• Title/Summary/Keyword: Na

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Swelling Indexes and Relevant Removal of Cd and Pb of the Na-bentonite activated with Na2CO3 and NaHCO3 (Na2CO3와 NaHCO3로 활성화한 Na-벤토나이트의 팽창특성과 Cd와 Pb의 상대적 등온흡착곡선)

  • Chung, Doug-Young;Yang, Jae E.;Oh, Taek-G.;Lee, Kyo-S.
    • Korean Journal of Soil Science and Fertilizer
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    • v.40 no.1
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    • pp.64-70
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    • 2007
  • In this experiment we transformed the Ca-bentonite into Na-bentonite with two inorganic Na-chemicals under different temperatures. These two Na-chemicals were selected among five different Na-chemicals which carries Na as cation. The swelling capacity of the Na chemical-treated bentonite was increased with increasing Na concentration, while the maximum concentration of Na solution decreased with increasing temperature. $Na_2CO_3$ was most effective in exchanging Ca ions and resulting in the highest swelling index among the Na-chemicals. The swelling index was significantly increased with increasing temperature to $100^{\circ}C$. But the equilibration time reversely affected the swelling index due to a rapid increase in evaporation of water. Within same amount of Na treatment SI slightly decreased not only with increasing contacting time but also with increasing temperature. The adsorption for the transformed Na-bentonite was increased with increasing equilibrium concentrations of Pb and Cd ions for all the activated Na-B and indigenous Ca-B and Na-B while the adsorbability of $Pb^{2+}$ onto each Na-B sample is more than that of $Cd^{2+}$. And the maximum adsorption capacity sequence of Na-B samples for Pb and Cd has been found to be 5 % $Na_2CO_3.$ - 5 % $NaHCO_3$ > 3 % $NaHCO_3$ > 3 % $Na_2CO_3$ > 1 % $NaHCO_3$ > 1 % $Na_2CO_3$ > indigenous Na-B > indigenous Ca-B, showing that there are contradictory results about the relationship of cation adsorption to CEC.

Performance of Naked Neck versus Normally Feathered Coloured Broilers for Growth, Carcass Traits and Blood Biochemical Parameters in Tropical Climate

  • Patra, B.N.;Bais, R.K.S.;Prasad, R.B.;Singh, B.P.
    • Asian-Australasian Journal of Animal Sciences
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    • v.15 no.12
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    • pp.1776-1783
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    • 2002
  • A population segregating for the naked neck (Na) gene was used to evaluate its effect on fast growing broilers at heat stress. An experimental stock comparable to those of modern broilers was established by backcrossing to colour synthetic male and female lines. Matings between heterozygous (Na/na) males and females produced normally feathered (na/na), heterozygous (Na/na) and homozygous (Na/Na) chicks for the present study. Day old to seven week old coloured broilers of three genotypes viz. normally feathered (na/na), heterozygous naked neck (Na/na) and homozygous naked neck (Na/Na) were compared for heat dissipation, growth performance, body conformation traits, blood biochemical parameters and carcass traits in tropical climate. In hot climate, naked neck broilers had significantly less body temperature and better heat dissipation capabilities as compared to normal broilers. The naked neck broilers had significantly higher body weight and better feed conversion ratio than na/na broilers. The Na/Na or Na/na broilers exhibited higher giblet yield, blood loss and lower feather mass compared to na/na broilers. The results indicated that the reduction in feather coverage in Na/Na and Na/na broilers facilitates better heat dissipation with lower body temperature, more body weight gain, better FCR and carcass traits compared to normal broilers.

