Corrosion Science and Technology

The Corrosion Science Society of Korea (한국부식방식학회)
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Effect of Zn/Al Cation Ratio on Corrosion Inhibition Capabilities of Hydrotalcites Containing Benzoate Against Carbon Steel

  • Thu Thuy, Pham (Institute for Tropical Technology, Vietnam Academy of Science and Technology) ;
  • Anh Son, Nguyen (Institute for Tropical Technology, Vietnam Academy of Science and Technology) ;
  • Thu Thuy, Thai (Institute for Tropical Technology, Vietnam Academy of Science and Technology) ;
  • Gia Vu, Pham (Institute for Tropical Technology, Vietnam Academy of Science and Technology) ;
  • Ngoc Bach, Ta (Institute of Materials Science, Vietnam Academy of Science and Technology) ;
  • Thuy Duong, Nguyen (Institute for Tropical Technology, Vietnam Academy of Science and Technology) ;
  • To Thi Xuan, Hang (Institute for Tropical Technology, Vietnam Academy of Science and Technology)
  • Received : 2022.07.19
  • Accepted : 2022.08.17
  • Published : 2022.12.30
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Abstract

Corrosion inhibitors based on Zn-Al hydrotalcites containing benzoate (ZnAlHB) with different molar ratios of Zn/Al were prepared with a co-precipitation process. Compositions and structures of the resulting hydrotalcites were studied with suitable spectroscopic methods such as inductively coupled plasma mass spectrometry (ICP-MS), ultraviolet-visible spectrophotometry (UV-Vis), scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and surface zeta potential measurements, respectively. Results of physico-chemical studies showed that crystallite sizes, compositions of products, and surface electrical properties were significantly changed when the molar ratio of Zn/Al was increased. The release of benzoate from hydrotalcites also differed slightly among samples. Anticorrosion abilities of hydrotalcites intercalated with benzoate at a concentration of 3 g/L on carbon steel were analyzed using electrochemical impedance spectroscopy (EIS), polarization curve, energy-dispersive X-ray spectroscopy (EDX), and SEM. Corrosion inhibition abilities of benzoate modified hydrotalcites in 0.1 M NaCl showed an upward trend with increasing Zn/Al ratio. The reason for the dependence of corrosion resistance on the Zn/Al ratio was discussed, including changes in the microstructure of hydrotalcites such as crystal size, density, uniformity, and formation of ZnO.

Keywords

Acknowledgement

The authors gratefully acknowledge the financial support of Vietnam Academy of Science and Technology for young researchers.

