as similar and have a good evaluation on comfort, preference, and touch. According to the result of wear comfort, clothing treated by UV for 90 minutes had the lowest value on the thermal and humidity sensations. In addition, the value of tactile and comfort sensation was the highest on the clothing treated by UV for 90 minutes. In the case of objective evaluation, PET treated for 90 minutes was the lowest on microclimate humidity. PET irradiated by UV for 90 minutes was more 'cool' in thermal sensation and more 'dry' in wet sensation. Accordingly, it was consistent with the result of subjective wear comfort. -
The purpose of this study was to evaluate the comfort of PET clothing treated by UV. The physiological responses of the human body were investigated. Mean skin temperature and physiological signals such as Electroencephalogram (EEG), and heart rate (Electrocardiogram, (ECG)) were examined for 20 minutes during stable wearing conditions. Mean skin temperature was measured every two seconds using Ramanathan's method. Physiological responses were measured using Biopac MP100 series and analyzed using the software, Acqknowledge 3.5.2. Psychological effects were analyzed every five minutes. Comfort of untreated PET clothing decreased with the passage of time. Compared with PET clothing untreated, treated for 30 minutes, and treated for 90 minutes, the analysis of EEG showed that PET clothing treated for 90 minutes was the most comfortable after 20 minutes. In addition, the interval of the heart rate shown on the ECG was the highest in PET clothing treated for 90 minutes. Skin temperature was the lowest in PET treated for 90 minutes. We thus conclude that suitable UV irradiation would improve comfort.
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The objectives of this study were to investigate physiological and psychological responses to the rustling sound of Korean traditional silk fabrics and to figure out objective measurements such as sound parameters and mechanical properties determining the human responses. Five different traditional silk fabrics were selected by cluster analysis and their sound characteristics were observed in terms of FFT spectra and some calculated sound parameters including level pressure of total sound (LPT), Zwicker's psychoacoustic parameters - loudness(Z), sharpness(Z), roughness(Z), and fluctuation strength(Z), and sound color factors such as
${\Delta}L\;and\;{\Delta}f$ . As physiological signals, the ratio of low frequency to high frequency (LF/HF) from the power spectrum of heart rate variability, pulse volume (PV), heart rate (HR), and skin conductance level (SCL) evoked by the fabric sounds were measured from thirty participants. Also, seven aspects of psychological state including softness, loudness, sharpness, roughness, clearness, highness, and pleasantness were evaluated when each sound was presented. The traditional silk fabric sounds were likely to be felt as soft and pleasant rather than clear and high, which seemed to evoke less change of both LF/HF and SCL indicating a negative sensation than other fabrics previously reported. As fluctuation strength(Z) were higher and bending rigidity (B) values lower, the fabrics tended to be perceived as sounding softer, which resulted in increase of PV changes. The higher LPT was concerned with higher rating for subjective loudness so that HR was more increased. Also, compression linearity (LC) affected subjective pleasantness positively, which caused less changes of HR. Therefore, we concluded that such objective measurements as LPT, fluctuation strength(Z), bending rigidity (B), and compression linearity (LC) were significant factors affecting physiological and psychological responses to the sounds of Korean traditional silk fabrics.