Direct synthesis of Na-kenyaite from amorphous silica (무정형 실리카로부터 Na-kenyaite의 직접합성)

  • 권오윤;박경원;백우현
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.9 no.1
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    • pp.70-73
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    • 1999
  • Amorphous silica was hydrothermally reacted for 48~120h at $170~180^{\circ}C$ in molar ratios of $SiO_{2}/(NaOH+Na_{2}CO_{3})=2~20\;and\;H_{2}O/(NaOH+Na_{2}CO_{3})=200~250$. Na-kenyaite nuclei were formed directly from amorphous silica without formation of Na-magadiite nuclei in wide range with $SiO_{2}/(NaOH+Na_{2}CO_{3})=3~20$. Above $SiO_{2}/(NaOH+Na_{2}CO_{3})=10$, Na-kenyaite always produced with a residual amorphous silica. Well-crystallized Na-kenyaite without residual amorphous silica were obtained in the range of $SiO_{2}/(NaOH+Na_{2}CO_{3})=3~10$. Morphology of Na-kenyaite exhibited that a large spherical and loosely packed aggregates changed into the smaller and individual platelets according to increase of reaction time.

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Computation of Ionic Conductivity at NASICON Solid Electrolytes (II) Effects of mid-Na Sites on Na1-Na2 Conduction Paths (NASICON 고체 전해질의 이온 전도도 계산 (II) Na1-Na2 전도 경로에 미치는 mid-Na의 영향)

  • 최진삼;서양곤;강은태
    • Journal of the Korean Ceramic Society
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    • v.32 no.11
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    • pp.1292-1300
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    • 1995
  • The ionic conductivity of NASICON solid electrolytes was simulated by using Monte Carlo Method (MCM). There were included two conduction paths: (1) Na1-Na2 and (2) Na1-Na2 including Na2-Na2. We assumed that mid-Na ions provde an additional driving force for Na mobile ions due to the interionic repulsion between Na1 and Na2 ions. The inflection point of vacancy availability factor, V has been shown at nearby x=2, the maximum mid-Na ions. The inflection point of vacancy availability factor, V has been shown at nearby x=2, the maximum mid-Na sites are occupied. The effective jump frequency factor, V has been shown at nearby x=2, the maximum mid-Na sites are occupied. The effective jump frequency factor, W increased rapidly with the composition at low temperature, but decreased at high temperature region. On Na1-Na2 conduction path, the minimum of charge correlation factor, fc and the maximum of $\sigma$T were appeared at x=2.0. this indicated that mid-Na ions affect on the high ionic conductivity behavior. At the whole range of NASICON composition, 1n $\sigma$T vs. 1/T* plots have been shown Arrhenius behavior but 1n (VWFc) vs. 1/T* have been shown the Arrhenius type tendency at x=2, which mid-Na is being the maximum. The results of MCM agreed with the experimental one when the chosen saddle point value was 6$\varepsilon$ : 3$\varepsilon$. Here the calculated characteristic parameter of materials, K and the phase transition temperature were -4.001$\times$103 and 178$^{\circ}C$ (1/T*=1.92, 1000/T=2.22), respectively.

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Separation of H2 and N2 Gases by PTMSP-NaA Zeolite Composite Membranes (PTMSP-NaA Zeolite 복합막에 의한 수소-질소 기체 분리에 관한 연구)

  • Kim, Ok-Su;Yun, Seok Il
    • Membrane Journal
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    • v.25 no.2
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    • pp.107-114
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    • 2015
  • PTMSP-NaA zeolite composite membranes were prepared by adding 0~50 wt% NaA zeolite to PTMSP. The membranes were characterized by FT-IR, $^1H$-NMR, GPC, DSC, TGA, SEM. The permeabilities of $H_2$ and $N_2$ gases through PTMSP-NaA zeolite composite membranes was studied as a function of NaA zeolite contents. According to TGA measurements, when zeolite was inserted into the polymer, weight loss temperature and weight loss wt% of PTMSP-NaA zeolite composite membranes were decreased. Based on SEM observation, NaA zeolite was dispersed in the PTMSP-NaA zeolite composite membrane with the size $2{\sim}5{\mu}m$. The permeability of PTMSP-NaA zeolite composite membranes increased added as NaA zeolite content increased. On the contrary, the selectivity ($H_2/N_2$) of the composite membranes decreased as NaA zeolite content increased. PTMSP-NaA zeolite composite membrane showed better permeability and selectivity ($H_2/N_2$) of $H_2$ and $N_2$ than PTMSP-NaY zeolite composite membrane.

