• Applied Chemistry for Engineering
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• v.35 no.2
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• pp.85-95
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• 2024

Direct air capture (DAC) technology plays a crucial role in mitigating climate change. Reports from the International Energy Agency and climate change emphasize its significance, aiming to limit global warming to 1.5 ℃ despite continuous carbon emissions. Despite initial costs, DAC technology demonstrates potential for cost reductions through research and development, operational learning, and economies of scale. Recent advancements in high-permeance polymer membranes indicate the potential of membrane-based DAC technology. However, effective separation of CO₂ from ambient air requires membranes with high selectivity and permeability to CO₂. Current research is focusing on membrane optimization to enhance CO₂ capture efficiency. This study underscores the importance of direct air capture, evolving cost trends, and the pivotal role of membrane development in climate change mitigation efforts. Additionally, this research delved into the theoretical background, conditions, composition, advantages, and disadvantages of permeance and selectivity in membrane-based DAC.

• Membrane Journal
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• v.30 no.3
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• pp.173-180
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• 2020

As the demand for fossil fuels continues to increase worldwide, carbon dioxide (CO₂) concentration in the air has increased over the centuries. The way to reduce CO₂ emissions to the atmosphere, carbon capture and sequestration (CCS) technology have been developed that can be applied to power plants and factories, which are primary emission sources. According to the climate change mitigation policy, direct air capture (DAC) in air, referred to as "negative emission" technology, has a low CO₂ concentration of 0.04%, so it is focused on adsorbent research, unlike conventional CCS technology. In the DAC field, chemical adsorbents using CO₂ absorption, solid absorbents, amine-functionalized materials, and ion exchange resins have been studied. Since the absorbent-based technology requires a high-temperature heat treatment process according to the absorbent regeneration, the membrane-based CO₂ capture system has a great potential Membrane-based system is also expected for indoor CO₂ ventilation systems and immediate CO₂ supply to smart farming systems. CO₂ capture efficiency should be improved through efficient process design and material performance improvement.

• International Journal of Aeronautical and Space Sciences
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• v.11 no.2
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• pp.110-117
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• 2010

We propose guidance laws based on a pursuit-evasion game. The game solutions are obtained from a pursuit-evasion game solver developed by the authors. We introduce a direct method to solve planar pursuit-evasion games with control variable constraints in which the game solution is sought by iteration of the update and correction steps. The initial value of the game solution is used for guidance of the evader and the pursuer, and then the pursuit-evasion game is solved again at the next time step. In this respect, the proposed guidance laws are similar to the approach of model predictive control. The proposed guidance method is compared to proportional navigation guidance for a pursuit-evasion scenario in which the evader always tries to maximize the capture time. The capture sets of the two guidance methods are demonstrated.

• Journal of Environmental Science International
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• v.4 no.1
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• pp.41-52
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• 1995

The effects of reaction temperature, SO2 and CO2 concentration in an air gas stream, particle sizes of limestone on the reactivity and capacity of SO2 removal have been determined in a thermogravimetric analyser(TGA). The apparent reaction order of sulfation reaction of pre-calcined lime(CaO) with respect to SO2 is found to be close to unity. The apparent activation energies are found to be 17,000 kcal/kmol for sulfation of pre-calcined lime and 19,500 kcal/kmol for direct sulfation of limestone(CaCO3). The initial sulfation reaction rate of pre-calcined lime increases with increasing temperature, whereas the sulfur capture capacity exhibits a maximum value at 90$0^{\circ}C$. In direct sulfation of limestone, sulfation reactivity and sulfur capature capacity of sorbent increase with increasing temperature and decreasing CO2 concentration in a gas bulk stream. The main pare of pre-calcined lime is shifted to the larger pore sizes and pore volume decreases with increasing sulfation time and temperature. The surface area of lime decreases with increasing calcination temperature under an air atmosphere, whereas is yearly constant under a CO2(5, 10%) atmosphere in a gas stream.

• International Journal of High-Rise Buildings
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• v.12 no.2
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• pp.121-128
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• 2023

Cities cover only 3% of the planet's surface, yet they are responsible for more than 75% of the global emissions. Given the projected urban built area will double by 2060, the carbon emitted from cities will further increase. SOM proposes the Urban Sequoia concept, for buildings that go beyond 'net zero' and absorb carbon from the atmosphere. This concept combines multiple strategies, including the use of an optimised building form with a highly efficient structural system, modularized prefabrication techniques, holistic integration of facade, MEP and interiors' components, bio-based materials, and Direct Air Capture (DAC) technology, to reduce a 40-storey building's whole life cycle carbon emissions by more than 300% over a 100-year lifespan. Calculations of embodied carbon emissions are performed with SOM's in-house Environmental Analysis (EA) Tool to demonstrate the effectiveness of employing Urban Sequoia's design strategies in the design of new buildings using current technologies.

