• Title/Summary/Keyword: 3-D nanostructure

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Ruthenium Oxide Electrode Deposited on 3D Nanostructured-nickel Current Collector and Its Application to Supercapacitors

  • Ryu, Ilhwan;Kim, Green;Park, Dasom;Yim, Sanggyu
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.181.1-181.1
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    • 2014
  • Supercapacitor is attracting growing attention for a promising energy conversion and storage device because of its desirable electrochemical properties such as rapid charge-discharge rate, high power density and long cycle life. Three-dimensional (3D) metal nanostructure has been widely studied since it can provide efficient charge transport along the 3D network in many device applications. In this work, we fabricated well-ordered 3D nickel (Ni) nanostructures using 3D-arrayed polystyrene nano-opal substrates. We also fabricated half-cell supercapacitors by electrodepositing $RuO_2$ onto these nanostructured Ni current collectors and investigated their morphological and electrochemical properties.

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Bio-Inspired Micro/Nanostructures for Functional Applications: A Mini-Review

  • Young Jung;Inkyu Park
    • Journal of Sensor Science and Technology
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    • v.32 no.1
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    • pp.31-38
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    • 2023
  • Three-dimensional (3D) micro/nanostructures based on soft elastomers have received extensive attention in recent years, owing to their potential and advanced applicability. Designing and fabricating 3D micro/nanostructures are crucial for applications in diverse engineering fields, such as sensors, harvesting devices, functional surfaces, and adhesive patches. However, because of their structural complexity, fabricating soft-elastomer-based 3D micro/nanostructures with a low cost and simple process remains a challenge. Bio-inspired designs that mimic natural structures, or replicate their micro/nanostructure surfaces, have greatly benefited in terms of low-cost fabrication, scalability, and easy control of geometrical parameters. This review highlights recent advances in 3D micro/nanostructures inspired by nature for diverse potential and advanced applications, including flexible pressure sensors, energy-harvesting devices based on triboelectricity, superhydrophobic/-philic surfaces, and dry/wet adhesive patches.

Microstructural analysis and characterization of 1-D ZnO nanorods grown on various substrates (다양한 기판위에 성장한 1차원 ZnO 나노막대의 특성평가 및 미세구조 분석)

  • Kong, Bo-Hyun;Kim, Dong-Chan;Cho, Hyung-Koun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.116-117
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    • 2006
  • I-D ZnO nanostructures were fabricated by thermal evaporation method on Si(100), GaN and $Al_2O_3$ substrates without a catalyst at the reaction temperature of $700^{\circ}C$. Only pure Zn powder was used as a source material and Ar was used as a carrier gas. The shape and growth direction of synthesized ZnO nanostructures is determined by the crystal structure and the lattice mismatch between ZnO and substrates. The ZnO nanostructure on Si substrate were inclined regardless of their substrate orientation. The origin of ZnO/Si interface is highly lattice-mismatched and the surface of the Si substrate inevitably has the $SiO_2$ layer. The ZnO nanostructure on the $Al_2O_3$ substrate was synthesized into the rod shape and grown into particular direction. For the GaN substrate, however, ZnO nanostructure with the honeycomb-like shape was vertically grown, owing to the similar lattice parameter with GaN substrate.

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Study on the Preparation of TiO2 3D Nanostructure for Photocatalyst by Wet Chemical Process (습식화학공정에 의한 광촉매용 TiO2 3차원 나노구조체 제조 연구)

  • Lee, Duk-Hee;Park, Jae-Ryang;Lee, Chan-Gi;Park, Kyoung-Tae;Park, Kyung-Soo
    • Journal of Powder Materials
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    • v.27 no.5
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    • pp.381-387
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    • 2020
  • In this work, TiO2 3D nanostructures (TF30) were prepared via a facile wet chemical process using ammonium hexafluorotitanate. The synthesized 3D TiO2 nanostructures exhibited well-defined crystalline and hierarchical structures assembled from TiO2 nanorods with different thicknesses and diameters, which comprised numerous small beads. Moreover, the maximum specific surface area of TiO2 3D nanostructures was observed to be 191 ㎡g-1, with concentration of F ions on the surface being 2 at%. The TiO2 3D nanostructures were tested as photocatalysts under UV irradiation using Rhodamine B solution in order to determine their photocatalytic performance. The TiO2 3D nanostructures showed a higher photocatalytic activity than that of the other TiO2 samples, which was likely associated with the combined effects of a high crystallinity, unique features of the hierarchical structure, a high specific surface area, and the advantage of adsorbing F ions.

