• Title/Summary/Keyword: S%2FI Ratio

Search Result 31, Processing Time 0.026 seconds

Nucleophilic Displacement at Sulfur Center (ⅩⅢ). Solvolysis of para-Substituted Benzenesulfonyl Chlorides in MeOH-MeCN Mixtures (황의 친핵성 치환반응 (제13보). 메탄올-아세토니트닐계에서의 파라치환 염화벤젠술포닐의 가용매 분해반응)

  • Ikchoon Lee;In Sun Koo
    • Journal of the Korean Chemical Society
    • /
    • v.25 no.1
    • /
    • pp.7-12
    • /
    • 1981
  • Solvolysis of $p-CH_3, p-H, p-Cl and p-NO_2$-benzenesulfonyl chlorides have heen studied in MeOH-MeCN mixtures. A nonlinear Hammett plot with a ratio order of p-NO_2 > p-CH_3 > p-H > p-Cl was obtained; the reaction was thought to proceed by an S_N1-S_N2 borderline mechanism. In all cases the reactivity was a maximum at 90∼95%(v) methanol, whereas methanol monomer selectivity defined as fi = \frac{k1}{ki}i (k1; observed pseudo-first order rate constant: ki; hypothetical rate constant for MeOH solution having the same polymer structure as in the pure MeOH) was a maximum at 80% methanol with a decreasing order of fi as p-NO_2 > p-Cl > p-H > p-CH_3.$ This was interpreted as the decrease in tightness of transition state; the larger the fi, the tighter is the MeOH attached to the substrate, and hence the more susceptible the substrate becomes to the approaching monomer methanol.

  • PDF

A study on the analysis of bus public Wi-Fi security access trends (버스 공공와이파이 보안 접속 동향 분석에 관한 연구)

  • Choi, Hong-Ju
    • Design & Manufacturing
    • /
    • v.15 no.4
    • /
    • pp.14-23
    • /
    • 2021
  • In this study, we have analyzed the access status and the data usage trend of the public Wi-Fi on the bus, which has not been carried out in the previous studies. The analysis period of this study is 5 months from Nov. 2020 to Mar. 2021. When we compared the access status of Seoul metropolitan and the non-metropolitan region against each region's deployment status ratio, the access ratio of the metropolitan region was higher than the non-metropolitan region, of which the gap was 4.53%. The access for each region showed the growing trend, which was 43.5% on average. The data usage also showed the growing trend, 2.7% on average. Weekly data usage showed the growing trend irrespective of weekdays or weekends. The data usage of the weekdays was 695GB higher than weekends. The data usage during commuting hours including school (7:00~9:00 a.m. and 4:00~6:00 p.m.) was higher than 3,000GB. We can conclude that bus public Wi-Fi was used more actively in non-metropolitan region than Seoul metropolitan region by the office workers and students. The secure access also showed the growing trend. And the secure data usage also showed the growing trend.

The Radiation Efficiency Change according to the Slot Antenna Location (슬롯 안테나의 위치에 따른 방사 효율 연구)

  • Jeon, Ji-Hwan;Liu, Yang;Lee, Jae-Seok;Kim, Hyeong-Dong
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
    • /
    • v.25 no.4
    • /
    • pp.381-386
    • /
    • 2014
  • In this paper, the effect of slot antenna's location in the radiation performance and impedance bandwidth was analyzed. The proposed antenna was designed to operate at Wi-Fi band(2.4~2.5 GHz) when the slot antenna is located at the center of the ground plane, the proposed antenna has a bandwidth of 340 MHz(2.24~2.58 GHz) under voltage standing wave ratio of = 2 and achieves average realized efficiency of 69 % over Wi-Fi bands.

