Electrospray is used in various industries because it can produce continuous and uniform droplets. However, it is difficult to find optimal spraying condition due to lack of data in various conditions. In this study, various conditions were divided into electric parameters and fluid property. The electric parameters set Nozzle to Substrate(NTS), nozzle diameters and the fluid property set viscosity and conductivity as conditions. In this study, it observes spray patterns, Sauter Mean Diameter(SMD) according to conditions. As a result, fluid properties had a greater effect on the cone-Jet mode than on the nozzle diameter, NTS, and flowrate. All of solutions have Stable cone-jet mode at voltage of 8.5 kV, NTS of 20 mm and nozzle diameter of 0.2 mm. SMD has 27% different depending on viscosity and conductivity. The increased flowrate and viscosity are rising break-up length and thickening jet also jet is thinned by increased conductivity. Experiments have confirmed that the jet is thickened by increased flowrate and viscosity, and that the jet is thinned by conductivity.