References

  1. M. Chen, H. Cen, C. Guo, X. Guo, Z. Chen, Preparation of Cu-MOFs and its corrosion inhibition effect for carbon steel in hydrochloric acid solution, Journal of Molecular Liquids, 318, 114328 (2020). Doi: https://doi.org/10.1016/j.molliq.2020.114328
  2. A. Fiala, W. Boukhedena, S.E. Lemallem, H. Brahim Ladouani, H. Allal, Inhibition of Carbon Steel Corrosion in HCl and H2SO4 Solutions by Ethyl 2-Cyano-2-(1,3-dithian-2-ylidene) Acetate, Journal of Bio- and Tribo-Corrosion, 5, 42 (2019). Doi: https://doi.org/10.1007/s40735-019-0237-5
  3. N.A. Negm, N.G. Kandile, E.A. Badr, M.A. Mohammed, Gravimetric and electrochemical evaluation of environmentally friendly nonionic corrosion inhibitors for carbon steel in 1M HCl, Corrosion Science, 65, 94 (2012). Doi: https://doi.org/10.1016/j.corsci.2012.08.002
  4. C. Liang, Z. Liu, Q. Liang, G.-C. Han, J. Han, S. Zhang, X.-Z. Feng, Synthesis of 2-aminofluorene bis-Schiff base and corrosion inhibition performance for carbon steel in HCl, Journal of Molecular Liquids, 277, 330 (2019). Doi: https://doi.org/10.1016/j.molliq.2018.12.095
  5. A. Thoume, A. Elmakssoudi, D.B. Left, N. Benzbiria, F. Benhiba, M. Dakir, M. Zahouily, A. Zarrouk, M. Azzi, M. Zertoubi, Amino acid structure analog as a corrosion inhibitor of carbon steel in 0.5 M H2SO4: Electrochemical, synergistic effect and theoretical studies, Chemical Data Collections, 30, 100586 (2020). Doi: https://doi.org/10.1016/j.cdc.2020.100586
  6. Y. Nie, J. Gao, E. Wang, L. Jiang, L. An, X. Wang, An effective hybrid organic/inorganic inhibitor for alkaline aluminum-air fuel cells, Electrochimica Acta, 248, 478 (2017). Doi: https://doi.org/10.1016/j.electacta.2017.07.108
  7. Z. Zheng, O. Olayinka, B. Li, 2S-Soy Protein-Based Biopolymer as a Non-Covalent Surfactant and Its Effects on Electrical Conduction and Dielectric Relaxation of Polymer Nanocomposites, Engineered Science, 4, 87 (2018). Doi: https://dx.doi.org/10.30919/es8d766
  8. K. Hu, J. Zhuang, J. Ding, Z. Ma, F. Wang, X. Zeng, Influence of biomacromolecule DNA corrosion inhibitor on carbon steel, Corrosion Science, 125, 67 (2017). Doi: https://doi.org/10.1016/j.corsci.2017.06.004
  9. H. Khani, R. Arefinia, Corrosion, Inhibition mechanism of nitrite on the corrosion of carbon steel in simulated cooling water systems, Materials and Corrosion, 69, 337 (2018). Doi: https://doi.org/10.1002/maco.201709735
  10. Y. Qiang, S. Zhang, B. Tan, S. Chen, Evaluation of Ginkgo leaf extract as an eco-friendly corrosion inhibitor of X70 steel in HCl solution, Corrosion Science, 133, 6 (2018). Doi: https://doi.org/10.1016/j.corsci.2018.01.008
  11. W. Guo, A. Umar, Q. Zhao, M.A. Alsaiari, Y. AlHadeethi, L. Wang, M. Pei, Corrosion inhibition of carbon steel by three kinds of expired cephalosporins in 0.1 M H2SO4, Journal of Molecular Liquids, 320, 114295 (2020). Doi: https://doi.org/10.1016/j.molliq.2020.114295
  12. A.Y. El-Etre, Physics, Inhibition of C-steel corrosion in acidic solution using the aqueous extract of zallouh root, Materials Chemistry and Physics, 108, 278 (2008). Doi: https://doi.org/10.1016/j.matchemphys.2007.09.037
  13. N. El Hamdani, R. Fdil, M. Tourabi, C. Jama, F. Bentiss, Alkaloids extract of Retama monosperma (L.) Boiss. seeds used as novel eco-friendly inhibitor for carbon steel corrosion in 1 M HCl solution: Electrochemical and surface studies, Applied Surface Science, 357, 1294 (2015). Doi: https://doi.org/10.1016/j.apsusc.2015.09.159
  14. D. Borisova, D. Akcakayiran, M. Schenderlein, H. Mohwald, D. Shchukin, Nanocontainer?based anticorrosive coatings: effect of the container size on the self?healing performance, Advanced Functional Materials, 23, 3799 (2013). Doi: https://doi.org/10.1002/adfm.201203715
  15. W. Li, A. Liu, H. Tian, D. Wang, Controlled Release of Nitrate and Molybdate Intercalated in Zn-Al-Layered Double Hydroxide Nanocontainers towards Marine Anticorrosion Applications, Colloid and Interface Science Communications, 24, 18 (2018). Doi: https://doi.org/10.1016/j.colcom.2018.03.003