An Analysis on the Factors Affectingy Online Search Effect (온라인 정보탐색의 효과변인 분석)

  • Kim Sun-Ho
    • Journal of the Korean Society for Library and Information Science
    • /
    • v.22
    • /
    • pp.361-396
    • /
    • 1992
  • The purpose of this study is to verify the correlations between the amount of the online searcher's search experience and their search effect. In order to achieve this purpose, the 28 online searchers working at the chosen libraries and information centers have participated in the study as subjects. The subjects have been classified into the two types of cognitive style by Group Embedded Figure Test. As the result of the GEFT, two groups have been identified: the 15 Field Independance ( FI ) searchers and the 13 Field Dependance ( FD ) searchers. The subject's search experience consists of the 3 elements: disciplinary, training, and working experience. In order to get the data of these empirical elements, a questionnaire have been sent to the 28 subjects. An online searching request form prepared by a practical user was sent to all subjects, who conducted searches of the oversea databases through Dialog to retrieve what was requested. The resultant outcomes were collected and sent back to the user to evaluate relevance and pertinence of the search effect by the individual. In this study, the search effect has been divide into relevance and pertinence. The relevance has been then subdivided into the 3 elements : the number of the relevant documents, recall ratio, and the cost per a relevant document. The relevance has been subdivided into the 3 elements: the number of the pertinent documents, utility ratio, and the cost per a pertinent document. The correlations between the 3 elements of the subject's experience and the 6 elements of the search effect has been analysed in the FI and in the FD searchers separately. At the standard of the 0.01 significance level, findings and conclusions made in the study are summarised as follows : 1. There are strong correlations between the amount of training and the recall ratio, the number of the pertinent documents, and the utility ratio on the part of FI searchers. 2. There are strong correlations between the amount of working experience and the number of the relevant documents, the recall ratio on the part of FD searchers. However, there is also a significant converse correlation between the amount of working experience and the search cost per a pertinent document on the part of FD searchers. 3. The amount of working experience has stronger correlations with the number of the pertinent documents and the utility ratio on the part of FD searchers than the amount of training. 4. There is a strong correlation between the amount of training and the pertinence on both part of FI and FD searchers.

  • PDF

Design of Mobile Handset Chip Antenna with a Backside Ground for Wi-Fi Application (후면 그라운드를 이용한 휴대단말 Wi-Fi 칩 안테나 설계)

  • Oh, Sae-Won;Kim, Hyeong-Dong
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
    • /
    • v.23 no.5
    • /
    • pp.592-597
    • /
    • 2012
  • In this paper, a new small chip antenna for Wi-Fi application of the mobile handset is proposed. To miniaturize the chip antenna, the proposed antenna is designed to have the backside ground. The proposed antenna has S-shaped structure, which is designed on the LCP(Liquid Crystal Polymer) with ${\varepsilon}_r$=3.5. The size of the proposed antenna is $6.0mm{\times}2.5mm{\times}1.2mm$. The measured impedance bandwidth under a voltage standing wave ratio (VSWR) of 2 was 300 MHz(fractional bandwidth: 12.2 % 2.3~2.6 GHz), and peak gain is 1.42 dBi. The proposed antenna was designed using CST Microwave Studio commercial software tool. And the fabricated antenna is measured using a network analyzer and in anechoic chamber.

Performance Analysis of MBMS and Wi-Fi Priority Policy in Heterogeneous Networks having a dispersed Single-cell MBMS (분산된 단일 셀 MBMS을 지원하는 이종 네트워크 환경에서 MBMS와 와이파이 사용자 우선 정책에 대한 성능 분석)

  • Jeong, Un Ho;Lee, Jung Moon;Kim, Gi Taek;Nam, Boo Hee;Kim, Dong Hoi
    • Journal of Broadcast Engineering
    • /
    • v.18 no.2
    • /
    • pp.215-224
    • /
    • 2013
  • With the rising popularity of smart-phones, the supply of Internet protocol television is largely increased and it causes the wireless communication network load to be increased. To overcome such an overloading problem, 3GPP is now working on the standardization of MBMS since LTE Release 6 specification. MBMS has good performance in bandwidth efficiency by sharing the same bandwidth with the mulitple MBMS users having the same content. According to the proposed algorithm, in heterogeneous networks having a dispersed Single-cell MBMS where 3GPP network and Wi-Fi network are mixed, if the number of MBMS users, who are belonging to cells supporting a dispersed Single-cell MBMS, is more than a specified threshold, the MBMS priority policy is operated. Otherwise, the Wi-Fi priority policy is executed. As the simulation results show both the increase of total available bandwidth ratio and the decrease of network usage cost, it is confirmed that the proposed scheme allows the network efficiency to be maximized.

