• Title/Summary/Keyword: H%E2%82%82O%E2%82%82

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The Effects of $O_2$ Partial Prewwure on Soft Magnetic Properties of Fe-Hf-O Thin Films (Fe-Hf-O계 박막에서 산소 분압 변화가 박막특성에 미치는 영향)

  • 박진영;김종열;김광윤;한석희;김희중
    • Journal of the Korean Magnetics Society
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    • v.7 no.5
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    • pp.243-248
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    • 1997
  • The effect of $O_2$ partial pressure on microstructure and soft magnetic properties of as-deposited Fe-Hf-O thin film alloys, which are produced by rf magnetron sputtering method in $Ar+O_2$ mixed gas atmosphere, are investigated. Saturation magnetization ($4{\pi}M_s$) of Fe-Hf-O film were decreased with increasing $O_2$ partial pressure, the best soft magnetic properties exhibit at $O_2$ partial pressure of 10%. With further increase of $O_2$ partial pressure, soft magnetic properties decreased continuously. The $Fe_{82}Hf_{3.4}O_{14.6}$ film with $P_{O2}=10%$ exhibits good soft magnetic properties with $4{\pi}M_s=17.7kG$, $H_c=0.7Oe$ and ${\mu}_ {eff}$ (1~100 MHz)=2,500, respectively. The addition of O is effective in grain refinement. In case of $P_{O2}=15%$, it is observed that $Fe_3O_4$ compound is formed and high frequency soft magnetic properties are decrease. The electrical resistvity($\rho$) of Fe-Hf-O film is increased with increasing $O_2$ partial pressure. Electrical resistivity of $Fe_{82}Hf_{3.4}O_{14.6}$ film was 5 times higher than that of the film without oxygen. Thus, it is considered that the good magnetic properties of $Fe_{82}Hf_{3.4}O_{14.6}$ film results from decreasing the $\alpha$-Fe grain size by precipitates (Hf and O), high electrical resistivity.

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A Study of $H_{2}O_{2}$ Production and BPA/17${\beta}$-estradiol Removal by Ultrasound and Pulsed UV in the Presence of Various Catalysts (Ultrasound와 Pulsed UV 조사시 $H_{2}O_{2}$ 발생량과 보조제 주입시 bisphenol A, 17${\beta}$-estradiol의 제거에 대한 연구)

  • Han, Jongh-Hun;Lee, Sung-Jae;Yoon, Yeo-Min;Her, Nam-Guk
    • Journal of Korean Society of Water and Wastewater
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    • v.26 no.2
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    • pp.313-319
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    • 2012
  • This study investigated the relative degradation of commonly known endocrine-disrupting compounds such as bisphenol A (BPA) and 17${\beta}$-estradiol (E2) using ultrasound (US) and pulsed ultraviolet (PUV) in water. The removal efficiency of BPA and E2 was determined as a function of generating power and $H_{2}O_{2}$ production. The ultrasound and PUV irradiation of the aqueous solution was performed in 3 L and 90 L stainless reactor at a constant temperature of $20^{\circ}C$ with an applied power of 200 W and 2000 W, respectively. The removal of BPA and E2 by US and PUV varied with catalysts. The experiments were conducted under the following conditions: total operating time, 30 min; initial concentration, 1 uM. In the case of E2 (10 min), % removal was 92.5/95.8/87.6/82.4, while % removal of BPA (10 min) was 62.3/82.3/91.1/67.0/64.3 in various conditions (PUV, $PUV+H_2O_2$, PUV+wire mesh, $PUV+TiO_2$ coated wire mesh), respectively.