  16. H. Tian, W. Li, A. Liu, X. Gao, P. Han, R. Ding, C. Yang, D. Wang, Controlled delivery of multi-substituted triazole by metal-organic framework for efficient inhibition of mild steel corrosion in neutral chloride solution, Corrosion Science, 131, 1 (2018). Doi: https://doi.org/10.1016/j.corsci.2017.11.010
  17. Z. Zheng, X. Huang, M. Schenderlein, D. Borisova, R. Cao, H. Mohwald, D. Shchukin, Self?Healing and Antifouling Multifunctional Coatings Based on pH and Sulfide Ion Sensitive Nanocontainers, Advanced Functional Materials, 23, 3307 (2013). Doi: https://doi.org/10.1002/adfm.201203180
  18. T.D. Nguyen, A.S. Nguyen, B.A. Tran, K.O. Vu, T.T. Phan, N. Scharnagl, M.L. Zheludkevich, T.X.H. To, Molybdate intercalated hydrotalcite/graphene oxide composite as corrosion inhibitor for carbon steel, Surface and Coatings Technology, 399, 126165 (2020). Doi: https://doi.org/10.1016/j.surfcoat.2020.126165
  19. S. K. Poznyak, J. Tedim, L. M. Rodrigues, A. N. Salak, M. L. Zheludkevich, L. F. P. Dick, and M. G. S. Ferreira, Novel inorganic host layered double hydroxides intercalated with guest organic inhibitors for anticorrosion applications, ACS Applied Materials & Interfaces, 1, 2353 (2009). Doi: https://doi.org/10.1021/am900495r
  20. E. Alibakhshi, E. Ghasemi, M. Mahdavian, B. Ramezanzadeh, Corrosion inhibitor release from Zn-Al-[PO43-]-[CO32-] layered double hydroxide nanoparticles, Progress in Color, Colorants and Coatings, 9, 233 (2016).
  21. Y. Tang, F. Wu, L. Fang, T. Guan, J. Hu, S. Zhang, A comparative study and optimization of corrosion resistance of ZnAl layered double hydroxides films intercalated with different anions on AZ31 Mg alloys, Surface and Coatings Technology, 358, 594 (2019). Doi: https://doi.org/10.1016/j.surfcoat.2018.11.070
  22. R.-C. Zeng, Z.-G. Liu, F. Zhang, S.-Q. Li, H.-Z. Cui, E.-H. Han, Corrosion of molybdate intercalated hydrotalcite coating on AZ31 Mg alloy, Journal of Materials Chemistry A, 2, 13049 (2014). Doi: https://doi.org/10.1039/C4TA01341G
  23. X. Yu, J. Wang, M. Zhang, P. Yang, L. Yang, D. Cao, J. Li, One-step synthesis of lamellar molybdate pillared hydrotalcite and its application for AZ31 Mg alloy protection, Solid State Sciences, 11, 376 (2009). Doi: https://doi.org/10.1016/j.solidstatesciences.2008.08.003
  24. L. Hou, Y. Li, J. Sun, S.H. Zhang, H. Wei, Y. Wei, Enhancement corrosion resistance of Mg Al layered double hydroxides films by anion-exchange mechanism on magnesium alloys, Applied Surface Science, 487, 101 (2019). Doi: https://doi.org/10.1016/j.apsusc.2019.05.048
  25. D. Li, F. Wang, X. Yu, J. Wang, Q. Liu, P. Yang, Y. He, Y. Wang, M. Zhang, Anticorrosion organic coating with layered double hydroxide loaded with corrosion inhibitor of tungstate, Progress in Organic Coatings, 71, 302 (2011). Doi: https://doi.org/10.1016/j.porgcoat.2011.03.023
  26. L. Guo, F. Zhang, J.-C. Lu, R.-C. Zeng, S.-Q. Li, L. Song, J.-M. Zeng, A comparison of corrosion inhibition of magnesium aluminum and zinc aluminum vanadate intercalated layered double hydroxides on magnesium alloys, Frontiers of Materials Science, 12, 198 (2018). Doi: https://doi.org/10.1007/s11706-018-0415-2
  27. X. Wang, L. Li, Z.-H. Xie, G. Yu, Duplex coating combining layered double hydroxide and 8-quinolinol layers on Mg alloy for corrosion protection, Electrochimica Acta, 283, 1845 (2018). Doi: https://doi.org/10.1016/j.electacta.2018.07.113
  28. B. Wu, J. Zuo, B. Dong, F. Xing, C. Luo, Study on the affinity sequence between inhibitor ions and chloride ions in MgAl layer double hydroxides and their effects on corrosion protection for carbon steel, Applied Clay Science, 180, 105181 (2019). Doi: https://doi.org/10.1016/j.clay.2019.105181
  29. D.T. Nguyen, H.T.X. To, J. Gervasi, M. Gonon, M.-G. Olivier, Corrosion inhibition of carbon steel by hydrotalcites modified with different organic carboxylic acids for organic coatings, Progress in Organic Coatings, 124, 256 (2018). Doi: https://doi.org/10.1016/j.porgcoat.2017.12.006
