• Title/Summary/Keyword: LI14

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Electrochemical Properties of Ionic Liquid Composite Poly(ethylene oxide)(PEO) Solid Polymer Electrolyte (이온성 액체 복합 Poly(ethylene oxide)(PEO) 고체 고분자 전해질의 전기화학적 특성)

  • Park, Ji-Hyun;Kim, Jae-Kwang
    • Journal of the Korean Electrochemical Society
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    • v.19 no.3
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    • pp.101-106
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    • 2016
  • In this study, we prepared an ionic liquid composite solid polymer electrolyte (PEO-LiTFSI-$Pyr_{14}TFSI$) with poly(ethylen oxide), lithium bis(trifluoromethanesulfonyl)imide, N-butyl-N-methylpyrrolidinium bis(trifluoromethanesulfonyl)imide by blending-cross linking process. Although the PEO-LiTFSI-$Pyr_{14}TFSI$ composite solid polymer electrolyte displayed a small peak at 4.4 V, it had high electrochemical oxidation stability up to 5.7 V. Ionic conductivity of the PEO-LiTFSI-$Pyr_{14}TFSI$ composite solid polymer electrolyte increased with increasing temperature from $10^{-6}S\;cm^{-1}$ at $30^{\circ}C$ to $10^{-4}S\;cm^{-1}$ at $70^{\circ}C$. To investigate the electrochemical properties, the PEO-LiTFSI-$Pyr_{14}TFSI$ composite solid polymer electrolyte assembled with $LiFePO_4$ cathode and Li-metal anode. At 0.1 C-rate, the cell delivered $40mAh\;g^{-1}$ for $30^{\circ}C$, $69.8mAh\;g^{-1}$ for $40^{\circ}C$ and $113mAh\;g^{-1}$ for $50^{\circ}C$, respectively. The PEO-LiTFSI-$Pyr_{14}TFSI$ solid polymer electrolyte exhibited good charge-discharge performance in Li/SPE/$LiFePO_4$ cells at $50^{\circ}C$.

Properties of N-butyl-N-methyl-pyrrolidinium Bis(trifluoromethanesulfonyl) Imide Based Electrolytes as a Function of Lithium Bis(trifluoromethanesulfonyl) Imide Doping

  • Kim, Jae-Kwang;Lim, Du-Hyun;Scheers, Johan;Pitawala, Jagath;Wilken, Susanne;Johansson, Patrik;Ahn, Jou-Hyeon;Matic, Aleksandar;Jacobsson, Per
    • Journal of the Korean Electrochemical Society
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    • v.14 no.2
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    • pp.92-97
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    • 2011
  • In this study we have investigated the Li-ion coordination, thermal behavior and electrochemical stability of N-butyl-N-methyl-pyrrolidinium bis(trifluoromethanesulfonyl)imide ($Py_{14}TFSI$) with lithium bis(trifluoromethanesulfony)imide (LiTFSI) doping intended for use as electrolytes for lithium batteries. The ionic conductivity is reduced and glass transition temperature ($T_g$) increases with LiTFSI doping concentration. Also, the electrochemical stability increases with LiTFSI doping. A high LiTFSI doping could enhance the electrochemical stability of electrolytes for lithium batteries, whereas the decrease in the ionic conductivity limits the capacity of the battery.

Electrochemical Properties on High Temperature Operating Battery by Electrolyte and Salts in Electrodes (고온 작동형 전지의 전해질 및 전극내 첨가염 변화에 따른 전기화학적 특성 연구)

