• Structural Engineering and Mechanics
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• v.25 no.4
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• pp.423-444
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• 2007

By using the incremental form of the endochronic theory of plasticity, a model of material function is proposed in this paper to investigate plastic behavior. By comparing the stress-strain hysteresis loop, the theory is shown to agree well with the experimental results, especially in the evolution of peak stress values of SAE 4340 steel loaded by cyclic loading with various amplitudes. Depending on the choice of material parameters, the present model can substantially result in six categories of material function, each of which can behave differently with respect to an identical deformation history. In addition, the present model of material function is shown to be capable of describing the behavior of erasure of memory of materials, as experimentally observed by Lamba and Sidebottom (1978).

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2000.05b
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• pp.269-272
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• 2000

Spinel $LiMn_2O_4$ samples are prepared by heating a $LiOH{\cdot}H_2O/MnO_2$ mixture in air at $800^{\circ}C$ for 36h, and their structure and electrochemical performance are studied by using X-ray diffraction, Cyclic Voltammetry, AC Impedance, and Charge-discharge measurements. It was found that the electrochemical properties of the $LiMn_2O_4$ samples are very sensitive to substituted volume of lithium. Initial impedances of all cathode was similar. Initial resistance was $60{\sim}70{\Omega}$. Reaction peak of Cyclic voltammetry was weak by increase of substituted volume of lithium. $Li[Li_{0.08}Mn_{1.92}]O_4$ and $Li[Li_{0.1}Mn_{1.9}]O_4$ cathode materials showed the charge and discharge capacity of about 125mAh/g at first cycle, and about 95mAh/g after 70th cycle. It showed excellent property in sample revealed good structure and other electrochemical property.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1996.11a
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• pp.105-108
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• 1996

The positive active material for polymer film battery was prepared by using Polyphenylenediamine(PPD) synthesized in our lab. and 2.5-dimercapto-1, 3, 4-thiadiazole(DMcT) in various mixture ratio. The transference measurement of surface morphology and thermal stability of prepared composite film was carried out by using SEM and TGA, respectively. Electrocyhemical property and electrical conductivity of composite film were also measured by using cyclic voltammetry and four-probe method in dry box, respectively. The thermal stability of prepared composite film is more than 20$0^{\circ}C$. The electrical conductivity of composite film increased and showed the highest value(about 3 S/cm)when doped at 0.4% LiClO$_4$solution. And we could confirm that DMcT effect on reactiviation of PPD through cyclic voltammogram.

• Advances in concrete construction
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• v.13 no.6
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• pp.423-431
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• 2022

Although the influence of moisture content on the mechanical properties of concrete has been studied for a long time, research related to its influence on the damping and energy dissipation property of concrete structure is still very limited. In this paper, the relationship between damping property and moisture content of concrete using cyclic uniaxial compression is firstly presented, and the mechanism of the influence of moisture content on concrete damping and energy dissipation capacity is analyzed. Based on the experimental research, moisture-related damping and energy dissipation model is proposed. Results show that the dissipated energy of concrete and loss factor increase as the moisture content increasing. The energy dissipation coefficient reflecting the influence of stress level of concrete under cyclic load, decreases first and then increases as the moisture content increasing. The mechanism of moisture-related energy dissipation behavior can be divided into the reactive force of water, the development of the internal micro cracks and the pore water pressure. Finally, the proposed moisture-related damping and energy dissipation model are verified.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2004.07b
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• pp.878-881
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• 2004

When it converted solar energy or light energy into chemical energy, it studied the electric charge transfer property of the viologen which is used widely as the electron acceptor for the electric charge delivery mediation of the devices. It was formed monolayer in QCM by self-assembled viologen. The absorbed quantities of viologen's electron through peak current and to analyze the electron transfer property of viologen in redox reaction made experiments in cyclic voltammetry among the electrochemical process. It studied the electron transfer relation of viologen from changing the anion in 0.1M NaCl and $NaClO_4$ electrolyte and the interrelation between scan rate and peak current when scan rate increased twice.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2000.07a
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• pp.544-547
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• 2000

Polypyrrole (PPy) was chemically synthesized within the pores of nanoporous polycarbonate (PC) Particle Track-etched Membranes (nano-PTM). Hollow tubules are formed because polypyrrole initially deposits on the surface of the pores walls. By running successive syntheses, we have obtained wires (filled tubules). The redox property of PPy nanotubules was investigated by cyclic voltammetry. The redox potential was lowered as much as 0.5V vs. Ag/AgC1, comparing with electrosynthesized PPy film. It suggests that an electron hopping mechanism of PPy nanotubules was improved. Electric conductivity of PPy nanotubules and nanowire was evaluated. We obtained good electric conductivity of PPy nanotubules even in the neutral state. The conductivity and activation energy were $10^1$ order at the room temperature and 25.3 meV respectively.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2005.07a
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• pp.395-396
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• 2005

