• Title/Summary/Keyword: Acetone

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Effects of Intraruminal versus Intravenous Infusions of Acetone on the Ruminating and Masticating Behavior of Goats

  • Asato, N.;Hirayama, T.;Higa, T.;Onodera, R.;Shinjo, A.;Oshiro, S.
    • Asian-Australasian Journal of Animal Sciences
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    • v.16 no.2
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    • pp.198-203
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    • 2003
  • Acetone, which is produced from butyric acid when it passes through the rumen wall, was infused into the rumen and jugular veins of three female goats to investigate the role of acetone in ruminating and masticating behavior. The ruminating behavior, as measured by the number of boli and the ruminating time, decreased (p<0.05) with intraruminal acetone infusion. However, the ruminating behavior did not change significantly in response to intravenous acetone infusion. Feed intake significantly decreased with intraruminal acetone infusion, but not with intravenous acetone infusion. The concentrations of acetone in the plasma increased significantly (p<0.05) with both acetone infusion regions. Ruminal fluid acetone, and isopropyl alcohol (IPA), which is one of the ketone bodies, produced from acetone by bacterial action in rumen, concentrations were significantly increased (p<0.05) with both acetone infusion regions. These results suggest that the chemoreceptors sensitive to acetone are more likely to be in the rumen epithelium, portal system, or liver, where they can respond to acetone levels.

A Study on the Development of Early Acetone Gas Detection to Prevent the Acetone Leakage Accident (아세톤 누출사고 예방을 위한 아세톤 가스 조기감지 기술개발에 관한 연구)

  • Seung Jin Jeon;Youngbo Choi
    • Journal of the Korean Society of Safety
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    • v.38 no.2
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    • pp.30-35
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    • 2023
  • Acetone is a widely used Volatile Organic Compound (VOC) in industries and laboratories. However, acetone affects human health adversely and causes fires and explosions. Early acetone detection and improved personnel training in safety and emergency management are necessary to prevent acetone-related accidents. The multi-VOC acetone detectors used currently have a sensitivity and selectivity limit. In this study, we discovered that Pt-loaded iron oxide (a metal oxide semiconductor) conversely, has high detection and selectivity for very low-levels of acetone gas. The loaded Pt catalyzes the reaction between the sensing materials' surface and the oxygen molecules in the air; this optimizes acetone detection and can decrease acetone-related illnesses, fires and explosions.

The Measurement and Investigation of Fire and Explosion Properties for Acetone (아세톤의 화재 및 폭발 특성치 측정 및 고찰)

  • Ha, Dong-Myeong
    • Journal of the Korean Society of Safety
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    • v.25 no.4
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    • pp.30-35
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    • 2010
  • For the safe handling of acetone, the flash point, the explosion limit at $25^{\circ}C$ and the temperature dependence of the explosion limits were investigated. And the AIT for acetone were experimented. By using the literatures data, the lower and upper explosion limits of acetone recommended 2.5 vol% and 13.0 vol%, respectively. In this study, the lower flash points of acetone recommended $-20^{\circ}C$. This study was determined relationship between the AITs and the ignition delay times by using ASTM E659-78 apparatus for acetone, and the experimental AIT of acetone was $565^{\circ}C$. The new equations for predicting the temperature dependence of the explosion limits of acetone is proposed. The values calculated by the proposed equations were a good agreement with the literature data.

Removal Characteristics of Single and Binary Vapors of Acetone, Toluene, and Methyl Mercaptan by Cylindrical UV Reactor Installed with TiO2-Coated Perforated Plane (TiO2를 코팅한 다공판을 설치한 원통형 UV 반응기에 의한 아세톤, 톨루엔, 메틸메르캅탄 단일 증기 및 2성분 혼합증기의 제거특성)

  • Jeon, Jin-Woo;Kam, Sang-Kyu;Lee, Min-Gyu
    • Journal of Environmental Science International
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    • v.24 no.3
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    • pp.317-322
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    • 2015
  • The photocatalytic decomposition characteristics of toluene, acetone, and methyl mercaptan (MM) by UV reactor installed with $TiO_2$-coated perforated plane were studied. The removal efficiency of single toluene, acetone, and MM vapor was increased with increasing oxygen concentration, but decreased with increasing inlet concentration. Elimination capacity of single toluene, acetone, and MM vapor was obtained to be $628g/m^3{\cdot}day$, $1,041g/m^3{\cdot}day$, and $2,158g/m^3{\cdot}day$, respectively. Also, the photocatalytic decomposition of binary vapor consisted of toluene and acetone, toluene and MM, acetone and MM were observed. Elimination capacity of toluene mixed with acetone, toluene mixed with MM, acetone mixed with toluene, acetone mixed with MM, MM mixed with toluene, and MM mixed with acetone was $327g/m^3{\cdot}day$, $512g/m^3{\cdot}day$, $128g/m^3{\cdot}day$, $266g/m^3{\cdot}day$, $785g/m^3{\cdot}day$ and $883g/m^3{\cdot}day$, respectively. The inhibitory effect of acetone was higher than MM in photocatalytic decomposition of toluene, the inhibitory effect of toluene was higher than MM photocatalytic decomposition of acetone, and the inhibitory effect of toluene was higher than acetone in photocatalytic decomposition of MM.