Computation of Ionic Conductivity at NASICON Solid Electrolyte (III) Na1$\longrightarrow$mid-Na$\longrightarrow$Na2 Conduction Paths (NASICON 고체 전해질의 이온 전도도 계산 (III) 전도경로가 Na1$\longrightarrow$mid-Na$\longrightarrow$Na2인경우)

  • 최진삼;서양곤;강은태
    • Journal of the Korean Ceramic Society
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    • v.33 no.6
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    • pp.645-652
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    • 1996
  • The ionic conductivity of NASICON (Na Super Ionic Conductor) solid electrolyte was simulated by using Monte Carlo Method (MCM)based on a hopping model. We assumed that the conduction path of Na ions is Na1→mid-Na→Na2 where the mid-Na sites are shallow potential sites to induce 'a breathing-like movement' of Na ions in the NASICON framework. The minimum of charge correlation factor Fc and the maximum of appeared at nearby x=2.0 The occupancy of mid-Na site affected the depth of potential barrier and the conduc-tivity of the NASICON. At above x=0.3 ln σT vs. 1/T* plots have been shown Arrhenius behavior but in (VWfc)vs. 1/T* have been shown the Arrhenius type tendency at x=1 MCM results accorded with the experi-mental procedure. The role of mid-Na on Na+ ion conduction could be explained by an additional driving force and a breating-like movement model for motions of Na+ ions in the NASICON framework. As we couldn't clearly remarked the model which is the better it seems reasonable to conclude that these hypothesies are suitable to explain the FIC behavior at NASICON.

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Effects of concentrations and types of neutral salts on the foaming properties of sodium caseinate (중성염의 종류 및 농도가 sodium caseinate의 거품성에 미치는 영향)

  • Yang, Seung-Taek;Park, Hyung-Sun
    • Applied Biological Chemistry
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    • v.36 no.6
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    • pp.434-439
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    • 1993
  • To investigate the effects of neutral salts on the foaming properties of sodium caseinate, turbidity, surface tension, absolute viscosity, foaming ability and foam stability of the caseinate solutions(5%, w/v) with added NaF, $Na_2SO_4$, NaCl, $NaNO_3$, and NaSCN at concentrations of 0.1, 0.5, 1.0, 1.5 and 2.0 M were examined. NaCl and $NaNO_3$ improved the foaming ability compared to sodium caseinate without salt, and also $Na_2SO_4$ and NaF did the foaming ability at the concentrations of 0.1M and 0.5M, while NaSCN did not improve the foaming ability. For foaming ability optimal concentrations of the salts were 0.5, 1.5, and 1.0 M in $Na_2SO_4$, NaCl, and NaSCN, respectively. Additions of $Na_2SO_4$, NaF and $NaNO_3$ at 0.5 M concentrations improved the foam stability of sodium caseinate by 825%, 615%, and 53% compared to control, while those of NaSCN reduced foam stability.

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Measurement of Na intake in Korean Adult Females (우리나라 성인 여성의 Na 섭취량 측정방법의 모색)