  • Choi, Yu-Song;Ha, Sang-Hyun;Cho, Sung-Baek
    • Journal of the Korea Institute of Military Science and Technology
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    • v.14 no.4
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    • pp.740-746
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    • 2011
  • Thermally activated batteries have good stability, reliability and long shelf life. Due to these characteristics and operational mechanism, thermal batteries are usually applied to military power sources. Especially, Li/$FeS_2$ thermal batteries, which are used mostly in these days, use LiCl-KCl and LiBr-LiCl-LiF as electrolytes. The electrochemistry of thermal batteries have been researched for long time, however, electrochemical study using impedance spectroscopy was not published so much. Through this research, microscopic electrochemical research was investigated with electrochemical impedance spectroscopy(E.I.S). Electrolyte effects on Li/$FeS_2$ thermal battery was researched changing electrolytes, LiCl-KCl and LiBr-LiCl-LiF. Additionally, the salts, which are added to electrolytes, effects on thermal battery were researched. It is expected that the impedance spectroscopy analysis is applicable to not only thermal battery electrochemical study effectively, but also, thermal battery developments.

Evaluation of Airborne LiDAR Data using Field Surveyed Ground Control Points (현지 측량기준점을 이용한 LiDAR 데이터의 정확도 검증)

  • Wie, Gwang-Jae;Yang, In-Tae;Suh, Young-Woon;Sim, Jung-Min
    • Journal of Korean Society for Geospatial Information Science
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    • v.14 no.4 s.38
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    • pp.11-18
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    • 2006
  • In this paper, airborne LiDAR data were evaluated in horizontal and vertical accuracy. By using zigzag scanning type of LiDAR, GCPs are not tested directly. So points around GCPs were used in this evaluation. Building corner points were made from LiDAR's building planar and compared with ground surveyed GCPs, in horizontal accuracy test. Its accuracy shows 19cm average and 21cm RMSE and 15 points were within 20cm among 16 points. In vertical accuracy test, 41 GCPs were used and it shows 11cm average and 14cm RMSE and 75% of GCPs were within 15cm. This could be a criterion in topographic map modification and basic geographic DB and 3D data construction using airborne LiDAR data.

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Scintillation Characteristics of CsI:X(X=Li+,K+,Rb+ Single Crystals (CsI:X(X=Li+,K+,Rb+단결정의 섬광특성)

  • Gang, Gap-Jung;Doh, Sih-Hong;Lee, Woo-Gyo;Oh, Moon-Young
    • Journal of Sensor Science and Technology
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    • v.12 no.1
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    • pp.1-9
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    • 2003
  • CsI single crystals doped with lithium, potassium or rubidium were grown by using Czochralski method at Ar gas atmosphere. The energy resolutions of CsI(Li:0.2 mole%), CsI(K:0.5 mole%) and CsI(Rb:1.5 mole%) scintillators were 14.5%, 15.9% and 17.0% for $^{137}Cs$(0.662 MeV), respectively. The energy calibration curves of CsI(Li), CsI(K) and CsI(Rb) scintillators were linear for $\gamma$-ray energy. The time resolutions of CsI(Li:0.2 mole%), CsI(K:0.5 mole%) and CsI(Rb:1.5 mole%) scintillators measured by CFT(constant-fraction timing method) were 9.0 ns, 14.7 ns and 9.7 ns, respectively. The fluorescence decay times of CsI(Li:0.2 mole%) scintillator had a fast component and slow one of ${\tau}_1=41.2\;ns$ and ${\tau}_2=483\;ns$, respectively. The fluorescence decay times of CsI(K:0.5 mole%) scintillator were ${\tau}_1=47.2\;ns$ and ${\tau}_2=417\;ns$. And the fluorescence decay times of CsI(Rb:1.5 mole%) scintillator were ${\tau}_1=41.3\;ns$ and ${\tau}_2=553\;ns$. The phosphorescence decay times of CsI(Li:0.2 mole%), CsI(K:0.5 mole%) and CsI(Rb:1.5 mole%) scintillators were 0.51 s, 0.57 s and 0.56 s, respectively.