Effects of Composition on Soft Magnetic Properties and Microstructures of Fe-Hf-O Thin Films (Fe - Hf - O계 박막에서 조성이 미세구조 및 연자기 특성에 미치는 효과)

  • 박진영;김종열;김광윤;한석희;김희중
    • Journal of the Korean Magnetics Society
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    • v.7 no.5
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    • pp.237-242
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    • 1997
  • The microstructure and soft magnetic properties of as-deposited Fe-Hf-O thin film alloys, which are produced at $P_{O2}=10%$ by rf magnetron sputtering method in $Ar+O_2$ mixed gas atmosphere, is investigated. Newly developed $Fe_{82}Hf_{3.4}O_{14.6}$ film exhibits good soft magnetic properties with $4{\pi}M_s=17.7$ kG, $H_c=0.7$ Oe and ${\mu}_{eff}$(0.5~100MHz)=2,500, respectively. The Fe-Hf-O films are composed of $\alpha$-Fe nanograins and amorphous phase with larger amounts of Hf and O elements which chemically combine each other. With increasing Hf area fraction, Hf and O contents increased proportionally. It was considered that O content in films was determined by Hf contents, because O was chemically combined with Hf. It results from decreasing the $\alpha$-Fe grain size by precipitates (Hf and O), high electrical resistivity. The $Fe_{82}Hf_{3.4}O_{14.6}$ film exhibits the quality factor (Q=$\mu$'/$\mu$") of 25 at 20 MHz. These good frequency characteristics are considered to be superior to other films already reported.o other films already reported.

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Biochemical properties and cultural characteristics of Escherichia coli isolated from chickens (닭에서 분리한 Escherichia coli의 생물화학적 및 배양 특성)

  • Woo, Yong-ku;Kim, Ki-seuk;Kim, Bong-hwan
    • Korean Journal of Veterinary Research
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    • v.30 no.4
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    • pp.421-425
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    • 1990
  • The present study was conducted to investigate the biochemical and cultural characteristics of Escherichia coli isolates from clinically affected chickens during the period from May 1988 to June 1989. A total of 82 E coli cultures were isolated from lesions of 75 chickens with colisepticemia. Biochemical properties of E coli isolates tested were in accordance with the general classification standard; all the isolates showed positive reaction in Catalase, Indol, and Methyl-Red tests, but negative reaction in Oxidase, Urease, $V{\ddot{o}ges$-Proskauer, Citrate utility, $H_2S$, Phenylalanine diaminase, and malonate tests. And the carbohydrate fermentation rates of them were shown to be variable. of the 82 isolates, 48(58.5%) cultures produced colicin to inhibit the indicator strain of E coli.

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Isolation of Verocytotoxin Producing Escherichia coli O157:H7 Due to Fcal Contamination on Carcass Surfaces (도체표면의 분변오염과 Verotoxin 생성 Escherichia coli O157:H7 분리에 관한 연구)

  • 홍종해;고주언
    • Journal of Food Hygiene and Safety
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    • v.12 no.1
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    • pp.78-82
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    • 1997
  • Surface swab samples from beef (188), pork (240) and chicken (95) carcasses were collected from slaughterhouse in Kangwon and Kyunggi areas from March through July 1996. The samples were examined on the level of E. coli biotype I relevant to fecal contamination due to unsanitary processing control and the existence of verocytotoxin-producing E. coli (VTEC). E. coli biotype I were confirmed from 38.8% of beef, 40.0% of pork, and 69.5% of chicken carcasses. Little variation was noted among three sampling points; rump, flank and neck of beef, ham, belly and jowls of pork. coli O157:H7 was only confirmed from 2 of 188 beef carcasses. E. coli biotype I. All the isolated E. coli O157 showed positive for vero cell cytotoxicity test. Isolation rate of E. coli O157 in summer was higher than in spring. In case of pork and chicken carcasses, E. coli O157 was isolated in summer only.

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Varistor Characteristics of ZPCCL-Based Ceramics Doped with $La_{2}o_{3}$ ($La_{2}o_{3}$가 첨가된 ZPCCL계 세라믹스의 바리스터 특성)