We fabricated self-assembled monolayers(SAMs) onto quartz crystal microbalance(QCM) using viologen, which has been widely used as electron acceptor and electron transfer mediator. We determined the time dependence to resonant frequency shift during self-assembly process and observed the morphology of self-assembled mono layers by STM and investigated the electrochemical behavior of SAMs by cyclic voltammetry. Electrochemical deposition of viologen was investigated using electrochemical quartz crystal microbalance(EQCM). The redox reactions of viologen were highly reversible and the EQCM has been employed to monitor the electrochemically induced adsorption of SAMs during the redox reactions.

• Journal of Biosystems Engineering
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• v.17 no.1
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• pp.79-90
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• 1992

Viscoelastic characteristics of agricultural products may be determined through three basic tests ; stress relaxation, creep, and dynamic test. Considering the changeability of living materials, dynamic test in which information is derived in a relatively short time appears to be highly desirable, in which either cyclic stress or cyclic strain is imposed and the remaining quantity (strain or stress) is measured. The periodically varying stress will also result in periodically varying strain which in a viscoelastic material should theoretically be out of phase with the stress, because part of the energy subjected to sample is stored in the material as potential energy and part is dissipated as heat. This behavior results in a complex frequency-dependent compliance denoted by J($i{\omega}$). The complex compliance and therefore the storage compliance, the loss compliance, the phase angle, and percent energy loss for the sample should be obtainable with a given static viscoelastic property of the material under static load. The complex compliance of the rough rice kernel were computed from the Burger's model describing creep behavior of the material which were obtained in the previous study. Also, the effects of cyclic load and moisture content of grain on the dynamic viscoelastic behavior of the samples were analyized. The results obtained from this study were summarized as follows ; 1. The storage compliance of the rough rice kernel slightly decreased with the frequency applied but at above the frequency of 0.1 Hz it was nearly constant with the frequency, and the loss compliance of the sample very rapidly decreased with increase in the frequency on those frequency ranges. 2. It was shown that the storage compliance and the loss compliance of the sample increased with increase in grain moisture content. Effect of grain moisture content on the storage compliance of the sample was highly significant than effect of the frequency applied, but effect of the frequency on the loss compliance of the sample was more significant than effect of grain moisture content. 3. In low moisture content, the percent energy loss of Japonica-type rough rice was much higher than that of Indica-type rough rice, but, in high moisture content, vice versa.

• Journal of the Society of Naval Architects of Korea
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• v.50 no.1
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• pp.41-48
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• 2013

Several fatigue damages have recently been reported which cannot be resolved in the context of the existing fatigue design procedure, and they are suspected to be the cracks induced by the low cycle fatigue mechanism. To tackle the problem, a series of material tests together with fatigue tests have been carried out, and elasto-plastic notch strain analysis using nonlinear kinematic hardening model has been performed. The cyclic stress-strain curves are obtained and the nonlinear kinematic hardening model was calibrated based on the obtained material data. Also, the fatigue test with non-load-carrying cruciform fillet welded joint has been performed in low cycle fatigue regime. Then, the notch strain analyses have been carried out to find the precise elasto-plastic behavior of the material at the notch root of the cruciform joint. The variation of the material property from the base metal via HAZ up to the weld metal was taken into account using spatial variation of the material property. Then the detail elasto-plastic behavior of the welded joint subjected to the repeated cyclic loading has been investigated further through the comparison with the prediction with Neuber's rule. The calibration of the nonlinear kinematic hardening model and nonlinear notch strain analyses have been performed using the commercial FE program ABAQUS.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2004.07b
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• pp.874-877
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• 2004

We carried out this subject to observe electrochemical properties of 1,2-dioleoyl-sn- glycero-3-phosphocholine(DOPC) mixed with fatty acid containing azobenzene group by using cyclic voltammetry with a three-electrode system, An Ag/AgCl reference electrode, a platinum wire counter electrode and LB film-coated ITO working electrode in $NaClO_4$ solution. We investigated the photoisomerization and electrochemical property of the organic ultra thin film of fatty acid containing azobenzene was prepared on the hydrophilic ITO(idium tin oxide) glass plate by LB method. As a result, the absorption spectra of BASH and DOPC of mixture LB films was induced to photoisomerization by alternating irradiation of ultraviolet and visible light. A measuring range was reduced from initial potential to -1350mV, continuously oxidized to 1650 mV and measured to the initial point. The scan rate were 50, 100, 150 and 200 mV/s. As a results, LB films of BASH-DMPC appeared reversible process caused by the reduction-oxidation current from the cyclic voltammogram.