• Title/Summary/Keyword: Aqueous Solution

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Study on Maillard Reaction Products Derived from Aqueous and Ethanolic Fructose-Glycine and Its Oligomer Solutions

  • Kim, Ji-Sang
    • Preventive Nutrition and Food Science
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    • v.15 no.4
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    • pp.297-303
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    • 2010
  • The present study compared the Maillard reaction products (MRPs) derived from aqueous and ethanolic fructoseglycine and its oligomer (dimer and trimer) solutions. The pH was lower in glycine (G) than in diglycine (DG) and triglycine (TG) in both aqueous and ethanolic solutions, but the pH difference between the DG and TG was not significant. MRPs derived from the DG had a greater absorbance at 294 and 420 nm in ethanolic solution than in an aqueous solution. In particular, the loss of sugar was higher in ethanolic solution than in aqueous solution. Enolization of fructose was observed in both aqueous and ethanolic MRP solutions; however, enolization was not observed for the G in aqueous MRP solutions. The glycine oligomer content in ethanolic MRP solutions remained higher than that in aqueous MRP solutions. Furthermore, neither diglycine nor triglycine were detected in the G aqueous or ethanolic MRP solutions, while triglycine was detected in both the DG aqueous and ethanolic MRP solutions. Absorption in the ultraviolet-visible (UV-Vis) spectra was higher with MRPs derived from the ethanolic solution than with those derived from the aqueous solution. MRPs derived from the DG in an ethanolic solution showed the highest absorption intensity.

Effect of pressurization on dissolution of a supercooled aqueous solution with a stationary state (가압조건이 정지상태 과냉각 수용액의 해소에 미치는 영향)

  • Kim, Byung-Seon;Peck, Jong-Hyun;Hong, Hi-Ki;Kang, Chae-Dong
    • Proceedings of the SAREK Conference
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    • 2006.06a
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    • pp.132-137
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    • 2006
  • Supercooled type ice slurry system is hard to keep a proper supercooling degree when solution becomes supercooling state. This is the reason of the ice blockage in pipe or cooling part due to an unstable cooling state. In this study, a cooling experiment was performed to pressurized solution in a stationary state. The behaviors during the supercooled aqueous solution were investigated at fixed flow rate of brine and aqueous solution of ethylene glycol 7 mass%. Also the effect to the freezing point of supercooled aqueous solution was investigated to the different pressure 101, 202, 303, and 404 kPa. At results, the pressure of the aqueous solution in the cylinder increased the supercooling degree increased and dissolution of supercooled point decreased.

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Studies on the Stability of Hexamine Aqueous Solution (Hexamine 수용액의 안정성에 관한 연구)

  • 우종학
    • YAKHAK HOEJI
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    • v.7 no.2_3
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    • pp.51-54
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    • 1963
  • In this experiment, it is found that the decomposition reaction of hexamine aqueous solution by heat is the pseudo first order reaction and the calculated decomposition velocity constants of Hexamine aqueous solution are 1.17 * $10^{-5}min.^{-1}(60{\deg}$ C), 1.99 * $10^{-5}min.^{-1}(70{\deg}$ C), 2.35 * $10^{-5}min.^{-1}(80{\deg}$ C), 6.63 * $10^{-5}min.^{-1}(100{\deg}$ C). In the result, the activation energy of decomposition reaction of hexamine aqueous solution is 12 $Cal.mole^{-1}$.

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Effect of Pressurization and Cooling Rate on Dissolution of a Stationary Supercooled Aqueous Solution (정지상태 수용액에서 가압과 냉각속도가 과냉각해소에 미치는 영향)

  • Kim, Byung-Seon;Peck, Jong-Hyun;Hong, Hi-Ki;Kang, Chae-Dong
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.19 no.12
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    • pp.850-856
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    • 2007
  • In a supercooled or capsule type ice storage system, aqueous solution (or water) may have trouble with non-uniform dissolution though the system contributes to the simplicity of system and ecological improvement. The non-uniform dissolution increases the instability of the system because it may cause an ice blockage in pipe or cooling part. In order to observe the supercooled state, a cooling experiment was performed with pressurization to an ethylene glycol(EG) 3 mass% solution in stationary state. Also, the effect of the pressurization from 101 to 505 kPa to the dissolution of supercooled aqueous solution was measured with the dissolution time of the supercooled aqueous solution at a fixed cooling rate of brine. At results, the dissolution of supercooled point decreased as the pressure of the aqueous solution in the vessel increased. Moreover, the dissolution point increased as the heat flux for cooling increased.

The Effect of Molecular Weight on the Gelation Behavior of Regenerated Silk Solutions

  • Cho, Hee-Jung;Um, In-Chul
    • International Journal of Industrial Entomology and Biomaterials
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    • v.23 no.1
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    • pp.183-186
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    • 2011
  • The various molecular weight (MW) regenerated silk fibroins were prepared with different dissolution condition and the effect of MW on the gelation behavior of regenerated aqueous silk fibroin (SF) solution was investigated. The result of gelation time measurement indicated that the gelation of SF aqueous solution was accelerated by the increase of MW and SF concentration. When formic acid was added in SF aqueous solution, the gelation time of SFL and SFC30 aqueous solution showed a significant decreaseat 0.03% formic acid addition. In case of the lowest MW sample, SFC180, SF molecules became aggregated and precipitated without gelation after 28 days storage time. These findings indicate that MW control of SF can be utilized to control the gelation time of SF aqueous solution.