  • 정영철;류정선;남춘우
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.415-418
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    • 2001
  • The I-V characteristics and its stability of ZPCCL-based ceramic varistors doped with La$_2$O$_3$in the range of 0.0~4.0 mol% were investigated. The density of ceramics was increased in the range of 4.7~5.8 g/cm$^3$ with increasing La$_2$O$_3$content. As La$_2$O$_3$content is increased, the varistor voltage was decreased in the range of 503.49-9.42 V/mm up to 2.0 mol%, whereas increasing La$_2$O$_3$content further caused it to increase. The ZPCCL-based varistors were characterized by nonlinearity, in which the nonlinear exponent is in the range of 3.05~82.43 and leakage current is in the range of 0.24-100.22 $\mu$A. Among ZPCCL-based varistors, 0.5 mol% added-varistors exhibited an excellent nonlinearity, in which the nonlinear exponent is 82.43 and the leakage current is 0.24 $\mu$A. Furthermore, they exhibited a high stability, in which the variation rate of the varistor voltage and the nonlinear exponent was -1.11% and -6.72%, respectively, under DC stress, such as (0.80 V$_{1mA}$9$0^{\circ}C$/12h)+(0.85 V$_{1mA}$115$^{\circ}C$//12h) +(0.90 V$_{1mA}$12$0^{\circ}C$//12h)+(0.95 V$_{1mA}$1$25^{\circ}C$//12h)+(0.95 V$_{1mA}$15$0^{\circ}C$//12h). Consequently, it was estimated that ZPCCL-based ceramics will be applied to development of Pr$_{6}$O$_{11}$ based ZnO varistors having a high performance.e.rformance.e.

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Theoretical Investigation for the Molecular Structures and Dimerization Energies for Complexes of H2O-C6H6 Dimer (물(H2O)과 벤젠(C6H6) 이합체의 분자 구조 및 결합 에너지에 관한 이론 연구)

  • Sun, Ju-Yong;Kim, Seung-Joon
    • Journal of the Korean Chemical Society
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    • v.53 no.1
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    • pp.7-16
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    • 2009
  • The global minimum structures of the benzene-water, Bz-$H_2O$ and benzene-water cation complex, [Bz-$H_2O]^+$ have been investigated using ab initio and density functional theory(DFT) with very large basis sets. The highest levels of theory employed in this study are B3LYP/cc-pVQZ for geometry optimization and MP2/aug-cc-pVTZ//B3LYP/aug-cc-pVTZ for binding energy. The harmonic vibrational frequencies and IR intensities are also determined at the various levels of theory to confirm whether the structure of water complex is affected by the presence of benzene. The binding energies of Bz-$H_2O$ (N-1) structure are predicted to be 3.92 kcal/mol ($D_e$) and 3.11 kcal/mol ($D_0$) after the zero-point vibrational energy correction at the MP2/cc-pVQZ//B3LYP/cc-pVQZ level of theory. The binding energies of [Bz-$H_2O]^+$ (C-1) structure are predicted to be 9.06 kcal/mol for $D_e$ and 7.82 kcal/mol for $D_0$ at the same level of theory.

Difference in the spatial distribution between $H_2O$ and $CO_2$ ices in M 82 found with AKARI

  • Yamagishi, Mitsuyoshi;Kaneda, Hidehiro;Oyabu, Shinki;Ishihara, Daisuke;Onaka, Takashi;Shimonishi, Takashi;Suzuki, Toyoaki;Minh, Young Chol
    • The Bulletin of The Korean Astronomical Society
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    • v.38 no.2
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    • pp.34.1-34.1
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    • 2013
  • Interstellar ices (e.g., $H_2O$, $CO_2$, and CO ices) are formed on the surface of dust grains in dense molecular clouds. In a near-infrared spectrum, we can observe deep absorption features particularly due to $H_2O$ ice at $3.05{\mu}m$ and $CO_2$ ice at $4.27{\mu}m$. These interstellar ices have many pieces of information on the interstellar environment. Among various ices, $CO_2$ ice is one of the most important ones as a probe of the interstellar environment. That is because $CO_2$ ice is a secondary product unlike $H_2O$ and CO ices which are primarily formed on dust grains. Past studies for $CO_2$ ice in nearby galaxies were performed only for the galactic center in a few galaxies. In order to utilize the information from $CO_2$ ice effectively, it is valuable to perform mapping observations of ices on a galactic scale. With AKARI, we obtain the spatially-resolved near-infrared ($2.5-5.0{\mu}m$) spectra for the central ~1 kpc region of the nearby starburst galaxy M 82. These spectra clearly show the absorption features due to interstellar $H_2O$ and $CO_2$ ices, and we created their column density maps. As a result, we find that the spatial distribution of $H_2O$ ice is significantly different from that of $CO_2$ ice; $H_2O$ ice is widely distributed, while $CO_2$ ice is concentrated near the galactic center. Our result for the first time reveals spatial variations in $CO_2/H_2O$ ice abundance ratio on a galactic scale, suggesting that the ice-forming interstellar environment changes within a galaxy. In this presentation, we discuss the cause of the variations in the ice abundance ratio.