  30. T.T.X. Hang, T.A. Truc, N.T. Duong, N. Pebere, M.-G. Olivier, Layered double hydroxides as containers of inhibitors in organic coatings for corrosion protection of carbon steel, Progress in Organic Coatings, 74, 343 (2012). Doi: https://doi.org/10.1016/j.porgcoat.2011.10.020
  31. T.T.X. Hang, T.A. Truc, N.T. Duong, P.G. Vu, T. Hoang, Preparation and characterization of nanocontainers of corrosion inhibitor based on layered double hydroxides, Applied Clay Science, 67, 18 (2012). Doi: https://doi.org/10.1016/j.clay.2012.07.004
  32. T.T.X. Hang, N.T. Duong, T.A. Truc, T. Hoang, D.T.M. Thanh, S. Daopiset, A. Boonplean, Effects of hydrotalcite intercalated with corrosion inhibitor on cathodic dis-bonding of epoxy coatings, Journal of Coatings Technology and Research, 12, 375 (2015). Doi: https://doi.org/10.1007/s11998-014-9642-3
  33. L. Wu, X. Ding, Z. Zheng, Y. Ma, A. Atrens, X. Chen, Z. Xie, D. Sun, F. Pan, Fabrication and characterization of an actively protective Mg-Al LDHs/Al2O3 composite coating on magnesium alloy AZ31, Applied Surface Science, 487, 558 (2019). Doi: https://doi.org/10.1016/j.apsusc.2019.05.115
  34. Y. Zhao, Y. Chen, W. Wang, Z. Zhou, S. Shi, W. Li, M. Chen, Z. Li, One-step in situ synthesis of nano silverhydrotalcite coating for enhanced antibacterial and degradation property of magnesium alloys, Materials Letters, 265, 127349 (2020). Doi: https://doi.org/10.1016/j.matlet.2020.127349
  35. T.D. Nguyen, A.S. Nguyen, B.A. Tran, K.O. Vu, D.L. Tran, T.T. Phan, N. Scharnagl, M.L. Zheludkevich, T.X.H. To, Molybdate intercalated hydrotalcite/graphene oxide composite as corrosion inhibitor for carbon steel, Surface and Coatings Technology, 399, 126165 (2020). Doi: https://doi.org/10.1016/j.surfcoat.2020.126165
  36. T.D. Nguyen, B.A. Tran, K.O. Vu, A.S. Nguyen, A.T. Trinh, G.V. Pham, T.X.H. To, M.V. Phan, T.T. Phan, Corrosion protection of carbon steel using hydrotalcite/graphene oxide nanohybrid, Journal of Coatings Technology and Research, 16, 585 (2018). Doi: https://doi.org/10.1007/s11998-018-0139-3
  37. J.E. Olszowka, R. Karcz, E. Bielanska, J. Krysciak-Czerwenka, B.D. Napruszewska, B. Sulikowski, R.P. Socha, A. Gawel, K. Bahranowski, Z. Olejniczak, E.M. Serwicka, New insight into the preferred valency of interlayer anions in hydrotalcite-like compounds: The effect of Mg/Al ratio, Applied Clay Science, 155, 84 (2018). Doi: https://doi.org/10.1016/j.clay.2018.01.013
  38. A.N. Salak, J. Tedim, A.I. Kuznetsova, J.L. Ribeiro, L.G. Vieira, M.L. Zheludkevich, M.G.S. Ferreira, Comparative X-ray diffraction and infrared spectroscopy study of Zn-Al layered double hydroxides: Vanadate vs nitrate, Chemical Physics, 397, 102 (2012). Doi: https://doi.org/10.1016/j.chemphys.2012.01.026
  39. Y. Zhang, Y. Li, Y. Ren, H. Wang, F. Chen, Double-doped LDH films on aluminum alloys for active protection, Materials Letters, 192, 33 (2017). Doi: https://doi.org/10.1016/j.matlet.2017.01.038
  40. D. Nguyen Thuy, H. To Thi Xuan, A. Nicolay, Y. Paint, M.-G. Olivier, Corrosion protection of carbon steel by solvent free epoxy coating containing hydrotalcites intercalated with different organic corrosion inhibitors, Progress in Organic Coatings, 101, 331 (2016). Doi: https://doi.org/10.1016/j.porgcoat.2016.08.021
  41. T.D. Nguyen, A.S. Nguyen, T.T. Thai, G.V Pham, T.X.H. To, M.-G. Olivier, The influence of hydrotalcite intercalated with benzoate on UV stability of acrylic coating, Corrosion science and Technology, 19, 16 (2020), Doi: https://doi.org/10.14773/cst.2020.19.1.16
  42. O. Meyer, F. Roessner, R. A. Rakoczy, R. W. Fischer, Impact of Organic Interlayer Anions in Hydrotalcite Precursor on the Catalytic Activity of Hydrotalcite-Derived Mixed Oxides, Chem.Cat.Chem., 2, 314 (2010). Doi: https://doi.org/10.1002/cctc.200900257
  43. A.V. Radha, P. Vishnu Kamath, C. Shivakumara, Mechanism of the anion exchange reactions of the layered double hydroxides (LDHs) of Ca and Mg with Al, Solid State Sciences, 7, 1180 (2005). Doi: https://doi.org/10.1016/j.solidstatesciences.2005.05.004