Layered $LiCo_{x}Mn_{1-x}O_2$ as Cathode Materials for Li-Ion Batteries

  • Kumagai, Naoaki;Myung, Seung-Taek;Komaba, Shinichi
    • Electrical & Electronic Materials
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    • v.14 no.12
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    • pp.7-10
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    • 2001
  • Orthorhombic type LiCo$_{x}$Mn$_{1-x}$ O$_2$(0$\leq$x$\leq$0.14) oxides have been synthesized by hydrothermal treatment of (Co$_{x}$Mn$_{1-x}$ )$_3$O$_4$precursors and LiOH aqueous solution at 17$0^{\circ}C$. As-synthesized powders showed well-ordered $\beta$-MaMnO$_2$structures, and the products were single crystalline particle oxides from TEM observations. The particle size decreased with increasing the amount of Co substituent. Much more improved capacity upon 100 cyclings was clearly seen in orthorhombic LiCo$_{0.1}$Mn$_{0.9}$O$_2$, comparing to orthorhombic LiMnO$_2$./TEX>.EX>.

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Mossbauer studies of LiFeO2 powders by sol-gel process (졸겔 합성에 의한 LiFeO2분말의 Mossbauer 연구)

  • An, Sung-Yong;Kim, Chul-Sung
    • Journal of the Korean Magnetics Society
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    • v.14 no.2
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    • pp.71-75
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    • 2004
  • $\alpha$-LiFe $O_2$ powders have been prepared by a sol-gel method. The crystallographic and magnetic properties were characterized with a x-ray diffractometry, Mossbauer spectroscopy, and vibrating Samples magnetometry. The ${\gamma}$-LiFe $O_2$+LiFe$_{5}$ $O_{8}$ phase is observed in the Samples annealed at $600^{\circ}C$ for 3h in air and $\alpha$-LiFe $O_2$ phase is observed in the Samples annealed at $600^{\circ}C$ for 3 h in $H_2$(5%)/Ar(Bal.) gas atmosphere. The crystal structure of $\alpha$-LiFe $O_2$ is found to be cubic with a lattice a=4.193$\pm$0.0005 $\AA$. The Neel temperature of $\alpha$-LiFe $O_2$ is found to be 130$\pm$3 K.

Anatomy of Large Intestine Meridian Muscle in human (수양명경근(手陽明經筋)의 해부학적(解剖學的) 고찰(考察))