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Gas Effect at High Temperature on the Supersonic Nozzle Conception

  • Boun-jad, Mohamed;Zebbiche, Toufik;Allali, Abderrazak
    • International Journal of Aeronautical and Space Sciences
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    • v.18 no.1
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    • pp.82-90
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    • 2017
  • The aim of this work is to develop a new computational program to determine the effect of using the gas of propulsion of combustion chamber at high temperature on the shape of the two-dimensional Minimum Length Nozzle giving a uniform and parallel flow at the exit section using the method of characteristics. The selected gases are $H_2$, $O_2$, $N_2$, CO, $CO_2$, $H_2O$, $NH_3$, $CH_4$ and air. All design parameters depend on the stagnation temperature, the exit Mach number and the used gas. The specific heat at constant pressure varies with the temperature and the selected gas. The gas is still considered as perfect. It is calorically imperfect and thermally perfect below the threshold of dissociation of molecules. A error calculation between the parameters of different gases with air is done in this case for purposes of comparison. Endless forms of nozzles may be found based on the choise of $T_0$, $M_E$ and the selected gas. For nozzles delivering same exit Mach number with the same stagnation temperature, we can choose the right gas for aerospace manufacturing rockets, missiles and supersonic aircraft and for supersonic blowers as needed in settings conception.

Combined Effect of Cold Plasma and UV-C Against Escherichia coli O157:H7, Salmonella Typhimurium, and Listeria monocytogenes on Fresh-cut Lettuce (양상추에 인위접종된 Escherichia coli O157:H7, Salmonella Typhimurium과 Listeria monocytogenes에 대한 저온 플라즈마와 UV-C의 살균 효과)

  • Seong, Ji-Yeong;Park, Mi-Jung;Kwon, Ki-Hyun;Oh, Se-Wook
    • Journal of Food Hygiene and Safety
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    • v.32 no.1
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    • pp.64-69
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    • 2017
  • This study was conducted to investigate the effect of cold plasma combined with UV-C irradiation against Escherichia coli O157:H7, Salmonella enterica serovar Typhimurium, and Listeria monocytogenes on lettuce. E. coli O157:H7, S. Typhimurium, and L. monocytogenes, corresponding to approximately 5.82, 5.09, 5.65 log CFU/g, were inoculated on lettuce, respectively. Then, the lettuce was treated with cold plasma, UV-C and combination (cold plasma + UV-C), respectively. The treated lettuce was stored for 9 days at $4^{\circ}C$ for microbiological analysis and sensory evaluation. Cold plasma reduced the populations of E. coli O157:H7, S. Typhimurium, and L. monocytogenes by 0.26, 0.65, and 0.93 log CFU/g, respectively. Each microorganism were reduced by 0.87, 0.88, and 1.14 log CFU/g after UV-C treatment. And, the combined treatment that was treated by cold plasma after UV-C treatment reduced the populations of inoculated microorganisms by 1.44, 2.70, 1.62 log CFU/g, respectively. The all treatment significantly (p < 0.05) reduced the populations of all inoculated bacteria compared to untreated lettuce. UV-C combined with cold plasma was the most effective for reducing the pathogenic bacteria on lettuce, by showing log-reductions of ${\geq}2.0\;log\;CFU/g$. All treatment was not significantly different until 6 day storage compared to control group in terms of appearance, texture and overall acceptability. Therefore, the combined treatment will be an effective intervention method to control the bacteria on lettuce.