Improvement of joining strength between aluminum alloy and polymer by two - step anodization

  • Lee, Sung-Hyung;Yashiro, Hitoshi;Kure-Chu, Song-Zhu
    • Journal of the Korean institute of surface engineering
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    • v.53 no.4
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    • pp.144-152
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    • 2020
  • In the manufacturing process of joining of aluminum alloy and polymer, the strength of the metal-polymer joining is greatly influenced by the nanostructure of the oxide film. In this study, we investigated the dependence of joining strength on the thickness, structure, pore formation and surface roughness of the formed film. After the two-step anodization process, the surface oxide layer became thinner and rougher resulting in higher joining strength with the polymer. More specifically, after the two-step anodization, the surface roughness, Ra increased from 2.3 to 3.2 ㎛ with pore of three-dimensional (3D) nanostructure, and the thickness of the oxide film was thinned from 350 to 250 nm. Accordingly, the joining strength of the aluminum alloy with polymer increased from 23 to 30 MPa.

Enhancement of Electrochemical and Mechanical Properties of 3D Graphene Nanostructures by Dopamine-coating (도파민 코팅을 이용한 3차원 그래핀 나노 구조체의 전기화학적/기계적 특성 향상 연구)

  • Lee, Guk Hwan;Luan, Van Hoang;Han, Jong Hun;Kang, Hyun Wook;Lee, Wonoh
    • Composites Research
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    • v.32 no.6
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    • pp.388-394
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    • 2019
  • Inherited the excellent electrical and mechanical properties based on the low dimensional structure of graphene, three-dimensional graphene nanostructures have gathered great attention as electrochemical energy storage electrodes owing to their high porosity and large specific surface area. Also, having the catecholamine structure, dopamine has been regarded as a multifunctional material to possess high affinity to various organic/inorganic materials and to modify a hydrophobic surface to a hydrophilic one. In this work, through coating dopamine on the three-dimensional graphene nanostructure, we tried to increase the specific capacitance by enhancing the wettability with electrolyte and to improve the mechanical compressive property by strengthening the nano-architecture. As a result, the dopamine-coated nanostructure exhibited significant improvement on the specific capacitance (51.5% increase) and compressive stress (59.6% increase).

3-dimensional nanostructured ZnO gas sensor (3차원 ZnO 나노구조체 가스센서)

  • Park, Yong-Wook;Shin, Hyun-Yong;Yoon, Seok-Jin
    • Journal of Sensor Science and Technology
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    • v.19 no.5
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    • pp.356-360
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    • 2010
  • Due to the high surface-to-volume ratio, the 3-dimensional(3D) nanostructures of metal oxides are regarded as the best candidate materials for the chemical gas sensors. Here we have synthesised flower-like 3D zinc oxide nanostructures through a simple hydrothermal route. Specific surface area of the 3D zinc oxide nanostructures synthesised in different pH values from 9.0 to 12.0 were evaluated by using a BET analyzer and the results were compared with that of a zinc oxide thin film fabricated by rf sputtering. Using interdigitated electrodes, superior CO gas sensing properties of the 3D zinc oxide nanostructures on the ZnO thin film to those of the ZnO thin film were demonstrated.

Rational Design and Facile Fabrication of Tunable Nanostructures towards Biomedical Applications

  • Yu, Eun-A;Choe, Jong-Ho;Park, Gyu-Hwan
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.105.2-105.2
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    • 2016
  • For the rational design and facile fabrication of novel nanostructures, we present a new approach to generating arrays of three-dimensionally tunable nanostructures by exploiting light-matter interaction. To create controlled three-dimensional (3D) nanostructures, we utilize the 3D spatial distribution of light, induced by the light-matter interaction, within the matter to be patterned. As a systematic approach, we establish 3D modeling that integrates the physical and chemical effects of the photolithographic process. Based on a comprehensive analysis of structural formation process and nanoscale features through this modeling, we are able to realize three-dimensionally tunable nanostructures using facile photolithographic process. Here we first demonstrate the arrays of three-dimensionally controlled, stacked nanostructures with nanoscale, tunable layers. We expect that the promising strategy would open new opportunities to produce the arrays of tunable 3D nanostructures using more accessible and facile fabrication process for various biomedical applications ranging from biosensors to drug delivery devices.

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