A Study on the Energy Transfer of YAlO3:Tbx3+ using Decay Curves

YAlO3:Tbx3+에서 발광소멸 곡선을 이용한 에너지 전달에 관한 연구

  • 김광철 (한국기술교육대학교 교양학부 물리학전공) ;
  • 최진수 (국방과학연구소)
  • Received : 2015.02.26
  • Accepted : 2015.03.23
  • Published : 2015.03.31

Abstract

$YAlO_3:Tb{_x}^{3+}$ has been synthesized by a combustion process and the concentration x of Tb was varied from 0.001 and 0.05 mol% per mole of YAlO3. The energy transfer of $^5D_3{\rightarrow}^7F_6$(385nm) and $^5D_4{\rightarrow}^7F_5$(544nm) transitions on the $YAlO_3:Tb{_x}^{3+}$(x =0.001, 0.05) have been investigated by using decay curves. The energy transfer mechanism was explained by Inokuti and Hirayama model. The results of calculation and fitting showed that values of n are 6.11(x=0.01) and 6.13(x=0.005). These indicate that the energy transfer mechanism between $Tb^{3+}$ ions is dipole-dipole interaction.

Keywords

References

  1. N. J. Turro, "Modern Molecular Photochemistry", Benjamin California, Chap. 9, 1978.
  2. V. M. Agranovich and M. D. Galanin, "Modern Problems in Condensed Matter Sciences", North-Holland Amsterdam, Vol. 3, 1982.
  3. A. Hara and Y. Gondo, "Energy-Donor Phosphorescence and Energy Transfer by Exchange Interaction in a Rigid Matrix", J. Chem. Phys., Vol. 85(4), pp. 1894-1897, 1986. https://doi.org/10.1063/1.451132
  4. G. J. Yi, J. A. Tuchman, and G. F. Neumark, "Excitation Transfer in Donor-Acceptor Pair Luminescence", Applied Physics Letters, Vol. 58(5), pp. 520-522, 1991. https://doi.org/10.1063/1.104601
  5. H. S. Jeon, S. K. Kim, S. C. Kim, S. H. Park, H. L. Park, and S. I. Mho, "Indirect Energy Transfer of $Ce^{3+}{\rightarrow}Eu^{2+}$ in $CaAl_{12}O_{19}$ Phosphor", Solid State Comm., Vol. 102(7), pp. 555-559, 1997. https://doi.org/10.1016/S0038-1098(97)00036-7
  6. H. S. Jeon, S. K. Kim, H.L.Park, G. C. Kim, J. H. Bang, and M. Lee, "Observation of Two Independent Energy Transfer Mechanisms in $BaAl_{12}O_{19}:Ce^{3+}{_{0.06}}+Eu^{2+}{_x}$ Phosphor", Solid State Comm., Vol. 120, pp. 221-225, 2001. https://doi.org/10.1016/S0038-1098(01)00323-4
  7. K. H. Kown, W. B. Im, H. S. Jang, H.S. Yoo, and D. Y. Jeon, "Luminescence Properties and Energy Transfer of Site-Sensitive $Ca_{6-x-y}Mg_{x-z}(PO_4)_4:Eu^{2+}{_y}$, $Mn^{2+}{_z}$ Phosphors and Their Application to Near-UV LED-Based White LEDs", Inorganic Chemistry, Vol. 48, pp. 11525-11532, 2009. https://doi.org/10.1021/ic900809b
  8. S. Taen, "Molecular Size and Luminescence decay Influenced by Energy Transfer by the Exchange Mechanism", J. Chemical Physics, Vol. 108(16), pp. 6857-6860, 1998. https://doi.org/10.1063/1.476099
  9. B. Henderson and G. F. Imbusch, "Optical Spectroscopy of Inorganic Solids", Clarendon Press Oxford, pp. 505-540,1989.
  10. V. M. Kenkrem and R. S. Knox, Physical Review, Vol. B9, pp. 5274,1974.
  11. Th. Forster, Ann. Physik, Vol. 2, pp. 55, 1948.
  12. D. L. Dexter, J. Chemical Physics, Vol. 43, pp. 1978, 1965. https://doi.org/10.1063/1.1697063
  13. M. Inokuti and F. Hirayama, "Infulence of Energy Transfer by the Exchange Mechanism on Donor Luminescence", J. Chemical Physics, Vol. 43(6), pp. 1978-1989, 1965. https://doi.org/10.1063/1.1697063
  14. G. C. Kim, J. S. Choi, and S. N. Lee, "Study on the Energy Process of $YAlO_3:Tb{_x}^{3+}$ Using Time-Resolved Photoluminescence" J. Korean Society for Imaging & Technology, Vol. 16(1), pp. 17-23, 2010.