• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.7 no.4
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• pp.219-227
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• 2009

The effect of organic acids on the adsorption of U(VI) onto oxide surfaces ($TiO_2)$(anatase), $SiO_2$(amorphous) and $Al_2O_3$(amorphous)) has been investigated. Two different organic acids, salicylic and picolinic acids, were used. Changes of adsorption ratio of U(VI), which depend on the existence of organic acids in a sample, were measured as a function of pH. Quantities of adsorbed organic acids, which depend on the existence of U(VI) in a sample, were also measured as a function of pH. It is confirmed that the soluble complex formation of U(VI) with organic acids can deteriorate the adsorption of U(VI) onto $TiO_2$ surface. It is noteworthy that salicylic acid does not affect the adsorption of U(VI) onto $SiO_2$ surface, however, picolinic acid enhances the adsorption of U(VI) onto $SiO_2$ surface. The latter effect can be understood by considering the formation of a ternary surface complex on $SiO_2$ surface, which was confirmed by the co-adsorption of picolinic acid with U(VI) and the change in a fluorescence spectra of U(VI) on surface, In the case of $Al_2O_3$, organic acids themselves were largely adsorbed onto a surface without deteriorating the adsorption of U(VI). This would support the possibility of a ternary surface complex formation on the $Al_2O_3$ surface, and an additional spectroscopic study is required.

• Journal of Korean Society of Water and Wastewater
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• v.32 no.2
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• pp.123-130
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• 2018

This paper provided the information related to the removal of 2,4,6-tribromophenol using in-situ and stable liquid ferrates(VI). This research's goal was to observe the differences of oxidation power between in-situ liquid ferrate(VI) and stable liquid ferrate(VI). The in-situ liquid ferrate(VI) ($FeO_4{^{2-}}$) has been successfully produced with the concentration 42,000 ppm (Fe) after 11 minutes of reaction time. The stable liquid ferrate(VI) was also successfully produced following the modification method by Sharma with the produced concentrations 7,000 ppm. The stable liquid ferrate(VI) was stable for 44 days and slightly decreased afterwards. This research has been carried out using 2,4,6-tribromophenol as the representative compound. Both of ferrates(VI) have the highest oxidation capability at the neutral condition. Furthermore, the stable liquid ferrate(VI) has higher oxidation power than the in-situ liquid ferrate(VI).

• Journal of Microbiology
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• v.38 no.1
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• pp.36-39
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• 2000

Toxic hexavalent chromium, Cr(VI), was reduced to a less toxic trivalent chromium form by E. coli ATCC 33456. The suitable electron donor for Cr(VI) reduction was glucose. E. coli ATCC 33456 was more resistant to metal cations than other reported Cr(VI) reducing microorganisms. Cell growth was inhibited by the presence of Cr(VI) in a liquid medium and Cr(VI) reduction accompanied cell growth. With a hydraulic retention time of 20 h, Cr(VI) reducing efficiency was 100% to 84% when Cr(VI) concentration in the influent was in the range of 10 to 40 mg L$\^$-1/. Specific rate of Cr(VI) reduction was 2.41 mg Cr(VI) g DCW$\^$-1/ h$\^$-1/ when 40 mg L$\^$-1/ of Cr(VI) influent was used. This result suggested the potential application of E. coli ATCC 33456 for the detoxification of Cr(VI) in Cr(VI) contaminated wastewater.

• Analytical Science and Technology
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• v.6 no.5
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• pp.489-499
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• 1993

Some sorption behaviors of U(VI) ion on Arsenazo I-XAD-2 chelating resin were investigated. This chelating resin was synthesized by the diazonium coupling of Amberlite XAD-2 resin with Arsenzo I chelating reagent and characterized by elementary analysis method and IR spectrometry. The optimum conditions for the sorption of U(VI) ion were examined with respect to pH, U(VI) ion concentration and shaking time. Total sorption capacity of this chelating resin on U(VI) ion was 0.39mmol U(VI)/g resin in the pH range of 4.0~4.5. This chelating resin was showed increased sorption capacity on the increased pH value. It was confirmed that sorption mechanism of U(VI) ion on the Arsenazo I-XAD-2 chelating resin was competition reacting between U(VI) ion and $H^+$ ion. Breakthrough volume and overall capacity of U(VI) ion measured by column were was 600 ml and 0.38 mmol U(VI)/g resin, respectively. The desorption of U(VI) ion was showed recovery of 90~96% using 3M $HNO_3$ and 3M $Na_2CO_3$ as a desorption solution. The separation and concentration of U(VI) ion from natural water and sea water was performed successfully by Arsenazo I-XAD-2 chelating resin.