Effect of Gel Nail Remover Liquid on Nail According to Acetone Concentrationon (아세톤 농도에 따른 젤네일 리무버액이 손톱에 미치는 영향)

  • Kim, Young-Hee;Li, Shun-Hua
    • Journal of the Korean Applied Science and Technology
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    • v.36 no.1
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    • pp.248-257
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    • 2019
  • On this study, we have observed the change of the gel nail morphology as the time elapse and measured the surface roughness/volume, moisture content/purcutaneous moisture vaporizing amount of the nail surface before gel nail treatment and after gel nail removing of the 100%acetone remover, 5%acetone remover and 0%acetone remover and the avocado non acetone remover for the comparison of the effect on the nail surface and the degree of the removing of the gel nail of the removers as the acetone contents. The removing ability were the order of 100%acetone remover, avocado non acetone remover, 5%acetone remover and the 0%acetone remover. There were no statistical significance difference in the nail surface roughness comparision before and after gel nail removing in 5%acetone, 0%acetone and avocado non acetone, and there was no statistical significance difference in the nail surface volume comparision before and after gel nail removing in 0%acetone. We measured the moisture content of the nail surface and the purcutaneous moisture vaporizing amount before gel nail treatment and after gel nail removing, resulted that, the decrease of the moisture content of the nail surface after removing the gel nail is the minimun and the increase of the purcutaneous moisture vaporizing amount of the nail surface after removing the gel nail is the minimun at the case of 0%acetone. In conclusion, 5%acetone remover and 0%acetone remover is possible to use as the gel nail remover and they had revealed that there was the least harmful effect on the nail. We hope that this study is utilized to the development of the non acetone remover and the basic research of the nail beauty industry.

Interaction of acetone molecule on Si(001) surface: A theoretical study (Si(001) 표면과 acetone 분자의 상호작용에 대한 이론적 연구)

  • Baek, Seung-Bin;Kim, Dae-Hee;Kim, Yeong-Cheol
    • Journal of the Semiconductor & Display Technology
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    • v.7 no.3
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    • pp.35-39
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    • 2008
  • We study the interaction of acetone molecule $[(CH_3)_2CO]$ on Si(001) surface using density functional theory. An acetone molecule is adsorbed on a Si atom of the Si dimer of the Si(001) surface. The adsorption of the acetone molecule on the Si atom at lower height between the two Si atoms of the dimer is more favorable than that on the Si atoms at upper height. Then we calculate an energy variation of dissociation and four-membered ring structures of the acetone molecule adsorbed on the Si surface. Total energy difference between the two structures is about 0.05 eV, indicating that the two structures are almost equally stable. Energy barrier exists when a hydrogen atom is dissociated and adsorbed on the other Si atom of the dimer, while energy barrier does not exist when the adsorbed acetone molecule changes to four-membered ring structure, except for the rotation of the acetone molecule along z-direction. Therefore, four-membered ring structure is kinetically more favorable than the dissociation structure when the acetone molecule is adsorbed on the Si(001) surface.

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Characteristics of Acetone Enhancement of Microsomal Cytochrome P45O-dependent B(a)P Hydroxylation in 3-Methylcholanthrene-inducible Rat Liver Microsomes

  • Lee, Dong-Wook;Moon, Ja-Young;Lim, Heung-Bin;Sohn, Hyung-Ok;Lee, Young-Gu;Park, Ki-Hyun
    • Journal of the Korean Society of Tobacco Science
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    • v.20 no.2
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    • pp.178-182
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    • 1998
  • Previously, we showed that acetone enhanced aryl hydrocarbon hydroxylase (AHH) activity in only 3-methylcholanthrene (MC)- or $\beta$-naphtoflavone (BNF)-inducible microsomes of rat liver. In the present study, the possible mechanism underlying acetone action on AHH was investigated in the liver microsomes from MC-pretreated rats. Other n-alkylketones except acetone did not increase AHH activity, which rather decreased significantly with the length of alkyl side chain. Acetone had no effect on the activity of NADPH-cytochrome P450 reductase or inhibited the formation of 3-OH benzo(a)pyrene (B(a)P) in nonenzymatic model ascorbic acid system. However, in cumene hydroperoxide (CuOOH)-supported B(a)P hydroxylation, acetone enhanced its velocity remarkably by 30% at the optimal concentration (30 $\mu$M CuOOH and 1.0% acetone). From these results, we conclude that acetone may facilitate the formation of an activated oxygen species or the insertion of oxygen into B(a)P molecule in CYP1A rich microsomes.