• Journal of ILASS-Korea
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• v.27 no.3
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• pp.126-133
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• 2022

The objective of this is to experimentally investigate the effect of mixed jet on the oxygen transfer characteristics with the primary nozzle area ratio of an annular nozzle ejector for the application of a microbial fuel cell. A direct visualization method with a high speed camera system was used to capture the horizontal mixed jet images, and a binarization technique was used to analyze the images. The clean water unsteady state technique was used for the oxygen transfer measurement. The air-water mixed jet discharging into a water tank behaved similar to a buoyancy or horizontal jet with the primary nozzle area ratio. It was found that an optimum primary nozzle area ratio was observed where the oxygen transfer performance reached its maximum value due to the decrease of air volume fraction and the increase of jet length and air bubble dispersion.

• Journal of the Korean Applied Science and Technology
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• v.31 no.1
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• pp.59-65
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• 2014

Indoor air quality including metro subway is of recent interests in large cities. Inflow air to the inside of the train and circulating air flow through MVAC of stations contain large amount of iron based fine particles. This paper evaluated the collection of such a dust by magnetic filters as comparing to conventional particle capturing mechanisms such as inertia, direct impaction and diffusion. It was found that filtration velocity, magnetic field intensity, and fiber size were the most important parameters for magnetic filtration. Application of magnetic force obviously enhances the collection efficiency particularly in fine modes smaller than 10 mm. However, its effect was found greater in 2.5 mm than submicron particles.

• Journal of Korean Society of Environmental Engineers
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• v.35 no.5
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• pp.307-311
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• 2013

Direct Air Capture (DAC) technology using reusable energy is a plausible process to capture $CO_2$ from non-point sources. In this paper, adsorption and desorption were repeatedly tested using low concentration $CO_2$. Three types of adsorbents were examined in cyclic $CO_2$ adsorption and thermal regeneration. Adsorption capacities of zeolite 5A, zeolite 13X and activated carbon were 21 mg/g, 12 mg/g and 6 mg/g, respectively. Zeolite 5A shows the highest adsorption capacities after cyclic thermal regeneration.

• Environmental Engineering Research
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• v.19 no.4
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• pp.299-308
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• 2014

This study presents a review on Chemical looping combustion (CLC) development, design aspects and modeling. The CLC is in fact an unmixed combustion based on the transfer of oxygen to the fuel by a solid oxygen carrier material avoiding the direct contact between air and fuel. The CLC process is considered as a very promising combustion technology for power plants and chemical industries due to its inherent capability of $CO_2$ capturing, which avoids extra separation costs of the of $CO_2$ from the rest of flue gases. This review covers the issues related to oxygen carrier materials. The modeling works are reviewed and different aspects of modeling are considered, as well. The main drawbacks and future research and prospects are remarked.

• Interaction and multiscale mechanics
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• v.3 no.2
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• pp.192-211
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• 2010

In most framed structures the nonlinearities and the damages are localized, extending over a limited length of the structural member. In order to capture the details of the local damage, the segments of a member that have entered the nonlinear range may need to be analyzed using the three-dimensional element (3D) model whereas the rest of the member can be analyzed using the simpler one-dimensional (1D) element model with fewer degrees of freedom. An Element-Coupling model was proposed to couple the small scale solid 3D elements with the large scale 1D beam elements. The mixed dimensional coupling is performed imposing the kinematic coupling hypothesis of the 1D model on the interfaces of the 3D model. The analysis results are compared with test results of a reinforced concrete pipe column and a structure consisting of reinforced concrete columns and a steel space truss subjected to static and dynamic loading. This structure is a reduced scale model of a direct air-cooled condenser support platform built in a thermal power plant. The reduction scale for the column as well as for the structure was 1:8. The same structures are also analyzed using 3D solid elements for the entire structure to demonstrate the validity of the Element-Coupling model. A comparison of the accuracy and the computational effort indicates that by the proposed Element-Coupling method the accuracy is almost the same but the computational effort is significantly reduced.