The Association between Mortality and the Oxygen Saturation and Fraction of Inhaled Oxygen in Patients Requiring Oxygen Therapy due to COVID-19-Associated Pneumonia

  • Choi, Keum-Ju;Hong, Hyo-Lim;Kim, Eun Jin
    • Tuberculosis and Respiratory Diseases
    • /
    • v.84 no.2
    • /
    • pp.125-133
    • /
    • 2021
  • Background: The coronavirus disease (COVID-19) can manifest in a range of symptoms, including both asymptomatic systems which appear nearly non-existent to the patient, all the way to the development of acute respiratory distress syndrome (ARDS). Specifically, COVID-19-associated pneumonia develops into ARDS due to the rapid progression of hypoxia, and although arterial blood gas analysis can assist in halting this deterioration, the current environment provided by the COVID-19 pandemic, which has led to an overall lack of medical resources or equipment, has made it difficult to administer such tests in a widespread manner. As a result, this study was conducted in order to determine whether the levels of oxygen saturation (SpO2) and the fraction of inhaled oxygen (FiO2) (SF ratio) can also serve as predictors of ARDS and the patient's risk of mortality. Methods: This was a retrospective cohort study conducted from February 2020 to Mary 2020, with the study's subjects consisting of COVID-19 pneumonia patients who had reached a state of deterioration that required the use of oxygen therapy. Of the 100 COVID-19 pneumonia cases, we compared 59 pneumonia patients who required oxygen therapy, divided into ARDS and non-ARDS pneumonia patients who required oxygen, and then investigated the different factors which affected their mortality. Results: At the time of admission, the ratios of SpO2, FiO2, and SF for the ARDS group differed significantly from those of the non-ARDS pneumonia support group who required oxygen (p<0.001). With respect to the predicting of the occurrence of ARDS, the SF ratio on admission and the SF ratio at exacerbation had an area under the curve which measured to be around 85.7% and 88.8% (p<0.001). Multivariate Cox regression analysis identified that the SF ratio at exacerbation (hazard ratio [HR], 0.916; 95% confidence interval [CI], 0.846-0.991; p=0.029) and National Early Warning Score (NEWS) (HR, 1.277; 95% CI, 1.010-1.615; p=0.041) were significant predictors of mortality. Conclusion: The SF ratio on admission and the SF ratio at exacerbation were strong predictors of the occurrence of ARDS, and the SF ratio at exacerbation and NEWS held a significant effect on mortality.

Consumption of Han-sik and its Association with Socioeconomic Status among Filipino Immigrant Women: the Filipino Women's Diet and Health Study (FiLWHEL) (필리핀 결혼이민여성의 한식 섭취실태 및 한식 섭취율에 따른 사회경제학적 요인)

  • Kim, Nayeon;Kang, Minji;Abris, Grace;Provido, Sherlyn Mae P.;Joung, Hyojee;Hong, Sangmo;Yu, Sung Hoon;Lee, Chang Beom;Lee, Jung Eun
    • Korean Journal of Community Nutrition
    • /
    • v.23 no.6
    • /
    • pp.475-487
    • /
    • 2018
  • Objectives: This study examined the consumption of Han-sik and its association with the years of residence in Korea and the socioeconomic status among Filipino immigrant women of the Filipino Women's Diet and Health Study (FiLWHEL). Methods: A total of 474 Filipino women married to Korean men were included in the analysis. Their dietary intake was assessed using a single-day 24-hour recall. The participants provided information on the demographics, socioeconomic, and health-related factors through face-to-face interviews. The generalized linear model and logistic regression model were used to examine the association between the socioeconomic status and consumption of Han-sik. Results: The mean age of the participants was 34.3 years old, and the average duration of residence in Korea was 8.2 years. Among 474 Filipino women, a total of 467 consumed Han-sik, with an average of 6.8 food items per day. The Han-sik foods that the participants consumed most frequently were rice, cabbage kimchi, mixed-grain rice, and fried eggs. The average ratio of Han-sik was 58.57%. The ratio of Han-sik showed no significant associations with the years of residence, years of living together with their husband, education levels, total annual family income, or linguistic competence of Korean. However, the ratio of Han-sik use was associated with cohabitation with parents-in-law; the odds ratio (95% confidence interval) was 2.41 (1.18-4.92, p-trend = 0.002) comparing the fourth quartile with the first quartile of the Han-sik ratio. Conclusions: Filipino immigrant women in the FiLWHEL study consumed a larger number of Han-sik than Philippine foods. In addition, cohabitation with their parents-in-law was associated with the consumption of Han-sik. Further epidemiologic studies will be needed to determine how the diet affects the health and wellbeing of immigrant women in Korea.