Evaluation of Early Strength of Red Clay Soil with Polymer Aqueous Solution (폴리머수용액을 첨가한 황토의 초기강도 평가)

  • Kim, Jin-Sung;Lee, Bo-Kyeong;Lee, Dong-Eun;Choi, Hyeong-Gil
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2019.11a
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    • pp.145-146
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    • 2019
  • In this study, we evaluated the early strength of red clay soil with the polymer aqueous solution at rammed earth construction. In order to satisfy the demolding strength of the formwork be due to the rammed of red clay soil, the polymer aqueous solution was added to evaluate the compressive strength at the early age according to the consolidation level. As a result, a high compressive strength was exhibited with the formulation to which the polymer aqueous solution was added.

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Heat and Mass Transfer Characteristics of LiCl Aqueous Solution for a Plate Heat Exchanger Type Dehumidifier (판형 열교환기식 제습기에서 LiCl 수용액의 열 및 물질전달 특성)

  • Jeon, Dong-Soon;Lee, Hae-Seung;Kim, Seon-Chang;Kim, Young-Lyoul
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.24 no.1
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    • pp.16-22
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    • 2012
  • Experimental investigations were carried out to examine the heat and mass transfer characteristics of LiCl aqueous solution for a plate heat exchanger type dehumidifier. Cooling dehumidification was adopted vertical type heat exchanger. Also non woven fabric is attached surface of the heat exchanger for spreadability of LiCl aqueous solution. Mass flow-rate of LiCl aqueous solution and concentration were selected as experimental conditions. Also, In this study, the effects of relative humidity of process air and velocity were investigated experimentally. As a result of heat transfer coefficient and mass transfer coefficient of were increased film reynolds number increased. heat transfer coefficient and mass transfer coefficient of LiCl aqueous solution were 0.14~0.24 kW/$m2^{\circ}C$ and $1.3{\times}10-63{\sim}6.2{\times}10-6$ m/s respectively.

A Study on Oxidation Characteristics and Phytoncide Oil Decomposition Characteristics of Aqueous Solution by 400 kHz Medium Frequency Ultrasound (400 kHz 중주파 초음파에 의한 수용액의 산화특성 및 피톤치드 오일 분해특성에 대한 연구)

  • Hwangbo, Sunae;Kim, Buan;Moon, Changkwan
    • Particle and aerosol research
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    • v.13 no.3
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    • pp.127-132
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    • 2017
  • In this paper, the effect of the irradiation of the median-frequency of ultrasonic wave on the aqueous solution have been investigated. In addition, the decomposition ability of radical species was observed using phytoncide oil of 0.1 wt %. By observing the degree of decomposition while maintaining magnetic stirring, the unirradiated aqueous solution maintained turbid condition and the particle size of the oil was the same as the initial size. On the other hand, the irradiated aqueous solution presented that the transparency degree became good after 3 days and became to the same as the original purified water after one week. The particle size of the after 3 days was about 0.1 to $0.5{\mu}m$. From these results it could be demonstrated that when a medium frequency (about 400 kHz) is applied to the aqueous solution, decomposition ability of radical species are formed and the medium frequency irradiation system can be possible to purify the turbid aqueous solution.

Selective Dissolution of ZnO Crystal by a Two-step Thermal Aging in Aqueous Solution (수용액 합성법의 2단계 성장온도 변화를 통한 ZnO 결정의 선택적 용해 현상)

  • Kim, Jeong-Seog;Chae, Ki-Woong
    • Journal of the Korean Ceramic Society
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    • v.48 no.4
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    • pp.263-268
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    • 2011
  • ZnO hexagonal rods grown in aqueous solution can be changed into a tubular shape by two-step aging in the course of the growing process. In the first step, hexagonal ZnO rods is grown by aging at $90^{\circ}C$ under a highly supersaturated aqueous solution giving rise to a fast precipitation rate. Meanwhile, during the second step aging at $60^{\circ}C$ in the same aqueous solution, the hexagonal polar face (001) having higher surface energy than (010) side planes dissolves to minimize surface energy. Hence the flat (001) face changes to a craterlike face and the hexagonal rod length of ZnO decreases at an initial-stage of this step aging. The formation of the (101) wedge-type faces is ascribed to the resultant of competitive reactions between the dissolution of polar face minimizing the surface energy which is a dominant reaction at the initial stage and the precipitation reaction dissipating supersaturation. At a later stage of the second-step the reaction rates of these two processes in the aqueous solution become similar and the overall reaction is terminated.

Stability of Minoxidil in Aqueous Solution (수용액중 미녹시딜의 안정성)

  • 김길수
    • YAKHAK HOEJI
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    • v.30 no.5
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    • pp.228-231
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    • 1986
  • The effect of temperature and pH on the degrdation of minoxidil in the aqueous solution was investigated and the stability of pharmaceutical preparation for solution was also studied. The degradation of minoxidil in the aqueous solution was first order type reaction and the rate constant at $20^{\circ}C$ in pH 7.0 phosphate buffer solution was 9.464${\times]10^{-3} day^{-1}$ and calculated activation energy was 11.7 kcal/mol. The degradation of minoxidil was acid-base catalytic reaction and the most stable range of pH was about 5.0. The liquid pharmaceutical preparation was very stable in 3 months.

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