  • 김영선
    • Journal of Nutrition and Health
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    • v.20 no.5
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    • pp.341-349
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    • 1987
  • Dietary intakes of na include both the amount present in food materials (nondiscretionary Na intake) and the amount added during cooking and eating to increase salty taste and flavor (discretionary Na intake). In the present study, total Na intake was measured by duplicate food sample collected from each subject for 1 day, nondiscretionary Na intake was calculated by dietary intake record, optimum gustation of salt was measured of from pooled 3-day urine collection in healthy female college students, to measure Na intake more accurately and to find suitable method to estimate total Na intake. Mean values of total, discretionary and mondiscretionary Na intakes were 169.6 mEq, 46.2mEq, and 123.4mEq. respectively. Mean 24-hour urinary Na excretion was 137.9mEq., which was about 84.5% of total intake. Subjects with optimum gustation of salt equal to or higher than 0.5% had significantly higher total Na intake and urinary Na excretion compared to subjects with optimum gustation of salt lower than 5%. Total Na intake of subjects were significantly correlated with optimum gustation of salt, non-discretionary and discretionary Na intakes, and urinary Na excretion. Multiple regression analysis showed that the best estimate of total Na intake is obtained when both optimum gustation of salt and non-discredinary Na intake were used as independent variables (r=.7071). Among the equations using one independent variable, regression, equation with urinary Na excretion provides the best approximation (r=.6627) of total Na intake.

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Separation of Hydrogen-Nitrogen Gases by PDMS-NaA zeolite Mixed Matrix Membranes (PDMS-NaA zeolite 혼합기지분리막에 의한 수소-질소 분리)

  • Kang, Tae Beom;Hong, Se Ryeong
    • Membrane Journal
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    • v.25 no.3
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    • pp.295-300
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    • 2015
  • PDMS-NaA zeolite membranes were prepared by adding 0~40 wt% NaA zeolite. Based on SEM observation, NaA zeolite was dispersed in the PDMS-NaA zeolite membranes with $2{\sim}5{\mu}m$. The permeabilities of $H_2$ and $N_2$ gases through PDMS-NaA zeolite membranes increased as NaA zeolite contents increased and $H_2$ gas had better permeabilities than $N_2$. The selectivity ($H_2/N_2$) of PDMS-NaA zeolite membranes increased as NaA zeolite contents increased.

Hydrothermal Synthetic Study of Zeolites from Siliceous Mudstone (규질 이암으로부터 제올라이트의 수열 합성에 관한 연구)

  • 노진환
    • Journal of the Mineralogical Society of Korea
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    • v.13 no.4
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    • pp.171-185
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    • 2000
  • Siliceous mudstones are embedded on a large scale in the Tertiary formations of Pohang area. Some useful zeolites such as NsP, (Na, TMA)P, analcime and hydroxysodalite were synthesized from the siliceous mudstones by treating with the variety of solution, i.e ., NaOH, NaOH+NaCl, NaOH, NaOH+$NaAlO_2$and NaOH+TMAOH at the low-temperature hydrothermal system ranging 60~12$0^{\circ}C$. Major precursor of zeolites is found as opal-CT in the zeolite-forming reaction. Smectite, which is included in considerable amounts in the mudstone, appears to play a major role of Al-source in the zeolite synthesis. In comparison, chalcedonic quartz and mica are rather insoluble in alkaline solution, and thus, these are observed as major impurities in the reaction products. An addition of $NaAlO_2$to NaOH solution is effective for eliminating these impurities in the reaction procedure, through these are partly dissolved when elevating the reaction temperature, concentration, and time. Phase change from NaP to hydroxysodalite takes place at the NaOH concentrations of 3.0~4.0 M, and the reaction is not sensitive to the temperature shift. NaP is more stable at lower NaOH concentration and higher activity of $Na_{+}$ whereas analcime is sensitive to the temperature change and stable at higher than $100^{\circ}C$ and 2.0~4.0 M in NaOH concentration. For the pure NaP synthesis without any other products, the treatment of mudstones with 1:1 solution of NaOH and $NaAlO _2$ turns out to be quite effective. NaP was successfully synthesized together with analcime at $100^{\circ}C$ as well as lower concentrations of NaOH+NaCl solution. In addition, the organic type, (Na, TMA)P was formed together with smectite in the 1:1 solution of NaOH and TMAOH.

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