Estimating the Relative Contribution of Organic Phosphorus to Organic Matters with Various Sources Flowing into a Reservoir Via Fluorescence Spectroscopy (형광스펙트럼을 이용한 유역 하류 저수지의 유입 유기물 내 유기인 기여도 평가)

  • Mi-Hee Lee;Seungyoon Lee;Jin Hur
    • Journal of Korean Society on Water Environment
    • /
    • v.40 no.2
    • /
    • pp.67-78
    • /
    • 2024
  • The introduction of a significant amount of phosphorous into aquatic environments can lead to eutrophication, which can in turn result in algal blooms. For the effective management of watersheds and the prevention of water quality problems related to nonpoint organic matter (OM) sources, it is essential to pinpoint the predominant OM sources. Several potential OM sources were sampled from upper agricultural watersheds, such as fallen leaves, riparian reeds, riparian plants, paddy soil, field soil, riparian soil, cow manure, and swine manure. Stream samples were collected during two storm events, and the concentrations of dissolved organic carbon (DOC) and phosphorous (DOP) from these OM sources and stream samples were assessed. DOM indicators using fluorescence spectroscopy, including HIX, FI, BIX, and EEM-PARAFAC, were evaluated in terms of their relevance in discerning DOM sources during storm events. Representative DOM descriptors were chosen based on specific criteria, such as value ranges and pronounced differences between low and high-flow periods. Consequently, the spectral slope ratio (SR) paired with fluorescence index (FI) using end-member mixing analysis (EMMA) proved to be suitable for estimating the contribution of organic carbon (OC). The contribution of each organic phosphorous (OP) in stream samples was determined using the phosphorous-to-carbon (P/C) ratio in conjunction with the OC contribution. Notably, OP derived from swine manure in stream samples was found to make the most dominant contribution, ranging from 61.3% to 94.2% (average 78.1% ± 12.7%). The results of this research offer valuable insights into the selection of suitable indicators to recognize various OM sources and highlight the main sources of OP in forested-agricultural watersheds.

Different Coefficients and Exponents for Metabolic Body Weight in a Model to Estimate Individual Feed Intake for Growing-finishing Pigs

  • Lee, S.A.;Kong, C.;Adeola, O.;Kim, B.G.
    • Asian-Australasian Journal of Animal Sciences
    • /
    • v.29 no.12
    • /
    • pp.1756-1760
    • /
    • 2016
  • Estimation of feed intake (FI) for individual animals within a pen is needed in situations where more than one animal share a feeder during feeding trials. A partitioning method (PM) was previously published as a model to estimate the individual FI (IFI). Briefly, the IFI of a pig within the pen was calculated by partitioning IFI into IFI for maintenance ($IFI_m$) and IFI for growth. In the PM, $IFI_m$ is determined based on the metabolic body weight (BW), which is calculated using the coefficient of 106 and exponent of 0.75. Two simulation studies were conducted to test the hypothesis that the use of different coefficients and exponents for metabolic BW to calculate $IFI_m$ improves the accuracy of the estimates of IFI for pigs, and that PM is applied to pigs fed in group-housing systems. The accuracy of prediction represented by difference between actual and estimated IFI was compared using PM, ratio (RM), or averaging method (AM). In simulation studies 1 and 2, the PM estimated IFI better than the AM and RM during most of the periods (p<0.05). The use of 0.60 as the exponent and the coefficient of 197 to calculate metabolic BW did not improve the accuracy of the IFI estimates in both simulation studies 1 and 2. The results imply that the use of $197kcal{\times}kg\;BW^{0.60}$ as metabolizable energy for maintenance in PM does not improve the accuracy of IFI estimations compared with the use of $106kcal{\times}kg\;BW^{0.75}$ and that the PM estimates the IFI of pigs with greater accuracy compared with the averaging or ratio methods in group-housing systems.