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Comparison of Phytoplankton Chlorophyll-$\alpha$ Extracted with Different Solvents

  • Lee, Yun-Kyoung;Shin, Myoung-Sun;Jung, Yu-Kyong;Jang, Chang-Won;Kim, Bom-Chul
    • Korean Journal of Ecology and Environment
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    • v.41 no.4
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    • pp.485-489
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    • 2008
  • Algal chlorophyll-$\alpha$ is commonly determined by spectro-photometric method using 90% acetone as solvents. However, acetone has low extraction efficiency without grinding filters, and DMF (dimethyl formamide) was tested for the compatibility with acetone. Chlorophyll-$\alpha$ concentration was determined for samples from 5 reservoirs of different trophic states and phytoplankton composition, using acetone extraction with grinding and DMF without grinding. Chlorophyll-$\alpha$ measured by DMF and Acetone did not show a significant difference when using trichromatic method of UNESCO and Lorenzen, and therefore, DMF can substitute acetone. But when acidification method was applied, they showed significant difference of 8%. It can be concluded that DMF can extract chlorophylls more effectively without grinding and it can be a better alternative for the standard extraction solvent.

Enantioselective Hydrolysis of (R,S)-Naproxen Methyl Ester Using Two-step Acetone-treated Candida rugosa Lipase (2단계 아세톤 침전법으로부터 얻어진 Candida rugosa Lipase를 이용한 (R,S)-Naproxen Ester의 광학선택성 수화반응)

  • 이은교;최순자;정봉현
    • Microbiology and Biotechnology Letters
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    • v.28 no.4
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    • pp.223-227
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    • 2000
  • A novel two-step acetone treatment method was developed to enhance the enantioselectivity of Candida rugosa lipase (CRL) toward the hydrolysis of racemic naproxen methyl ester. The acetone-teated CRL was considerably more enantioselective than the crude CRL, yielding an enantiomeric excess of 98~100%. The crude and acetone-treated CRLs were subjected to anion exchange chromatography, and their chromatography profiles were compared. In consequence, both chromatography profiles were found to be almost identical, resulting in two separate lipase peaks (lipase A and B). The lipase B, which is known to be less enantioselective, was treated with acetone using a two-step treatment method. The enantioselectivity of acetone-treated lipase B was dramatically increased, yielding an enantiomeric excess of 99%.

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Photolysis of a New Insecticide KH-502 [O,O-diethyl O-(1-phenyl-3- trifluoromethyl-5-pyrazolyn) thiophosphoric acid ester] (신규(新規) 살충제(殺蟲劑)인 KH-502 [O,O-Diethyl O-(1-phenyl-3-trifluoromethyl-5-pyrazoyl) thiophosphoric acid ester]의 광(光)에 의한 분해성(分解性))

  • Cho, Boo-Yeon;Han, Dae-Sung;Yang, Jae-E
    • Korean Journal of Environmental Agriculture
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    • v.12 no.2
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    • pp.176-183
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    • 1993
  • Photolysis experiments were conducted to investigate the stability of a new insecticide, [O,O-Diethyl O-(1-phenyl-3-trifluoromethyl-5-pyrazoyl) thiophosphoric acid ester: KH-502] under the various conditions. In the photolysis experiment, KH-502 was, after being added into the acetone or acetonitrile solution, irradiated under the sunlight or UV lamp $(300{\sim}350nm)$, where acetone or acetonitrile solution was varied with water and $O_2$contents and was treated with humic acid, rosebengal or tryptophan. Results for stability and degradation pattern of KH-502 from the above experiment can be summarized as follows: 1. The significant difference in KH-502 decomposition due to photolysis was shown for between KH-502s irradiated at $300{\sim}350$ nm and non-irradiated. KH-502 was photolyzed in the acetone by the sensitizing effect, but was stable in the acetonitrile. 2. The degradation pattern of KH-502 in the photolysis was different as compared to that in the thermal decomposition, and the decomposed products were O,O-Diethyl O-(1-phenyl-3-trifluoromethyl-5-pyrazoyl)phosphoric acid ester (KH-502 oxo form), O,S-Diethyl O-(1-phenyl-3-trifluoromethyl-5-pyrazoyl)phosphorothiolate(S-ethyl KH-502), 1-Phenyl-3-trifluoromethyl-5-hydroxy pyrazole (PTMHP) and several unknown compounds. 3. Treatments of acetone or acetonitrile solution with humic acid, rosebengal or tryptophan revealed no-sensitizing effect on the photolysis of KH-502. Dissolved oxygen in the acetone played as a cosensitizer with acetone competitively to enhance the photolysis of KH-502. 4. Treatments of acetone with humic acid or paddy soil water collected from fields decreased the photolysis of KH-502.

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