• Journal of Microbiology and Biotechnology
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• v.23 no.8
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• pp.1123-1132
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• 2013

The removal of toxic Cr(VI) by microorganisms is a promising approach for Cr(VI) pollution remediation. In the present study, four indigenous bacteria, named LY1, LY2, LY6, and LY7, were isolated from Cr(VI)-contaminated soil. Among the four Cr(VI)-resistant isolates, strain LY6 displayed the highest Cr(VI)-removing ability, with 100 mg/l Cr(VI) being completely removed within 144 h. It could effectively remove Cr(VI) over a wide pH range from 5.5 to 9.5, with the optimal pH of 8.5. The amount of Cr(VI) removed increased with initial Cr(VI) concentration. Data from the time-course analysis of Cr(VI) removal by strain LY6 followed first-order kinetics. Based on the 16S rRNA gene sequence, strain LY6 was identified as Pseudochrobactrum asaccharolyticum, a species that had never been reported for Cr(VI) removal before. Transmission electron microscopy and energy dispersive X-ray spectroscopy analysis further confirmed that strain LY6 could accumulate chromium within the cell while conducting Cr(VI) removal. The results suggested that the indigenous bacterial strain LY6 would be a new candidate for potential application in Cr(VI) pollution bioremediation.

• Resources Recycling
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• v.28 no.1
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• pp.55-61
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• 2019

The extraction behavior of Mo(VI) and W(VI) from dilute chloride solution was investigated by employing amine (Alamine308 and TEHA) and neutral extractants (TOP) in the solution pH range from 2 to 9. W (VI) was selectively extracted over Mo(VI) by these three extractants and TEHA led to the highest separation factor. Without the pretreatment protonation of the tertiary amines, the extraction percentage of the two metal ions decreased steadily to zero as solution pH increased to 9. The extraction behavior of the metals was discussed on the basis of the distribution diagram of each metal. Alamine 308 and TEHA were much better than TOP in extracting and separating the two metal ions.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2010.06a
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• pp.126-126
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• 2010

대표적인 친환경 차단부로 Vacuum Interrupter(VI)를 에폭시 수지로 성형한 Embedded VI 의 적용이 확대되고 있다. 이러한 Embedded VI의 제작에 있어, 기존에는 대부분 VI의 Ceramic 표면과 에폭시 성형층의 계면에 고무재질의 완충층을 적용하는 방식으로 제작되었다. 본 연구에서는 이러한 완충층 형성시 발생되는 문제를 해결하기 위한 방법으로 VI외부에 추가적인 완충층을 형성하지 않고, 에폭시 수지를 성형하는 Direct Molding 방안을 제시하고. VI표면과 에폭시간에 화학적 결합 메커니즘을 도출하여 Direct Molding 을 적용한 Embedded VI의 제작기술을 개발하였다.

• Rapid Communication in Photoscience
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• v.4 no.3
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• pp.73-75
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• 2015

Cr(VI) reduction was successfully achieved in the presence of cationic micelles (CMs) under visible light illumination. Micelle formation of cationic surfactants seems to be critical in Cr(VI) reduction. Cr(VI) was reduced very fast above the critical micelle concentration (cmc) of CTAB solutions, but was not reduced at all either below or around the cmc of CTAB. The reduction rate of Cr(VI) was enhanced in the absence of dissolved oxygen, supporting that the removal of Cr(VI) should be achieved via a reductive pathway. When CTAB was substituted by Brij 35 or SDS, the reduction of Cr(VI) was negligible. This indicates that the electrostatic interaction between Cr(VI) and headgroups of surfactants is important in the visible light-induced Cr(VI) reduction in micellar solutions.

• Journal of Advanced Marine Engineering and Technology
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• v.39 no.6
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• pp.592-598
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• 2015

In this study, we experimentally investigate the performance characteristics of a high-performance summer-cooling heat pump for an R410A by applying an air-cooled-type vapor-injection (VI) cycle. The devices used for the experiment consist of a VI compressor, condenser, oil separator, plate-type heat-exchanger, economizer, evaporator, and re-cooler. The experimental conditions employed for the cooling performance were divided into three cycles. First, in Cycle A, we apply a VI cycle and with no heat exchange between the evaporator outlet refrigerant and the VI cycle suction refrigerant in the re-cooler. For Cycle B, there is heat exchange, and for Cycle C, there is neither a VI cycle nor heat exchange between the evaporator outlet refrigerant and the VI cycle suction refrigerant. From the analysis results, we observe that the performance was highest in the VI cycle with heat exchange between the evaporator outlet refrigerant and the VI cycle suction refrigerant (Cycle B), while it was lowest in Cycle C without application of the VI cycle. Moreover, the cooling coefficient of Performance ($COP_C$) averaged 3.5 in Cycle B, which was 8.6% higher than the corresponding value in Cycle A, and 33% higher than that in Cycle C.

• Proceedings of the Korean Information Science Society Conference
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• 2003.10c
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• pp.712-714
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• 2003

과거 우리는 장비에 대한 제어 및 모니터링 소프트웨어의 효율적인 생성을 위한 프레임웍[1][2]을 제안하였다. 제안한 프레임웍은 세가지의 XML 문서(IID, MAP, CMIML), VI Wizard, Generator로 구성되었다. 본 논문에서는 제안한 프레임웍의 핵심이라고 할 수 있는 VI Wizard에 대한 설계와 구현을 보인다. VI Wizard는 장비의 인터페이스 정보를 기술하고 있는 IID(Instrument Interface Description) 문서를 이용해서 GUI 기반으로 VI(Virtual Instrument)를 구성하고, 새롭게 구성된 VI를 이용하여 장비의 제어정보, 사용자 인터페이스 정보, 모니터링 정보, 통신 정보, 스케줄 정보 등을 기술하는 CMIML(Control & Monitoring Instrument Markup Language)문서를 생성한다.