  • Sim Young;Park Kyoung-Sik;Lee Joon-Moo
    • Korean Journal of Acupuncture
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    • v.19 no.1
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    • pp.15-23
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    • 2002
  • This study was carried to identify the component of Large Intestine Meridian Muscle in human, dividing into outer, middle, and inner part. Brachium and antebrachium were opened widely to demonstrate muscles, nerve, blood vessels and the others, displaying the inner structure of Large Intestine Meridian Muscle. We obtained the results as follows; 1. Meridian Muscle is composed of the muscle, nerve and blood vessels. 2. In human anatomy, it is present the difference between a term of nerve or blood vessels which control the muscle of Meridian Muscle and those which pass near by Meridian Muscle. 3. The inner composition of meridian muscle in human arm is as follows. 1) Muscle; extensor digitorum tendon(LI-1), lumbrical tendon(LI-2), 1st dosal interosseous muscle(LI-3), 1st dosal interosseous muscle and adductor pollicis muscle(LI-4), extensor pollicis longus tendon and extensor pollicis brevis tendon(LI-5), adductor pollicis longus muscle and extensor carpi radialis brevis tendon(LI-6), extensor digitorum muscle and extensor carpi radialis brevis mucsle and abductor pollicis longus muscle(LI-7), extensor carpi radialis brevis muscle and pronator teres muscle(LI-8), extensor carpi radialis brevis muscle and supinator muscle(LI-9), extensor carpi radialis longus muscle and extensor carpi radialis brevis muscle and supinator muscle(LI-10), brachioradialis muscle(LI-11), triceps brachii muscle and brachioradialis muscle(LI-12), brachioradialis muscle and brachialis muscle(LI-13), deltoid muscle(LI-14, LI-15), trapezius muscle and supraspinous muscle(LI-16), platysma muscle and sternocleidomastoid muscle and scalenous muscle(LI-17, LI-18), orbicularis oris superior muscle(LI-19, LI-20) 2) Nerve; superficial branch of radial nerve and branch of median nerve(LI-1, LI-2, LI-3), superficial branch of radial nerve and branch of median nerve and branch of ulna nerve(LI-4), superficial branch of radial nerve(LI-5), branch of radial nerve(LI-6), posterior antebrachial cutaneous nerve and branch of radial nerve(LI-7), posterior antebrachial cutaneous nerve(LI-8), posterior antebrachial cutaneous nerve and radial nerve(LI-9, LI-12), lateral antebrachial cutaneous nerve and deep branch of radial nerve(LI-10), radial nerve(LI-11), lateral antebrachial cutaneous nerve and branch of radial nerve(LI-13), superior lateral cutaneous nerve and axillary nerve(LI-14), 1st thoracic nerve and suprascapular nerve and axillary nerve(LI-15), dosal rami of C4 and 1st thoracic nerve and suprascapular nerve(LI-16), transverse cervical nerve and supraclavicular nerve and phrenic nerve(LI-17), transverse cervical nerve and 2nd, 3rd cervical nerve and accessory nerve(LI-18), infraorbital nerve(LI-19), facial nerve and infraorbital nerve(LI-20). 3) Blood vessels; proper palmar digital artery(LI-1, LI-2), dorsal metacarpal artery and common palmar digital artery(LI-3), dorsal metacarpal artery and common palmar digital artery and branch of deep palmar aterial arch(LI-4), radial artery(LI-5), branch of posterior interosseous artery(LI-6, LI-7), radial recurrent artery(LI-11), cephalic vein and radial collateral artery(LI-13), cephalic vein and posterior circumflex humeral artery(LI-14), thoracoacromial artery and suprascapular artery and posterior circumflex humeral artery and anterior circumflex humeral artery(LI-15), transverse cervical artery and suprascapular artery(LI-16), transverse cervical artery(LI-17), SCM branch of external carotid artery(LI-18), facial artery(LI-19, LI-20)

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Ashi Points-acupuncture for Wrist Sprain (수근관절염좌 환자에 대한 아시혈 치료)

  • Kang, Tae Kyoung;Kim, Myung Dong
    • Journal of Physiology & Pathology in Korean Medicine
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    • v.29 no.4
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    • pp.337-346
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    • 2015
  • Sprain is the injury of meridian-muscle, and is caused by qi and blood obstruction or regional stagnation of qi and blood. So we take the channel points where pain flows. If we take the locations that feel pain, those locations are treatments points and ashi points. So we searched over the ashi points appearing on the patients with wrist sprain. Ashi points appeared on LI5, TE4, SI5 around wrist joints, LI10, LI11, LU6 around elbow joints, LI14, LU3, LU4, PC2 around upper arm. Also, ashi points appeared much on ST17, KI23, PC1, SP18, ST18 around thoracic region, and, on BL15, BL44, BL13 around anterior and thoracodorsal region, in order stated. Ashi points of the highest frequency appeared on LI14 around upper arm, and on LI5, TE4 around wrist joint, and SI5, ST17, KI12, PC1, SP18 appeared with second highest frequency. And ashi points on elbow points and thoracodorsal region appeared with the same frequency. Therefore, it is possible for us to know that the pain location appears in order of upper arm, anterior thoracic region, elbow joint region, and, thoracodorsal region, in treating wrist joints. There was a tendency that pain and movement disturbance recovered more quickly, depending on the pain reduction, as we found out the ashi points closely from stagnated qi and blood caused by wrist arthritis, and relaxed the stiff location. Rubbing treatments in treating pain ashi points is considered to play an important role to reduce pain effectively, so it is necessary to make a further study.